ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We report a combined experimental and theoretical study of the intermolecular vibrations and van der Waals isomerism of the 2,3-dimethylnaphthalene⋅He van der Waals complex. Two-color resonant two-photon ionization spectra of the S0→S1 electronic transition of 2,3-dimethylnaphthalene⋅He exhibit five bands within 30 cm−1 of the electronic origin. The intermolecular potential energy surface was modeled as a sum of atom–atom Lennard-Jones pair potentials; it exhibits two equivalent global minima on each side of the naphthalene moiety, and a single shallower local minimum adjacent to the two methyl groups. Based on this surface, accurate three-dimensional quantum calculations of the van der Waals vibrational levels using the discrete variable representation method were performed. Careful optimization of the potential parameters lead to a quantitative reproduction of four observed bands as intermolecular vibrational excitations, a vibrationally averaged He atom distance from the aromatic plane 〈z0〉=3.22 Å, and a dissociation energy D0(S1)=−60.3 cm−1, compatible with experiments. The fifth band is assigned as a van der Waals isomer, corresponding to the local minimum. The quantum calculations were extended up to the dissociation limit, yielding (approximate)173 van der Waals vibrational states. Above 70% of D0, many vibrational states are completely delocalized over the potential surface, with root-mean-square vibrational amplitudes up to 6 Å parallel to and up to 1.5 Å perpendicular to the molecular surface. Calculated tunnelling splittings range from 〈10−4 cm−1 for localized states, to 〉3 cm−1 for highly delocalized ones. © 1997 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.475170
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