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  • Chemistry  (404)
  • 1980-1984
  • 1975-1979  (404)
  • 1955-1959
  • 1940-1944
  • 1979  (404)
  • 1
    Electronic Resource
    Electronic Resource
    Untersuchungen zur Sulfochlorierung von Paraffinen. V. Kinetische Untersuchungen über die Sulfochlorierung definierter Alkansulfochloride (1979)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 279-292 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Studies on Sulphochlorination of Paraffins. V. Kinetic Studies on the Sulphochlorination of Pure AlkanesulphochloridesThe mixtures of disulphochlorides formed by sulphochlorination of 1-alkanesulphochlorides C4—C9 may be analyzed gaschromatographically after transformation into the corresponding dimethylamides. The individual peaks could be identified in some cases with the aid of pure isomeric disulphochlorides, in other cases they were identified by analogy. The mixtures formed by sulphochlorination of the isomeric heptane sulphochlorides also could be analyzed after transformation into the dimethylamides; the identification of all peaks was possible by comparison of the mixtures obtained from different heptane sulphochlorides.For the alkane sulphochlorides studied the relative rates of sulphochlorination (with reference to n-octane) were determined, and therefore the relative reaction rates of the individual C—H-bonds with reference to one primary C—H-bond of n-octane could be calculated.The results show a geminal or vicinal disubstitution not to take place in noticeable amount. In position 3 or in greater distance the influence of the sulphochloride group on the reactivity of the C—H-bonds is not significant.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19793210214
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  • 2
    Electronic Resource
    Electronic Resource
    D2-m-carboranesiloxanes. VIII. Preparation and characterization of carboranesiloxane/polysulfone alternating block copolymer (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 115-123 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A D2-m-dodecacarboranesiloxane containing alternating block copolymer \documentclass{article}\pagestyle{empty}\begin{document}$\rlap{--}[{\rm A}\hbox{---}{\rm B}\rlap{--}]_n$\end{document} was prepared by the reaction of a ureidosilane-terminated polysulfone hard block with a carboranesilanol-terminated carboranesiloxane oligomer. The resulting block copolymer exhibited thermoplastic elastomeric behavior. This unique polymer had excellent thermal stability up to 400°C.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070240110
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  • 3
    Electronic Resource
    Electronic Resource
    Platelet interaction with synthetic copolypeptide films (1979)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 13 (1979), S. 765-782 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Kinetic and equilibrium studies of blood platelet binding to copolypeptide films show that attachment and serotonin release are not dependent upon the composition of the copolypeptide. Data may be explained by postulating that platelets frequently collide elastically with the surface but leave behind material that modifies subsequent behavior. Similarly, material released from platelets adsorbs at the interface and the extent of attachment and serotonin release are modified and controlled by these adsorbed species. Basically, if the platelet is exposed to a clean surface, its collision with the surface leads to activation and release. In the presence of inert protein, the collision is cushioned by the protein and platelets do not attach or release to any extent. Finally, if protein (or other entities) released from the platelet provide attachment sites, than attachment occurs without release. It is postulated that the behavior of platelets at surfaces is controlled by these interrelated processes.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820130508
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  • 4
    Electronic Resource
    Electronic Resource
    Composition-Depth profiling and interface analysis of surface coatings using ball cratering and the scanning auger microprobePaper presented at the International Conference on Quantitative Surface Analysis, held at the National Physical Laboratory, Teddington, UK, 16-17 October 1979. (1979)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 1 (1979), S. 204-210 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The provision of accurate composition-depth profiles to depths 〉 1 μm is important in the characterization and investigation of thick films, surface coatings, surface treatments and many other technologically important applications. At present, such profiles are usually achieved by sequential ion bombardment and surface analysis and hence involve many difficulties in interpretation due to the non-uniform erosion of surfaces under ion bombardment. In this paper a method of obtaining accurate depth profiles is described using a ball-cratering device. The method employs a rotating ball to fashion a well-defined spherical crater in the sample surface, the depth and width of which can be accurately controlled. The specimen is then cleaned in situ using a scanning ion beam for a short period and the composition-depth profile is obtained either by point-by-point analysis down the sloping sides of the crater wall or by using Auger line-scan techniques across the crater. Coating-substrate interface analysis can also be obtained by sputter-depth profiling at a point on the coating close to the exposed substrate. The method is not only considerably faster than ion etching, but the resulting depth profile also has a well-defined depth resolution. Composition-depth profiles through nitrocarburized mild steel surfaces and protective surface coatings are presented to illustrate the usefulness of the technique.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740010607
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  • 5
    Electronic Resource
    Electronic Resource
    Cis-trans double bond distribution in poly(1,3-cyclopentylenevinylene); dependence on metathesis catalyst, cocatalyst, and additives (1979)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 180 (1979), S. 1989-2000 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: About one hundred samples of poly(1,3-cyclopentylenevinylene) (2) were prepared by ring-opening polymerization of norbornene using a variety of metathesis catalysts based mainly on WCl6 or MoCl5, with EtAlCl2, BuLi, Ph4Sn, and (CH2=CHCH2)4Sn as cocatalysts, and with methyl acrylate, diethyl maleate or diethyl fumarate as additives. Ir, Re, V, and Os compounds were also used as catalysts. The double bond pair sequences, trans-trans (tt), trans-cis (tc) etc. were determined from the 13C NMR spectra of these samples and the ratios rt(=tt/tc) and rc(=cc/ct) examined as a function of the fraction of double bonds σc having cis structure. For σc up to 0,35 all polymers showed random distribution of cis and trans structures (rtrc = 1), corresponding to a single type of propagating species. Polymers having σc = 0,35-0,85 invariably gave rtrc ≥ 1, with values greater than 5 in some cases. It is proposed that steric crowding of the active site leads both to high values of σc and to restriction of rotation about the metal-carbene bond of the propagating metalcarbene species, such as to give rise to kinetically distinct conformations which tend to regenerate their own kind on addition of monomer.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1979.021800813
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  • 6
    Electronic Resource
    Electronic Resource
    Solvent barrier property for fluorinated polyethylene (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1907-1913 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Solvent barrier studies for fluorinated polyethylene have shown that the fluorinated surfaces reduce the rate of permeation for many solvents. The barrier property has been related to physical and chemical properties of the solvent. For instance, solvents having a dielectric constant between 7 and 10 were not retained as well as solvents with a dielectric constant less than 7.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070230701
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  • 7
    Electronic Resource
    Electronic Resource
    The characterization of nylon 6 filaments by x-ray diffraction (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1747-1757 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method is described for calculating crystallinity indices and crystalline orientation functions for the α and γ components of the crystalline phase of nylon 6 filaments using wide-angle x-ray diffraction (WAXS) analysis. The method is shown to be applicable to a wide range of filament samples (“conventional” as-spun, fast spun, drawn, and annealed) even when only a single broad diffraction maximum is observable from the WAXS photograph. The component indices can be used to illustrate differences present in the filament microstructure which would be unobservable if a total crystallinity index, such as that determined by density, were determined alone. For example, the initially mixed α-γ structure is retained in low-temperature drawing (75-150°C) of nylon 6 fiber, but the predominantly α form is produced at higher draw temperatures.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070230615
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  • 8
    Electronic Resource
    Electronic Resource
    Melt spinning of fibers: Effect of air drag (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 3105-3122 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Experimental measurements of the magnitude of air drag on the filament and the air velocity profile around the filament in the spinning and drawing down of a fiber filament in the surrounding of stagnant air are reported. The results are examined in comparison with the existing theoretical correlations that have been used in the studies of the spinning processes. The experimental values of the air drag are found to be larger than the values based on the existing correlations to such an extent that, in some cases of past studies, the air drag effect on the filament tension may have been underestimated.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070231028
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  • 9
    Electronic Resource
    Electronic Resource
    Water-soluble photocurable elastomer (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 115-122 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A low molecular weight copolymer of vinylbenzyl chloride and butadiene was quaternized with N-dimethylaminoethylmethacrylamide. The resin was coated from water solution to give a photorelief plate which could be developed with water. A photocured protective coating on steel showed good toughness.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070230110
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  • 10
    Electronic Resource
    Electronic Resource
    Human interferon production with diploid fibroblast cells grown on microcarriers (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 21 (1979), S. 433-442 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A variety of diploid human fibroblast lines have been successfully grown to high densities (〉106 cell/ml) on recently developed microcarriers. Interferon induction using poly I·poly C and a superinduction procedure resulted in yields greater than 10,000 units/ml with one cell line. A direct comparison of microcarrier cultures to roller bottle cultures showed equivalent interferon yields on a per cell basis and some apparent differences relating to optimum inducer concentrations and kinetics of interferon accumulation.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260210306
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