Summary
The retention index of a planar polynuclear aromatic hydrocarbon on the GC phases OV-101, SE-52, and OV-17 is strictly related only to the boiling point, and less closely to the relative molecular mass. The very approximates relation with connectivity index ins only a consequence of the latter. On a nematic lqiuid crystal phase, a variation of activity coefficient, expressed in terms of a shape factor, also influences the retention of PAH.
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References
M. L. Lee andB. W. Wright, J. Chromatogr. Sci.18, 345 (1980).
L. S. Lysyuk andA. N. Korol, Chromatographia10, 712 (1977).
H. Borwitzky andG. Schomburg, J. Chromatogr.170, 99 (1979).
G. M. Janini, K. Johnston andW. L. Zielinski, Anal. Chem.47, 670 (1975).
W. L. Zielinski andG. M. Janini, J. Chromatogr.186, 2237 (1979).
G. M. Janini, G. M. Muschik andW. L. Zielinski, Anal. Chem.48, 1879 (1976).
R. Kaliszan andH. Lamparczyk, J. Chromatogr. Sci.16, 246 (1978).
A. Radecki, H. Lampacrzyk andR. Kaliszian, Chrioamtographia12, 595 (1979).
H. Beernaert, J. Chromatogr.173, 109 (1979).
H. Purnell, “Gas Chromatography”, Wiley, New York, 1962.
M. L. Lee, D. L. Vassilaros, C. M. White andM. Novotny, Anal. Chem.51, 768 (1979).
W. E. Harris andH. W. Habgood, “Programmed Temperature Gas Chromatography”, Wiley, New York, 1966.
L. B. Kier andL. H. Hall, “Connectivity in Chemistry and Drug Research”, Academic Press, New York, 1976.
J. K. Haken, Advances in Chromatogr.14, 367 (1976).
J. Timmermans, “Physico-Chemical Constants of Pure Organic Compounds”, Elsevier, New York, 1950.
“Handbook of Chemistry and Physics”, Chemical Rubber Co., Cleveland, Ohio, 1979.
API Publications 708 and 709, American Petroleum Institute, Washington D.C., 1979.
R. Kaliszan, H. Lamparczyk andA. Radecki, Biochem. Pharmacol.28, 123 (1979).
S. A. Wise, W. J. Bonnett, F. R. Guenther andW. E. May, J. Chromatogr. Sci., submitted.
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Bartle, K.D., Lee, M.L. & Wise, S.A. Factors affecting the retention of polycyclic aromatic hydrocarbons in gas chromatography. Chromatographia 14, 69–72 (1981). https://doi.org/10.1007/BF02279514
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DOI: https://doi.org/10.1007/BF02279514