Summary
Wall-coated open tubular columns prepared from chemically modified teflon tubing have been developed for gas chromatography. Chemical reaction of the inner walls of teflon tubing allows bonding of an adhesive layer on which a variety of stationary phaes can be coated. Test mixtures of alkanes and alcohols were used to investigate the chromatographic properties of these columns and the stability and mixing of the adhesive and stationary phae layers. the results in dicate that mixing of the layers is negligible and that the column is stable for a long period of time.
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D. H. Desty, J. H. Haresnape, B. H. Whyman, Anal. Chem.32 302 (1960).
K. Grob, Helv. Chim Acta51, 718 (1968).
F. I. Onuska, Can Res.12, 26 (1979).
J. J. Franken, G. A. Rutten, J. A. Rijks, J. Chromatogr.126, 117 (1976).
A. S. Christophersen, K. E. Rasmussen, F. Tonnesen, J. Chromatogr.179, 87 (1979).
G. Schomburg, H. Husmann, H. Borwitzky, Chromatographia12, 651 (1979).
K. Grob Jr., g. Grob, K. Grob, J. Chromatogr.156, 1 (1978).
M. H. J. van Rijswich, K. Tesarik, Chromatographia7, 135 (1974).
M. L. Lee, D. L. Vassilaros, L. V. Phillips, D. M. Hercules, H. Azumaya, J. W. Jorgenson, M. P. Maskariner, M. Novotny, Anal Lett.12, 191 (1979).
M. Verzele, P. Sandra, J. High Resolut. Chromatogr. Chromatogr. Commun.2, 303 (1979).
K. Grob, “Blood, Drugs and Other Analytical Challenges”,E. Reid, Ed., Wiley, New York, 1978, p. 85.
A. L. Gordon, P. J Taylor, F. W. Harris, J. Chromatogr. Sci.14, 428 (1976).
K. Grob, G. Grob, K. Grob, Jr., J. High Resolut. Chromatogr. Chromatogr. Commun.2, 31 (1979).
K. D. Bartle, M. Novotny, J. Chromatogr.94, 35 (1974).
R. Dandeneau, P. Bente, T. Rooney, R. Hiskes, Amer Lab.11 (9), 61 (1979).
S. R. Lipsky, W. J. McMurray, M. Hernandez, J. E. Purcell, K. A. Billeb, J. Chromatogr. Sci.18, 1 (1980).
J. J. Krirkland, Anal. Chem.35, 2003 (1963).
R. L. Pecsok, B. H. Gump, J. Phys. Chem.71, 2202 (1967).
J. R. Conder, D. C. Locke, J. H. Purnell, J. Phys. Chem.73, 700 (1969).
J. R. Conder, Anal. Chem.43, 367 (1971).
J. R. Conder, C. Young “Physicochemical Measurments by Gas Chromatography”, Wiley, New York, 1979, p. 487.
J. Roeraade, Chromatographia8, 511 (1975).
L. S. Ettre, “Open Tubular Columns in Gas Chromatography”, Plenum Press, New York, 1956, p. 76.
E. R. Nelson, T. J. Kilduff, A. A. Benderly, Ind. Eng. Chem.50, 329 (1958).
A. A. Beneerly, J. Appl. Polym. Sci.6, 221 (1962).
W. Jennings, “Gas Chromatography with Glass capillary Columns”, Academic Press, New York, 1980. p. 39.
J. R. Conder, C. Young, “Physicochemical Measurements by Gas Chromatography”, Wiley, New York, 1979, pp. 17–18.
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Bombick, D., DiNunzio, J. Chemically modified teflon wall-coated open tubular columns for gas chromatography. Chromatographia 14, 19–22 (1981). https://doi.org/10.1007/BF02262057
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DOI: https://doi.org/10.1007/BF02262057