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  • Cadmium  (4)
  • Gas chromatography  (4)
  • 42.55
  • Springer  (10)
  • American Association of Petroleum Geologists (AAPG)
  • 1980-1984  (10)
  • 1981  (10)
Collection
Keywords
Publisher
  • Springer  (10)
  • American Association of Petroleum Geologists (AAPG)
  • Wiley-Blackwell  (6)
Years
  • 1980-1984  (10)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Radiocarbon dating by infrared laser spectroscopy (1981)
    Springer
    Applied physics 24 (1981), S. 381-386 
    Details
    ISSN: 1432-0630
    Keywords: 33 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A tunable diode laser and a multipass optical cell are used to investigate the feasibility of performing radiocarbon dating by means of infrared spectroscopy. We show that the detection of14CO2 at concentrations of14C/12C≲10−12 is not limited by interferences from the background of normal CO2 molecules, provided the gas sample is cooled. Using short-time constants, the present sensitivity of the infrared technique is comparable to that of an ideal disintegration counter. The experimental results are extrapolated to long time constants to demonstrate that radiocarbon dating by infrared spectroscopy is feasible, and that carbon samples with a mass of less than 1 gm can be dated by this technique.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00899738
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  • 2
    Electronic Resource
    Electronic Resource
    Environmental quality criteria: Some considerations (1981)
    Springer
    Environmental management 5 (1981), S. 191-205 
    Details
    ISSN: 1432-1009
    Keywords: Pollutant toxicity ; Water Quality Criteria ; Microbemediated ecological processes ; Ecological dosage 50% (EcD50) ; Cadmium ; Phenol ; Physicochemical environmental factors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The physicochemical characteristics of the recipient environment into which chemical contaminants are deposited may influence their chemical speciation, mobility, bioavailability, and toxicity. In formulating Water Quality Criteria, the Environmental Protection Agency of the United States (EPA) considered the modifying effect of abiotic environmental factors on pollutant toxicity in an innovative regulatory approach. Scientific knowledge of the interactions and correlations between pollutant toxicity and abiotic factors remains limited. Recognition of the influence of the physicochemical characteristics of the recipient environment on pollutant toxicity has implications for the eventual formulation of regional, rather than uniform and national, criteria. In addition, in developing Water Quality Criteria that incorporate the effects of pollutants on “aquatic life,” EPA primarily focused on toxicity to aquatic animals and plants (including unicellular algae). The effects of pollutants on microbe-mediated ecological processes that are necessary for maintaining the state and quality of the ecosphere (such as biogeochemical cyclings, litter decomposition, and mineralization) were not included in the formulation of the Water Quality Criteria. To facilitate the recognition and quantification of adverse effects of pollutants on these ecological processes, the development of a computation, termed the “ecological dosage 50%” (EcD50) is recommended. Such a formulation could also be applied to setting environmental quality criteria for terrestrial ecosystems.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01873278
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  • 3
    Electronic Resource
    Electronic Resource
    A magnetically stabilized coaxial laser discharge (1981)
    Springer
    Applied physics 26 (1981), S. 161-167 
    Details
    ISSN: 1432-0649
    Keywords: 52.80 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new magnetic discharge stabilization technique for coaxial laser systems is described. The approach utilizes crosses electric and magnetic fields to create and maintain a large and rapidly rotating plasma volume which does not experience glow-to-arc transitions. Very high cw specific discharge power loadings have been achieved even without the benefit of external gas cooling or circulation. Performance is insensitive to gas composition and pressure such that high power coaxial discharges have been run in CO2 laser gas mixtures up to several hundred torr. Stable cw discharges have also been obtained in mixtures containing several torr of SF6. The technique appears to be readily scalable to give very large excited volumes in systems with comparatively small overall physical dimensions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00692441
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  • 4
    Electronic Resource
    Electronic Resource
    Activation of potassium-dependent H+ efflux from mitochondria by cadmium and phenylarsine oxide (1981)
    Springer
    Journal of bioenergetics and biomembranes 13 (1981), S. 425-431 
    Details
    ISSN: 1573-6881
    Keywords: Cadmium ; phenylarsine oxide ; mitochondria ; H+ translocation ; potassium ion ; uncoupling ; dithiol ; monothiol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Physics
    Notes: Abstract Addition of Cd2+ or phenylarsine oxide (PhAsO) to respiring rat liver mitochondria results first in acidification of the medium (H+ efflux) followed by disappearance of H+ (discharge of the pH gradient or uncoupling). The first phase of H+ efflux is dependent upon the presence of K+ in the medium, and is not seen in the presence of valinomycin, which is consistent with the conclusion that H+ efflux is linked to membrane potential-dependent uptake of K+. These effects are abolished by low levels of 2,3-dimercaptopropanol but potentiated by excess of 2-mercaptoethanol, showing involvement of a dithiol type of group in the response. Mersalyl produces only the H+ efflux, and subsequent addition of Cd2+ or PhAsO produces collapse of the ΔpH.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00743214
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  • 5
    Electronic Resource
    Electronic Resource
    Influence of lead, cadmium, and nickel on the growth ofMedicago sativa (L.) (1981)
    Springer
    Plant and soil 60 (1981), S. 223-236 
    Details
    ISSN: 1573-5036
    Keywords: Alfalfa ; Cadmium ; Lead ; Nickel ; Tissue concentration ; Yield depressions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Alfalfa (Medicago sativa L.), cv. Iroquois, was grown in the greenhouse in soils amended with additions of either lead, cadmium, or nickel. Metals, at rates varying from 0–250 ppm, were not uniformly mixed but were placed close to the soil surface so as to simulate surface deposition. In one series of experiments the sulphate salt of each metal and two soils were used. In a second series of experiments the nitrate salts and one soil were used. Neither salt of lead significantly depressed alfalfa yields. Both salts of either cadmium or nickel significantly depressed yields. Additions of all metals to the soil resulted in both increased metal uptake and concentrations in alfalfa tissue, particularly for cadmium and nickel. The highest tissue concentrations of cadmium and nickel were associated with plant stunting and necrosis. However, at rates of 125 ppm and less, substantial increases in cadmium and nickel concentrations were obtained frequently without serious yield reductions. Generally, metal concentrations were greatest in the first harvest following metal application. Concentration and uptake of lead and cadmium were greater when the metal was applied to the soil as nitrate than when applied as the sulphate salt.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02374107
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  • 6
    Electronic Resource
    Electronic Resource
    The influence of lead, cadmium, and nickel on the growth of ryegrass and oats (1981)
    Springer
    Plant and soil 62 (1981), S. 81-89 
    Details
    ISSN: 1573-5036
    Keywords: Cadmium ; Lead ; Nickel ; Oats ; Ryegrass ; Tissue concentration ; Yield depression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary A 24 factorial experiment was conducted under greenhouse conditions. Factors and levels in the experiment were soil pH at 4.5 and 6.4, and cadmium, lead, and nickel added to the soil to provide soil concentrations of 50, 250, and 50 ppm, respectively, above background levels. Two species were grown in succession in the same experimental pots. Ryegrass (Lolium hybridum Hausskn. cv. Tetrelite) was harvested three times and then one crop of oats (Avena sativa L. cv. Garry) was grown and harvested. Plant tissue concentrations of cadmium, lead, and nickel were monitored throughout the experiment. Addition of cadmium to the soil lowered the dry matter yields in all three ryegrass harvests and also reduced the yield of oat grain. The application of lead nitrate to the soil enhanced the yield of ryegrass obtained at the first harvest and also increased the yield of oat grain. Nickel, added to the soil at 50 ppm, was relatively innocuous to ryegrass and oats. The presence of added cadmium, lead, or nickel to the soil resulted in enhanced tissue concentrations of these metals in both ryegrass and oats. This effect was particularly enhanced by a soil pH of 4.5. A single exception to this observation was that lead was not detected, under any of the conditions of this experiment, in oat grain. The presence of lead in the soil enhanced cadmium concentrations in ryegrass tissues. The presence of cadmium in the soil decreased lead tissue concentrations in ryegrass and oat straw. Soil pH interacted with both nickel and lead in the second ryegrass harvest with subsequent changes in tissue cadmium concentrations. At a soil pH of 4.5, the presence of added lead or nickel to the soil significantly increased the ryegrass tissue cadmium concentration beyond that observed at a soil pH of 6.4 with or without enhanced nickel or lead concentrations.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02205027
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  • 7
    Electronic Resource
    Electronic Resource
    Determination of average molecular polarizabilities of polycyclic aromatic hydrocarbons directly from retention indices (1981)
    Springer
    Chromatographia 14 (1981), S. 707-708 
    Details
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Polycyclic aromatic hydrocarbons ; Retention index ; Average molecular polarizabilities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A significant correlation has been found between the retention indices of polycyclic aromatic hydrocarbons on non-polar stationary phases and the average molecular polarizabilities of the molecules separated on these phases. Equations have been derived for the determination of the average molecular polarizabilities, directly from the retention indices.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02259460
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  • 8
    Electronic Resource
    Electronic Resource
    Factors affecting the retention of polycyclic aromatic hydrocarbons in gas chromatography (1981)
    Springer
    Chromatographia 14 (1981), S. 69-72 
    Details
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Polynuclear aromatic hydrocarbons ; Retention index ; Vapour pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The retention index of a planar polynuclear aromatic hydrocarbon on the GC phases OV-101, SE-52, and OV-17 is strictly related only to the boiling point, and less closely to the relative molecular mass. The very approximates relation with connectivity index ins only a consequence of the latter. On a nematic lqiuid crystal phase, a variation of activity coefficient, expressed in terms of a shape factor, also influences the retention of PAH.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02279514
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  • 9
    Electronic Resource
    Electronic Resource
    Chemically modified teflon wall-coated open tubular columns for gas chromatography (1981)
    Springer
    Chromatographia 14 (1981), S. 19-22 
    Details
    ISSN: 1612-1112
    Keywords: Teflon columns ; Chemically modified teflon ; Gas chromatography ; Capillary columns
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Wall-coated open tubular columns prepared from chemically modified teflon tubing have been developed for gas chromatography. Chemical reaction of the inner walls of teflon tubing allows bonding of an adhesive layer on which a variety of stationary phaes can be coated. Test mixtures of alkanes and alcohols were used to investigate the chromatographic properties of these columns and the stability and mixing of the adhesive and stationary phae layers. the results in dicate that mixing of the layers is negligible and that the column is stable for a long period of time.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02262057
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  • 10
    Electronic Resource
    Electronic Resource
    Characterization of glass, quartz, and fused silica capillary column surfaces from contact-angle measurements (1981)
    Springer
    Chromatographia 14 (1981), S. 387-397 
    Details
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Capillary columns ; Fused silica ; Contact angle ; Wettability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary This paper describes the systematic characterization of glass and the newly introduced fused silica and quartz capillary columns from surface wettability measurements. Common gas chromatographic stationary phases were used in capillary-rise measurements at temperatures up to 300°C. By construction of Zisman plots and using the Cassie equation, the relative surface concentrations of wettable and non-wettable groups were determined. By application of the Fowkes equation, the dispersion force component of the surface energy was investigated. The influence of various surface treatments such as leaching, silylation, and polymeric film formation are discussed. Wettability measurements were also used to evaluate the thermostability of various treated surfaces and to compare the surface properties of glass, quartz, and fused silica. The wettability of the surfaces with selected stationary phases as a function of temperature is also discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02262872
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