ALBERT

Description: Analyses of stable isotopes of monospecific planktonic foraminifers (G. quadrilobatus group) and monogeneric benthic foraminifers (Cibicidoides spp.) from late Neogene Atlantic Site 502 and Pacific Site 503 were conducted in order to determine the paleoceanographic changes resulting from the late Neogene uplift of the Panama Isthmus and from climatic cooling. In general, results at each site are similar to those from previous studies for the late Miocene and late Pliocene time interval, documenting the late Miocene (6 Ma) shift in carbon isotopes and the inferred growth of permanent Northern Hemisphere continental ice sheets beginning about 3.2 Ma. Comparison of Atlantic-Pacific planktonic-benthic isotope data for four stratigraphic intervals (~6-8, ~5-6, ~3-5, and ~2-3 Ma) suggests that increasing isolation of Atlantic and Pacific low-latitude waters may be related to the emergence of the Panama Isthmus. The contrast between Atlantic and Pacific benthic foraminiferal d13C increased in two steps from 0.60 per mil to 1 per mil (the modern contrast) at about 6 Ma and 3 Ma. The first increase (0.15 per mil) may represent the end of previously limited deep-water communication between the Atlantic and Pacific at the present location of Panama. The second increase (0.25 per mil) may be due to increased production of North Atlantic Deep Water. This probably reflects the development of modern deep-sea circulation. The d18O of planktonic foraminifers begins to increase in Atlantic Site 502 at 4.2 Ma and may reflect the increasing salinity of the North Atlantic Ocean arising from diminishing surface-water exchange across Panama. This increase is clearly shown by contrasting the d18O of Atlantic and Pacific planktonic foraminifers, as well as the d18O of planktonic and benthic foraminifers at Site 502. This inferred increase in surface-water salinity begins at the time of increasing provinciality of Atlantic and Pacific planktonic foraminifers.

Description: The object of the present study is to introduce a means of comparing the Vostok and marine chronologies. Our strategy has been to use the delta18O of atmospheric O2 (denoted delta18Oatm) from the Vostok ice core as a proxy for the delta18O of seawater (denoted delta18Osw). Our underlying premise in using delta18Oatm as a proxy for delta18Osw is that past variations in delta18Osw (an indicator of continental ice volume) have been transmitted to the atmospheric O2 reservoir by photosynthesizing organisms in the surface waters of the world's oceans. We compare our record of delta18Oatm to the delta18Osw record which has been developed from studies of the isotopic composition of biogenic calcite (delta18Oforam) in deep-sea cores. We have tied our delta18Oatm record from Vostok to the SPECMAP timescale throughout the last 135 kyr by correlating delta18Oatm with a delta18Osw record from V19-30. Results of the correlation indicate that 77% of the variance is shared between these two records. We observed differences between the delta18Oatm and the delta18Osw records during the coldest periods, which indicate that there have been subtle changes in the factors which regulate delta18Oatm other than delta18Osw. Our use of delta18Oatm as a proxy for delta18Osw must therefore be considered tentative, especially during these periods. By correlating delta18Oatm with delta18Osw, we provide a common temporal framework for comparing phase relationships between atmospheric records (from ice cores) and oceanographic records constructed from deep-sea cores. Our correlated age-depth relation for the Vostok core should not be considered an absolute Vostok timescale. We consider it to be the preferred timescale for comparing Vostok climate records with marine climate records which have been placed on the SPECMAP timescale. We have examined the fidelity of this common temporal framework by comparing sea surface temperature (SST) records from sediment cores with an Antarctic temperature record from the Vostok ice core. We have demonstrated that when the southern ocean SST and Antarctic temperature records are compared on this common temporal framework, they show a high degree of similarity. We interpret this result as supporting our use of the common temporal framework for comparing other climate records from the Vostok ice core with any climate record that has been correlated into the SPECMAP chronology.

Description: The usefulness of cosmogenic beryllium-10 (half life = 2.5 Ma) for studying the rates of accumulation of ferromanganese nodules is reported based on its measured depth distribution in the top 20 mm of these deposits. Accumulation rates have been obtained in the range of 1 to 4 mm/Ma, which are in good agreement with rates determined using the 230Th method on the same nodules. The use of 10Be offers promise in extending the dating to the outer few cm of the nodules. This contrasts with conventional methods using 230Th and 231Pa isotopes which, due to their comparatively short half lives, are limited to a few mm at the surface of the nodules. Detailed studies of 10Be in the manganese deposits coupled with other trace element analyses should prove valuable in understanding the processes of formation of these deposits and the chronology of events recorded by them.