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  • 2010-2014
  • 2000-2004  (57)
  • 1975-1979  (23)
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  • 2001  (57)
  • 1979  (11)
  • 1975  (12)
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 79 (1975), S. 2531-2535 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 79 (2001), S. 1118-1120 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report a reduction of inhomogeneous broadening in CdSe-related quantum wells in ZnSe by employing a growth technique that uses a CdS-compound source instead of the standard Cd elemental source for molecular-beam epitaxy. Assisted by the low sticking coefficient of sulfur and possibly an exchange reaction between S and Se, only a small S contamination is observed. A comparison with standard layers reveals an increase in quality and homogeneity by a strong reduction of the photoluminescence (PL) linewidth. Samples obtained by our method show extremely little lateral confinement as indicated by a lack of sharp single dot emission lines in micro PL and the absence of the extensive redshift observed in temperature dependent PL of fluctuating well potentials. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 1170-1177 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We measured absolute partial cross sections for the formation of various singly charged and doubly charged positive ions produced by electron impact on SiF4 from threshold to 900 eV using a time-of-flight mass spectrometer. Dissociative ionization was found to be the dominant process, although we found evidence of the presence of the SiF4+ parent ion in our experiment. The SiF3+ fragment ion has the largest partial ionization cross section with a maximum value of 4.3×10−16 cm2 at 90 eV. All other singly charged fragment ion cross sections are about one order of magnitude smaller at this impact energy. The cross-section values of the doubly charged ions with the exception of SiF2++ are about two orders of magnitude smaller. A comparison is made with available previously measured data. Additional measurements using a sector-field mass spectrometer revealed that all fragment ions are formed with excess kinetic energy. The experimentally determined total single ionization cross section of SiF4 is compared with results of semiempirical and semiclassical calculations and reasonable agreement is found. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science, Ltd
    Molecular microbiology 40 (2001), S. 0 
    ISSN: 1365-2958
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Medicine
    Notes: The diffuse adherence of Escherichia coli strain 2787 (O126:H27) is mediated by the autotransporter adhesin AIDA-I (adhesin-involved-in-diffuse-adherence) encoded by the plasmid-borne aidA gene. AIDA-I exhibits an aberrant mobility in denaturing gel electrophoresis. Deletion of the open reading frame (ORF) A immediately upstream of aidA restores the predicted mobility of AIDA-I, but the adhesin is no longer functional. This indicates that the mature AIDA-I adhesin is post-translationally modified and the modification is essential for adherence function. Labelling with digoxigenin hydrazide shows AIDA-I to be glycosylated. Using carbohydrate composition analysis, AIDA-I contains exclusively heptose residues (ratio heptose:AIDA-I ≈19:1). The deduced amino acid sequence of the cytoplasmic open reading frame (ORF) A gene product shows homologies to heptosyltransferases. In addition, the modification was completely abolished in an ADP–glycero-manno-heptopyranose mutant. Our results provide direct evidence for glycosylation of the AIDA-I adhesin by heptoses with the ORF A gene product as a specific (mono)heptosyltransferase generating the functional mature AIDA-I adhesin. Consequently, the ORF A gene has been denoted ‘aah’ (autotransporter-adhesin-heptosyltransferase). Glycosylation by heptoses represents a novel protein modification in eubacteria.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1434-6036
    Keywords: PACS. 74.72.Jt Other cuprates – 79.60.-i Photoemission and photoelectron spectra – 74.25.Jb Electronic structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: In recent years insight has been gained into the electronic structure of layered cuprates using angle-resolved photoelectron spectroscopy. In many of these studies it is assumed that the electron-photon matrix element follows the trends set by the atomic photoionization cross sections and does not influence lineshape, dispersion and the k-dependence of the spectral intensity. In this study using Sr2CuO2Cl2 as an example it will be shown that the electron-photon matrix element can have a strong impact on both strength and shape of a feature in an angle-resolved photoelectron spectrum of a layered cuprate which can strongly affect information on character and the momentum-dependence of the energy and spectral weight of a state deduced from the spectra. The results of this study put an emphasis on the need to employ the whole parameter range of the ARPES method to get reliable information on the spectral function of cuprates for which purpose synchrotron radiation is an uniquely suited tool.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 206-213 (Dec. 2001), p. 219-222 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Pharmacy world & science 1 (1979), S. 1443-1450 
    ISSN: 1573-739X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Für die Kompressionsgleichung (s − a) (p + b) = C wurden die drei Hyperbelkonstanten a, b, und C interpretiert und ihre Abhängigkeit vom Mischungsverhältnis zweier Substanzen untersucht. Die Grö\e b wurde als Verformungsspannung bezeichnet, sie kann mit der Flie\grenze eines Materials in Beziehung gesetzt werden. In einer Tablettenrezeptur kann der Anteil an verformtem Arzneistoff mit Hilfe der Konstanten b abgeschätzt werden.
    Notes: Abstract The three hyperbolic constants a, b and C were interpreted for the compression equation (s − a) (p + b) = C. Their dependence upon the mixture ratio of two substances was investigated. The quantity b was designated as deformation strain, it can be related to the yield point of a material. The proportion of deformed drug in a tablet formulation can be estimated by means of the constant b.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 452 (1979), S. 112-122 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Nucleophilic Degradation of Tris(pentasulfido)platinum(IV), [Pt(S5)3]2-, and Bis(pentasulfido)platinum(II), [Pt(S5)2]2-The behaviour of [Pt(S5)3]2-, (I), towards sulfite, arsenite, sulfide, hydroxide, and triphenylphosphine has been studied qualitatively and quantitatively. With stoichiometric amounts of nucleophile one ring is degraded; the reaction product [Pt(S5)2]2-, (II), can be isolated. With excess of nucleophile all sulfur atoms are taken off from the platinum; with triphenylphosphine, however, (PPh3)2PtS4, (III), is formed. A mechanistic interpretation of the course of the reaction is given and supported by kinetic studies.
    Notes: Das Verhalten von [Pt(S5)3]2-, (I), gegenüber Sulfit, Arsenit, Sulfid, Hydroxid und Triphenylphosphin wird qualitativ und quantitativ untersucht. Mit stöchiometrischen Mengen an Nukleophil wird ein Ring abgebaut; als Reaktionsprodukt kann [Pt(S5)2]2-, (II), isoliert werden. Mit Überschuß an Nukleophil werden alle Schwefelatome vom Platin abgelöst; mit Triphenylphosphin entsteht dagegen (PPh3)2PtS4, (III). Der Reaktionsablauf wird mechanistisch gedeutet und durch kinetische Untersuchungen erhärtet.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 454 (1979), S. 160-166 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Addition Compounds between Antimony(III)-Halides and 1,4-DithiacycloheptaneSbCl3, SbBr3, and SbI3 do form the addition compounds SbCl3 · 1,4-Dithiacycloheptane, SbBr3 · 1,4-Dithiaheptane and 2 SbI3 · 1,4-Dithiacycloheptane from benzene solutions. The new compounds are only stable in the solid form. FIR spectra of the SbCl3 and SbBr3 complexes are recorded as well as the X-ray structure of the SbCl3 compound.
    Notes: Aus benzolischen Lösungen von SbCl3, SbBr3 und SbI3 bilden sich mit 1,4-Dithiacycloheptan die nur in fester Form existenzfähigen Verbindungen SbCl3 · 1,4-Dithiacycloheptan, SbBr3 · 1,4-Dithiacycloheptan und 2 SbI3 · 1,4-Dithiacycloheptan. Die FIR-Spektren der SbCl3- und SbBr3-Addukte sowie die Röntgenstrukturanalyse der SbCl3-Verbindung werden mitgeteilt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 418 (1975), S. 208-216 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Some Substitution Reactions of Trimeric ThioformaldehydeTreatment of s-trithiane with n-butyllithium results in the formation of lithium salts of carbenium ions. Their reactions with the halo-functional compounds lead to mono- or multi-substituted trithianes besides lithium chloride.
    Notes: Die Behandlung von s-Trithian mit n-Butyllithium führt zu Lithiumsalzen von Carbanionen. Bei der Umsetzung mit den halogenfunktionellen Verbindungen CH3J. (CH3)3SiCl, (CH3)3GeCl, (CH3)3SnCl und (CH3)2SiCl2 reagieren diese unter Abspaltung von LiCl zu ein- oder mehrfach substituierten s-Trithianen.
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