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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 57-62 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The pyrolysis and combustion products of poly-(vinyl chloride) and those of some of its polymer, especially of vinyl chloride with vinylidene chloride, were analysed using gas chromatography and gas chromatography mass spectrometry. The toxic effect of the individual products on the human organism was evaluated and presumed total toxicity of the poly-(vinyl chloride) combustion products (0.3g PVC products per m3) was determined.
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  • 2
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 42-42 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 3
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 6
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 125-125 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 7
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 97-102 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Assesing the total potential fire hazard of modern interior surfacing of buildings requires a method which includes determination of smoke toxicity concurrently with fire and smoke production parameters. The Fire Propagation Box Test (British Standards Institution BS 476, Part 6) is a promising contender. It has been examined in the flaming mode as a method for evaluating smoke production concurrently with fire propagation indices for a range of surfacings, rather than resorting to a separate procedure by using fans with the same apparatus, as described in the former British Standards Institution Draft for relation to rate of burning the concurrent procedure is shown to be the more valied method.
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  • 8
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 52-56 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper discusses the relative merits of a number of flame-resistant fabrics. The information quoted draws heavily from a five year programme of research carried out on the subject by Lambeg Industrial Research Association. The fabrics concerned were made either from flame-resistant fibres or by flame-resistant treatment of fabrics. The textile problems which can arise in the production of these fabrics are considered and means of avoiding them suggested. Test methods for flammability are discussed briefly and the subject of toxic gases generated from flame-resistant materials in fire situations is introduced as an area which needs further study. The paper is essentially a situation report describing the present state of knowledge indicating gaps therein, the limitations of the fibres, fabrics and finishes available and hence areas for future work.
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  • 9
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new experimental method for studying the ablation, ignition and extinction of polymers exposed to flames and other ignition sources is presented. The technique is called the ‘Moving Wire Technique’. The polymer sample is carried on a wire support which is moved uniformity through the ignition source which is a flame in the example given. In the laboratory coordinate system, points along the path of the wire correspond to increasing residence time. The polymer combustion thus becomes a steady-state phenomena which can be studied at leisure with the improvements in precision associated with long time steady-state measurements. In addition to steady-state combustion, ignition and extinction transitions are observed whose onsets are sharp and can be accurately characterized in this system. In a favorable case, a reproducibility of a few parts per thousand is attained in determining critical ignition exposure times and extinction velocities. Results from initial studies of commercial Teflon® and poly-(vinylchloride) are presented. Measurements include critical ignition times and extinction velocities a function of free oxygen concentration. For poly-(vinylchloride), measurements are given of gas phase composition, mass loss of the polymer, and surface temperature of the polymer as a function of exposure time. A discussion is given of the relation of the results to other experiments and potential uses of the technique.
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  • 10
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 83-84 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 11
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A statistical study of fires in the United Kingdom involving the ignition of furniture and furnishings is presented. This paper examines the data for one year (1970). The analysis shows that in fires starting in furniture and furnishings the chance of a fatality is over twice that in other domestic fires. The majority of furniture fires involve upholstery or bedding and over 90% were started by smokers' materials, electric appliances, space heating or as the result of the activities of children or suspected arsonists. Eighty-five percent of the fatalities were found in the room of origin of the fire. Eighty per cent were overcome by smoke or toxic gases. Sixty percent of the fatalities were either under 5 or over 65 years of age. Monetary values are assigned for damage, casualties and deaths in fire. These costs can be used to assess the value of fire precautions. With the values taken, the total losses in furniture fires in the home amounted to £19 million in 1970. Life loss accounted for the major part of this sum. The expected annual loss per dwelling as a result of the ignition of furniture is thus only about £1, and is only £3 for all dwelling fires. This low figure suggests an approach of either selective spending on those most at risk (the elderly and handicapped) or by government activity through publicity and education.
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  • 12
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 85-89 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The chemical mechanisms for the action of flame retardants are often mentioned in the literature but the physical modes of action are seldom. Discussed. This article presents one way to quantify their efficiency. The technique is based on literature data for the physical and thermal properties of flams retardants for temperatures from 25°C up to 1000°C. The prolongation of the time to ignition by heat absorption by the retardant and the amount of inert gas evolved by the retardant are calculated at a given radiation for a material flame-proofed with a given amount of the flame retardant. The ability to form an insulating surface layer is considered but not quantified. It is assumed that a medium density wood fibre building boards is treated with 2 kg of flame retardant per m2. The flame retardants included are borates, boric acid, phosphates and silicates. The board is assumed to be irradiated with an intensity of 15 k W m-2. Under these conditions an untreated board ignites after 6-7 min. The time to ignition is prolonged by 1-5 min through heat absorption by the different retardants, and the amount of inert gases evolved may be as high as 2.6 m3 per m2 board. The formation of an insulating surface layer is more difficult to quantify. The results confirm the importance of the physical modes of action of flame retardants and the technique could form the basis for evaluating materials in simulated fire situations.
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  • 13
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 103-115 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Stress-strain behaviour of concrete at elevated temperatures is extremely complex and is not completely understood up to now. The creep properties of concrete at temperatures up to 300°C thus need to be determined, as well as the thermal stability of concrete during repeated cycles of heating and cooling. In this report the results of recent high temperature experiments with normal concrete specimens are presented. The main objectives of the tests were to investigate the dependence of strength and elasticity on temperature and to study the creep and deformation characteristics of concrete at temperatures up to 450°C. Transient creep data, i.e. data derived under transient temperature conditions, are compared with creep data which were measured at constant elevanted temperatures. The results suggest that transient creep values and steady state creep values in some cases may be of the same magnitude.The creep measurements appear to be in good agreement with data presented by other workers. However, the scatter in all data increases significantly with increasing temperature and differences of more than 100% can be observed. When loaded concrete specimens were cooled down to ambient temperature exptraordinarily large compressive strains can be observed. The experiments indicate clearly the considerable strain capacity of normal structural concrete can be used at temperatures higher than 100°C. In areas of high stress concentrations a tures. On the other hand, with respect to the whole structure it is necessary to limit the deformations. For a constant maximum temperature this can only be done by limiting the admissible stresses. The test results permit an initial estimation of maximum permissible stress and temperature values.
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  • 14
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 126-127 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 15
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 2 (1978) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 16
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 2 (1978), S. 102-109 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A limited review of the methods available for measuring smoke from burning materials has been carried out in order to define a method that could provide data for calculating smoke load. Results available in the literature have been expressed on a common basis and augmented by further experimental work carried out with a furnace similar to the National Bureau of Standards test furnace and a smoke-containment volume (13.4m3) closer to that used by the Fire Research Station test. Encouraging agreement between the data have been found for methods which allow smoke to become diluted and to accumulate. Agreement could be improved if an allowance was made for flaming being extinguished at different times in a test, dependent on thermal stress and oxygen concentration, even when a pilot light is present. To help express the results clearly, a new unit for smokiness is proposed - the obscura (ob) defined as 1 ob=1 dB light attenuation per metre of light path. The smoke-producing potential of different materials (Do) is then expressed in units of obscura - cubic metres per gram of volatiles produced during the fire condition (ob m3 g -1).
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  • 17
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 2 (1978), S. 122-131 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nitrogen-containing compounds such as hydrogen cyanide, acetonitrile, acrylonitrile, pyridine, benzonitrile, ammonia and methylamine, which are typical of the products likely to be encountered during the decomposition of nitrogen-containing polymers in fires, have been introduced into hydrogen and methane flames burning in oxygen-argon atmospheres. There is a complete conversion of fuel nitrogen in all cases to oxides of nitrogen and molecular nitrogen. The relative conversion to oxides of nitrogen (as NOx/N2) increases as the injection rate of nitrogen-containing fuels is decreased. The relative yields of oxides of nitrogen tend to be similar with methane and hydrogen premixed flames and markedly greater than observed with hydrogen diffusion flame. In all cases the yield of oxides of nitrogen-containing products such as hydrogen cyanide can also present a toxic risk during the burning of nitrogen-containing polymers, particularly when high temperature are involved. The combustion of these products in flame zones cannot be assumed to alleviate the additional toxic risk because of their conversion to oxides of nitrogen.
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  • 18
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. iv 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In order to evaluate the performance of the indices of toxicity which have been developed, thermal decomposition products of three polymers, polyvinylchloride, polychloroprene, and polycarbonate were tested for sensory irritation, physiological stress induction, and acute lethality. Each polymer has been contrasted with the same polymer containing 5% zinc ferrocyanide. The most irritating and the most stressful pyrolysis products were those from polyvinylchloride. The least irritation and stress were associated with polycarbonate decomposition products. The acute lethality for polychloroprene was higher than that of the other two polymers by a factor of 4. The addition of zinc ferrocyanide had a variable effect, depending on the polymer and the index of toxicity being evaluated. Sensory irritation was lessened by the presence of zinc ferrocyanide in polycarbonate. The sample weight required to cause death of 50% of the animals was reduced for the two hydrogen chloride-generating polymers, polyvinylchloride and polychloroprene. However, the acute lethality of polycarbonate did not change with addition of zinc ferrocyanide. By itself, zinc ferrocyanide decomposed very slowly during heating, caused almost no irritation or stress, and no deaths.
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  • 20
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 2 (1978), S. 173-176 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Various celloulosic materials were evaluated for ignitability and flash-fire propensity, using screening test methods developed at the University of San Francisco. Time to ignition, using radiation from a high-temperature radiant source without a pilot flame, appeared to be primarily a function of heat flux and material density, rather than of type of wood or celloulosic board. At heat flux levels from 5.8 to 10.5 W cm-2, time to ignition was shortest for cellulose fiberboard with a density of 0.2225 g ml-1, followed by western red cedar at 0.314 g ml-1, eastern white pine at 0.348 g ml-1, southern yellow pine at 0.422 g ml-1, Douglas fir at 0.565 g ml -1, and longest for hardboard at 0.878 g ml-1. For the cotton and rayon woven-pile upholstery fabrics, time to ignition appeared to increase with increasing fabric weight.For Cellulose insulation treated with boron-containing additives, flash-fire magnitude decreased with increasing additive content. Flash-fire magnitude decreased more that could be accounted for by decreasing weight loss alone, indication reduction in the combustibility of the volatiles produced. Reduction in flash-fire propensity of cotton bating by treatment with boron-containing additives was also observed.
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  • 21
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 2 (1978), S. iii 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 22
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Australian Children's Nightwear Standards have been accepted as the basis of legislation in all States of Australia and by the Commonwealth Government. The standards are based on the philosophy that garment design as well as combustion characteristics of the material is an important consideration in assessing the fire hazard of nightwear. Using this approach a classification system has been devised which place children's nightwear into three categories of potential fire hazard. If a garment cannot be classified then it cannot be legally sold in Australia. The combustion characteristics tested are ease of ignition, rate of flame propagation and surface burn properties. For classification all materials used for children's nightwear must pass the latter test. The design of the standard test methods, criteria for classification and the concepts of safe design were developed by collection data from burns accidents and burnt clothing from accident victims from the burns research unit of a large children's hospital and by the study of the burning behavior of clothing on a manikin. The combustion criteria are not so stringent as to require the use of inherently flame resist materials or the use of flame retardant finishes. This approach in combination with safe design criterial enable commercially available textiles to meet the legislative requirements for children's nightwear. This mean that the nightwear standards are inexpensive to attain and do not require a sophisticated textile technology. A consumer labeling system has been designed to describe the three categories but yet there is no evidence to suggest that this had had any effect in reducing the number of burns accidents - consumers apparently regrading safe nightwear as a low priority. An inconsistent aspect of the calssification system is the incorporation into the standards in 1977 of criteria to prevent the classification of cotton flannelette nightdresses and the incorporation of arbitrary requirements for other nightdress containing cotton. These inconsistencies have been caused fundamentally by a problem which continues to bedevil the writing of good standards in Australia - that is, the lack of nationwide statistics on burns accidents.
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  • 23
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    Fire and Materials 2 (1978), S. 132-135 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of halogen additives, containing bromine as one of the substituents (e.g. CF2CIBr, CF3Br), on the self-ignition of polypropylene has been investigated. These compounds appear to promote self-ignitionat low concentration and inhibit self-ignition at high concentration when introduced into the oxidant gas. The lability of bromine is thought to influence the limiting concentration above which these additives act as inhibitors. By comparison with other systems of oxidation the authors propose an explanation an explanation in which HBr and Br' radical species are the only active entities in all cases.
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  • 24
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Much of the information accumulated on the fire resistance of ‘dividing’ elements can be utilized in the design of buildings for fire safety, if the fire tolerance values are converted into fire resistance. Three methods of conversion, one based on the concept of equal temperature-time areas, the second on the concept of equal maximum temperatures, and the third, Law method, are critically examined and handy conversion tools presented. In the case of the ‘key’ elements of buildings, basing the fire safety design on fire resistance information is not recommended.
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  • 25
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    Fire and Materials 3 (1979), S. 1-7 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Numerical solutions of the post-flashover fire are considered and a computer program is presented. The solutions are compared with experiment and the sensitivity of the solutions to a number of variables is discussed. It is shown that increasing the ventilation may either increase or decrease fire intensity, and the importasnce of the ventilation controlled phase of the fire is discussed. Application of the model to calculate the expected time-temperature history is illustrated and its significance is discussed. The deterministic approach is compared with a new method for calculating the most severe fire by letting one variable take any value between certain limits. The latter method is called pessimization. The significance for designers is noted.
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  • 26
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    Fire and Materials 3 (1979), S. 238-242 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This note describes a digital circuit for the measurement of combustion intermittency in fire gases. The measurement has been achieved by analyzing the positive ion current drawn by an electrostatic probe immersed in the flow. The circuits used are modular in design so that signals from different types of sensor may be presented for intermittency analysis. Some results obtained in an unbounded diffusion flame are reported.
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  • 27
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    Fire and Materials 4 (1980), S. 45-49 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This study provides basic data with respect to pain and burns produced on short-term contact of bare skin with heated substances. The data may also be used to determine the thermal properties and thicknesses of fabrics or coatings required to prevent injury in such contacts. The maximum temperature any material might attain without causing injury on contact with bare skin was determined from measurements of pain threshold during contact with heated materials representing a wide spectrum of thermal properties form good conductors to good insulators. Pain threshold times were converted to blister times and the latter extrapolated to predict those temperatures at which blistering would result form ‘instantaneous’ (0.3 s) contact. The predicted temperatures were verified experimentally in contacts with four different materials. From these data, charts and equations were derived by which the maximum permissible temperature for safe contact could be determined for any material solely form a knowledge of its thermal conductivity, density and specific heat. Additionally, equations for transient heat flow in two-layer systems yield the thickness of coatings, fabrics or other thermal barriers of known properties which would be required to protect the skin form pain or burn on contact with materials at excessive temperatures.
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  • 28
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    Fire and Materials 4 (1980), S. 50-58 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The toxicological end-points used in a method for the assessment of the toxicity of combustion products are described. The evaluation considers three areas of toxicological interaction: incapacitation, death, and post-exposure involvement. The model of incapacitation described is the leg-flexion avoidance response of the rat. Additional end-points to assist in the determination of the causality of the observed toxicity are included. The effects of the combustion products of Douglas fir, a phenolic foam, a urea formaldehyde foam and a flexible polyurethane foam on these endpoint are described. The wide range of types of potential toxicities resulting form exposure of animals to the combustion products of materials is discussed. Additionally discussed are the relative merits of the leg-flexion avoidance response as a model of incapacitation. Conclusions as to the important components of a first-tier toxicological evaluation of combustion products are drawn.
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  • 29
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    Fire and Materials 3 (1979) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 30
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    Fire and Materials 4 (1980), S. 71-76 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Because language conveys the idea of fire severity by a single expression, it has always seemed desirable to find a single variable for its quantification. The earlier suggestion by the author that the total heat absorption per unit surface area of the compartment boundaries during the period of full fire development, to be referred to as overall heat load, be used as a measure of destructive potential of fires, has been critically examined. It has been found that for many reinforced and prestressed concrete building elements, the overall heat load is indeed an approximate descriptor of the severity of compartment fires, irrespective of their temperature histories.
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    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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  • 32
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    Fire and Materials 3 (1979), S. 132-139 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Fire Propagation Test (BS 476 Part 6) has been used with the discharge of combustion products into a small test room, to provide a fire hazard assessment of some polyvinylchloride floor covering systems, and includes measurements of fire propagation, smoke, CO and HCI production. Particular attention has been given to the change in the HCI concentration of the Room atmosphere during the test and the influence of relative humidity and the nature of the surface linings of the room. The results have been discussed as a contribution to the understanding of the role of HCI in toxicity of fire atmospheres. Some approaches for improving further the reproducibility of the test method are indicated and support is given to the Japanese proposal that such a test be standardized to enable comparison of fire hazard potential of lining systems used in buildings.
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  • 33
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    Fire and Materials 3 (1979), S. 154-155 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The toxic gases released by combustion/pyrolysis of wool include CO, HCN and four compounds containing sulphur. Animal test data suggest that the toxicity of the sulphur compounds is significant. Wool was pyrolysed and the gases were analysed by GC-MS. SO2 was the main sulphur-containing gas produced by flaming combustion in an oxygen-enriched atmosphere. In pyrolysis under various conditions COS was a major sulphur-containing product. Although it is a highly toxic gas, COS has not so far been reported by workers engaged in the toxicity of fire gases. It is suggested that analysis of COS be included in the analytical toxicology of sulphur-containing polymers.
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  • 34
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    Fire and Materials 3 (1979), S. 156-166 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Protective clothing against head and flames should be evaluated not only for flame retardance but also for protection against various heat exposure from convection (flames), conduction (molten metal splashes) and radiation sources, depending on the end use, to ensure a realistic assessment of the potential protection offered and required. Evaluations of various flame-retardant fabrics to different heat exposures showed that the fibre and the flame retardant finish should preferably form a well developed char on exposure to heat, without softening and melting. The flame retardant should act in the solid phase and the fibre should be of low thermal conductivity. For protection against convective heat (flames), a woven Zirpro wool fabric of high density over a bulky knitted Zirpro wool underwear fabric offered a significantly better protection than a single layer of a woven or knitted fabric or a double layer of a woven fabric of the same total weight. The optional multi-layer fabric approach could also decrease overall garment weight and improve wearers' comfort without adverse effect on the protection offered. Of the FR fabrics evaluated, Zirpro wool fabric assemblies showed the longest time to reach pain (first degree burn) and blister (second degree burn) thresholds, as well as the longest pain alarm time-the time available to the wearer to withdraw from the flame heat source before serious injuries occur. Zirpro wool fabric assemblies had one of the lowest residual heat transfers after al limited flame exposure to the pain threshold while some other fibres, e.g. aramid and novoloid, transferred significant residual heat, possibly causing second degree burns. For protection against conduction, such as from molten aluminium splashes, the fabric should have a smooth surface, high density and thickness, besides the other previously mentioned, basic requirements. Zirpro wool fabrics offered a significantly better protection in this case than aramid, FR cotton, glass fibre, asbestos, and other FR fibres. Aluminized fabrics are essential for adequate protection against radiant heat and the aluminization technique affects heat transfer significantly. A low density base fabric made from a fibre of low thermal conductivity, such as Zirpro wool, reduces heat transfer in this case.
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  • 35
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    Fire and Materials 3 (1979), S. 188-194 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This paper describes in some detail the sources of data on fires occurring in Australia with to their scope and reliability. Particular reference is made to the data published by the Fire Brigades Board of New South Wales for these are the most detailed and comprehensive published in Australia although limited to one State. Data are given on the number of fires, property loss, and deaths and injuries due to fires in Australia and on causes, occupancies, points of origin and extents of fires in New South Wales. Comparisons are made with United Kingdom and United States of America statistics where relevant data are available. In conclusion, some trends which indicate that better data should be available in the future are discussed.
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  • 36
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    Fire and Materials 5 (1981), S. 33-38 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fire test methods cited in Australian regulations codes and specifications and the authorities promulgating them are reviewed. The pertinent regulations are generally drafted and administered by departments of the seven State governments, in some cases in reference to model codes developed by committees supported by the federal government to promote uniformity. The test methods, specifications and codes of practice are standardized by the Standards Association of Australia, an independent body with no statutory powers: the standards become mandatory when called up in legislation. Building materials and structures, consumer products, certain electrical components and children's nightwear are the main areas concerned with regulations that invoke fire test methods. The intent of the regulations and the test methods are discussed with particular emphasis on matters unique to Australia.
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  • 37
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 38
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    Fire and Materials 4 (1980), S. 60-60 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 39
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Measurement of the rate of oxygen consumption provides a simple, versatile and powerful tool for estimating the rate of heat release in fire experiments and fire tests. The method is based on the generalization that the heats of combustion per unit of oxygen consumed are approximately the same for most fuels commonly encountered in fires. A measurement of the rate of oxygen consumption can then be converted to a measure of rate of heat release. Data on heats of combustion are presented to support this generalization. The applicability of the technique to combustion under fire conditions is examined, possible sources of error in the measurements are discussed, and applications of the method are reviewed. It is concluded that the accuracy of oxygen consumption based rate of heat release measurements should compare favorably with those derived from conventional calorimetric measurements.
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    Fire and Materials 4 (1980), S. 66-70 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Results of measurements of thermal expansion of Portland cement paste, mortar, concrete and a dolomitic rock aggregate are presented. Test temperatures ranged from 27 to 871°C. Cement paste contracted when subjected to temperatures from 204 to 871°C. Thermal expansion of mortar and concrete was dominated by thermal expansion characteristics of the mineral aggregate. However, expansion was moderated by contraction of the cement paste matrix at elevated temperatures. Average coefficients of expansion, over specific temperature ranges, are given for the materials tested. Equipment developed to control automatically the rate of heating and record strain vs. temperature relationships is described.
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  • 41
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    Fire and Materials 4 (1980), S. 77-82 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Experiments using a thermobalance, a hot-plate and a moving furnace have all shown that polymers can evolve oxidation products in air even at moderate temperatures. These gases can include carbon monoxide, formaldehyde and acrolein. The amounts are generally low except near the very top of the temperature range used in some processes. Tests in the vicinity of three different extruders have confirmed some of these small-scale findings but also showed that the evolved gases were adequately handled by the ventilation installed. The evolution of other gases in certain cases has also been briefly studied. Some measure of the heat evolved in oxidative pyrolysis has also been obtained for polyethylene. The polymers investigated were low density and high density polyethylene, poly(ethylene vinylacetate), polypropylene, poly(vinylonitrille) polypropylene, poly(vinylchloride), polystyrene, poly(methylmethacrylate), polycarbonate, poly(ethylene terephthalate), nylon 6-6, acrylonitrile/butadiene/styrene and one nature material (wood).
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    Fire and Materials 4 (1980), S. 92-97 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Considerable concern has been expressed about the increasing number and changing pattern of fires and the fact that modern upholstered furniture is relatively easy to ignite and, once ignited, burns rapidly to produce large quantities of smoke and toxic gas. This led to a number of major research programmes and to the evolution of a number of test procedures in the UK. The first major test procedure was published in 1976 by the BPF in conjunction with RAPRA, BRMA and FIRA. An important aspect of this approach was the linking of ignition and rate of initial burning data with the application of the product and the environmental hazard. It was evolved within a short period of time to proved furniture designers and specifies with a means of avoiding products of high risk. The DOE/PSA are using a comprehensive series of Fire Retardant Specifications to control and specify their upholstered furniture and bedding. Specifications have been developed which enable individual components and sub-assemblies as well as the final product to be characterized in terms of ignitability and burning characteristics, i.e. temperatures, smoke, and carbon monoxide production. BS DD58 and BS 5852 Part1, ignitability tests for upholstered seating are essentially a combination of BPR and DOE/PSA test procedures. Cigarettes, gas flames and wooden cribs are used for the ignition sources and are positioned on a composite seat/back test rig.
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    Fire and Materials 5 (1981), S. 163-174 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The results of applying the tentative, high temperature, International Standards Organization test methods DP 5925 Part 3, which was developed to measure smoke leakage of door assemblies during the course of a standard fire endurance test, are reported. A critical analysis reveals that the basic objective of the test method is limited in its utility in that fire scenarios in high-rise buildings may not be adequately simulated. Independent of this limitation, the analysis then identifies certain theoretical problems with the test method and its procedures. These lead to a conclusion that the test method is not generally reliable. An alternative test concept which appears to remove this limitation and all of its problems is described, and its development is advocated.
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    Fire and Materials 5 (1981), S. 179-179 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 5 (1981), S. iii 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 6 (1982), S. 10-12 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Thermal analysis and limiting oxygen index flammability tests were used for elucidation of details in phosphorous-nitrogen synergism in cotton modified with methylol phosphonopropionamide and subsequently hydrolyzed by acid. The results indicate that not all the phosphorus incorporated into the material is effective for flame retardancy purposes in the condensed phase. The comparison of modified and acid hydrolyzed cotton has shown the important influence of nitrogen in the structure of the flame retardant. A simplified theory of nitrogen-phosphorus synergism, considering this influence, is proposed.
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    Fire and Materials 6 (1982), S. 23-26 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: An apparatus has been designed and a procedure adopted for studing the oxygen index of materials over a range of pressures. It has been found that the oxygen index falls with increase in pressure so that materials become more flammable, the effect being more marked with the less flammable materials. An empirical method has been devised for predicting the oxygen index at varying pressures.
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    Fire and Materials 6 (1982), S. 32-37 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Concentrations of elements were determined in tracheal specimeans of fatal fire casualties and of non-fire fatalities. Elevated concentrations of antimony, bromine, zinc, chromium, cobalt, iron, lead, cadmium and gold found in the group exposed to the fire environment were associated with deposition of soot. The presence of raised concentrations of antimony in fatalities was found to occur in association with increased content of carboxyhaemoglobin in blood and was greatest in fires involving major destruction of property. A relationship between the increased concentration of this element and the use of antimony containing fire-retardants in construction materials could not be demonstrated.
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    Fire and Materials 4 (1980), S. 185-191 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: In this paper the definition of heat release rate in fires is given in terms of heat of combustion and mass loss rate of the fuel. Various components of the heat of combustion are defined. The dependency of heat of combustion components and mass loss rate on factors such as fire stages, oxygen to fuel ratio, heat flux received by the fuel, chemical composition of the fuel vapors and products are enumerated. Applications of heat release rate data for relative fire hazard of fuels, for various fire conditions, for human escape potential from fires and for the operation of fire-sensing devices are discussed.
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    Fire and Materials 4 (1980), S. 192-200 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The activities within the framework of TNO's research project on smoke problems in buildings on fire are reviewed. Two aspects will be dealt with extensively: smoke production and smoke movement. Furthermore, possible application of its finding will be discussed. The article reflects the state of the art at the end of 1978. In the meantime, the research programme has been concluded.
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    Fire and Materials 6 (1982), S. 59-64 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The theromo-oxidative decomposition, flash ignition and burning of high-impact polystyrene containing the flame-retardant system decabromodiphenyl oxide + antimony trioxide was investigated using the Setchkin apparatus combined with mass spectrometry. The time dependences of the release rate of the main products into the gas phase during decomposition and burning showed that the flame-retardants markedly influence these processes. It was found that the retardants used exhibit an acceleration of the polymer degradation and that the efficiency of inhibition in the gas phase depends on the atomic ratio antimony: bromine.
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    Fire and Materials 6 (1982), S. 68-71 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The development, construction, and testing of a gas-fired radiant heat source for use as part of a fire test method is described. The unit has been shown capable of operation over extended periods at surface temperatures yielding radiance corresponding to that of a black body at 935 °C. This permits a 60% increase of specimen irradiance over that possible with a burner previously used, without modifying the specimen-burner configuration factor. One such application of this burner allows operation with specimen irradiance levels at 5 W cm-2 or for short periods at levels approaching 7 W cm-2 at higher temperatures. This performance is achieved while maintaining effective spatial separation between specimen and heat source. This assists in avoiding imposition of vitiated air near the surface of a burning specimen. Some performance data are provided on its behavior when supplied with natural gas. The unit can burn propane but only with a significant reduction of thermal output.
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    Fire and Materials 6 (1982), S. 98-98 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 5 (1981), S. 77-84 
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    Notes: For building control purposes of wall-lining and flooring materials in Europe several empirical reaction to fire tests are used. This paper examines the correlation between a number of different tests looking at some 42 different materials, and comments thereon.
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    Fire and Materials 5 (1981), S. 85-85 
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    Fire and Materials 5 (1981), S. i 
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    Fire and Materials 5 (1981), S. 153-162 
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    Notes: Ignitability, one of the new fire test methods for building materials developing within the International Standards Organization is compared with the national fire test methods in Austria, Britain, France, Germany and Scandinavia. Different commercial wood-based panels have been tested, including fire retardant treated panels. The International Standards Organization ignitability test measures the time to ignition at radiation intensities from 1 to 5 Wm -2; it seems to be able to distinguish between different materials in an intelligible way. An evaluation of the results of this ignitability test is discussed. One possibility which is proposed here is to calculate the mean time to ignition at different fixed radiation intensities; such a mean value simplifies the evaluation and takes into account all the test data. Agreement with the national fire test methods is rather low, since they partly measure other fire parameters; agreement with the Austrian Schlyter method, which also evaluated ignitability, is somewhat better and agreement between the national fire test methods is relatively good for wood-based panels. This is consistent with earlier experience, which has shown that mainly new types of materials behave differently according to different national test methods.
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    Fire and Materials 5 (1981), S. 180-181 
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    Fire and Materials 6 (1982) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 6 (1982), S. 13-15 
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    Notes: Thermal degradation products of nitrogen-containing polymeric materials were analysed for hydrogen cyanide. A spectrophotometric method was used for the determination of cyanides using the formation of a characteristic absorption peak of cyanonickel(II) ion in the ultraviolet spectral region. Pyrolysis and thermooxidation products were studied and conclusions on the reproducibility of the degradation process were drawn. The effect of temperature on the quantity of hydrogen cyanide formed was studied as well.
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    Fire and Materials 5 (1981), S. 177-178 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 6 (1982), S. 7-9 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The thermal behaviour in air of lignins modified by chlorophosphazenes as well as that of the raw materials of lignins has been investigated using thermogravimetry (TG), derivative thermogravimetry (DTG) and differential thermal analysis (DTA). The thermogravimetry and derivative thermogravimetry studies of lignins modified by chlorophosphazenes have shown their thermal resistance to be relatively higher than that of the intital raw materials of lignins in concrete kraft lignin and sodium ligninosulfonate. The differential thermal studies have demonstrated that the thermal degradation of products investigated takes place via exothermic processes. The lignins modified by chlorophosphazenes have been shown to be thermal and flame-resistant materials.
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    Notes: The combustion of polypropylene flame-retarded by the synergistic action between Sb2O3 and bromine-containing flame retardants has been studied. From the relationship between a number of the variables, a parameter quantatively reflecting the flame retardant effect has been found. With the addition of flame retardant, the rate of weight loss, the CO and CO2 emission rates and heat release all decrease while smoke density increases. These effects were considered to depend on the concentration of HBr gas in the pyrolysates released into the gas phase (i.e., dWHBr/dW, HBr flux ensity), and the following equations were obtained: \documentclass{article}\pagestyle{empty}\begin{document}$$ \frac{1}{W_0}\left(\frac{\rm d{W}}{\rm d{t}}\right)_{\max} \propto\left(\frac{\rm d{W_{HBr}}}{\rm d{W}}\right)^{-0.64}\quad\quad {\rm and}\quad\quad\eta^{\rm *} =\frac{W_{\rm[C], CO + CO_2}}{W_{0[\rm C]}}\,\propto \left(\frac{\rm d{W_{HBr}}}{\rm d{W}}\right)^{-0.37} $$\end{document} η*(dW/dt)max, which approximately corresponds to the oxidation velocity of pyrolized hydrocarbon, is inversely proportional to the HBr flux density. As the conversion of CO to CO2 was almost independent of the amount of flame retardants added, the flame retardant effect of bromine-containing flame retardants was considered to be a retardant effect of the initial oxidation reaction at the gas liquid interface. Moreover, η* is almost proportional to the combustion efficiency η, which was obtained from the heat release measured in the flaming region. The heat release is therefore considered to be governed by the HBr flux density.
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    Fire and Materials 6 (1982), S. 38-41 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This study was performed to establish the appropriate moisture level for textile flammability test specimens. Three investigations were carried out: into the effect of the level of humidity in dwellings; into the moisture content of garments worn at various distances from the body; and into the effect of relatively short exposures to heat on the moisture content of fabrics (simulating the case of a person standing in front of an open fire or space heater). The moisture content of ambient air in dwellings was found to be primarily governed by the moisture content of the air outside and can be quite low, ten to twenty percent, especially in winter (unless, of course, humidifying equipment is used). The moisture content of garment parts which are at some distance from the body (e.g., the loosely fitting parts of skirts) is governed by the relative humidity of the room. Closely fitting parts are more likely to be exposed to ignition sources than closely fitting parts. Fabric specimens exposed at a short distance from an electric space heater had moisture contents similar to specimens which has been oven-dried and cooled in a desiccator. The results of these studies indicate that oven-drying is a reasonable conditioning requirement for testing the flammability of apparel and home furnishing fabrics.
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    Fire and Materials 6 (1982) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 6 (1982), S. 76-79 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: In making fire safety decisions the designer often finds that some input variables concerning his problems are chance variables. As detailed statistical data are rarely available the designer must rely largely on his expert judgment. With the application of the Delphi method such decisions can be optimized and formalized. The essence of the Delphi method is described and its use illustrated through an example related to the assessment of fire resistance requirements.
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    Fire and Materials 6 (1982), S. 80-95 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: NBS burned eleven mattresses made up with bedding in two different rooms, typical of a residential bedroom and a nursing home patient room, respectively. Seven of the mattresses flamed and burned vigorously, the other four were of a construction or so heavily flame-inhibited that they only smoldered. The burning behavior of the seven that flamed was modeled with the Harvard Mark V fire simulation. The experimental burn behavior for tests conducted in one room was well reproduced using only total weight of combustible, surface area and heat of combustion. Smoke production values were found to have little effect on the predicted behavior except for the smoke production itself. Fires in a second room, whose ventilation was intentionally restricted by the configuration of the adjoining space, could not be as well reproduced by the present, single-room fire model. During this study several changes were made to the simulation. The most significant change was the inclusion of mixing of the hot exiting fire gases with the cold incoming air. As a part of this, the inter-layer radiation exchange was reformulated to include the effect of smoke contamination of the lower layer. The reformulation of the radiation model has a marked effect on the predicted upper layer gas temperatures, generally improving the quality of the simulation.
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    Fire and Materials 6 (1982) 
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    Fire and Materials 6 (1982), S. 119-121 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Melamine orthophosphate crystals vary in shape and formula according to their method of production. The types vary widely in their behaviour when incorporated into an epoxy resin intumescent coating for trials in a small scale fire test. Heat treatment of melamine phosphate crystals at 210 °C, a process designed to reduce their solubility, profoundly affects the performance of any crystal type in a fire test. In such cases crystal shape alone appears to determine performance, whereas the shape, formula, and state of agglomeration affect performance in coatings produced with untreated melamine phosphate. Small plates of side 20 μm heat treated at 210 °C, are the preferred type for optimum performance and weathering characteristics.
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    Fire and Materials 6 (1982), S. 145-160 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An extensive review is presented demonstrating the nature of comparison between full-scale fire smoke data and test method results for materials. These correlations are presented in terms of consistent parameters established through a development of the governing equations for smoke concentration and light attenuation. Visibility data limited to light transmission through smoke are also presented. The complex dependence of smoke production on many parameters acting in fire growth limits the success of simple correlation methods. Recommendations are made for further research to establish a sound basis for correlations, and the prediction of smoke obscuration due to fire.
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    Fire and Materials 7 (1983), S. 38-40 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 7 (1983) 
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    Fire and Materials 6 (1982), S. 135-144 
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    Notes: A mathematical Model for estimating the time available for safe egress from a fire is formulated. The model simulates the conditions which develop during the course of an enclosure fire. Since life safety considerations are primary, the simulation model which is adopted focuses attention only on phenomena which develop between the times of fire ignition and onset of hazardous conditions. This allows significant simplifications in modeling which may not be otherwise justified. Using computed variables of a simulated fire scenario of interest, times of fire detection and onset of hazard which are deduced from realistic detection and hazard criteria would be estimated. The Available Safe Egress Time (ASET) would be defined as the length of the time interval which separates these two events. Quantitative specifications for a variety of detection and hazard criteria are identified. Results of exercising the model are presented, and ASET estimates are obtained for a wide variety of realistic fire scenarios. A comparison between experimental results of a multi-room fire test and prediction of the single-room model suggest that the model has potential utility in providing practical simulations of multi-room fire environments.
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    Fire and Materials 7 (1983), S. 1-24 
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    Notes: This review concerns the mathematical modeling of fire phenomena. The fire is treated as a head and mass source driving a fluid flow process. Combustion is not included. It deals in detail with the field modeling approach incorporating the effects of turbulence, strong buoyancy and variable density on the transport of momentum, heat and mass. For the sake of simplicity, other effects such as those due to the interactions of the above mechanisms with the wall, radiation, etc., which may be crucial to the dynamics of the fire phenomenon, are not dealt with in this review. These effects will be the subject of future work.
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    Fire and Materials 7 (1983), S. 32-37 
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    Notes: Raman scattering is a possible technique for analysing gas mixtures. In the work here described Raman scattering was used for detection of gases extracted from different model fires, where wood, polymethylmetachrylate (PMMA) and polystyrene were used as test materials. Raman spectra of gas samples from differently ventilated model fires are presented as well as the variation of O2, CO2 and CO concentrations as a function of time with an effective time constant of less than 5 s. The sensitivity of the experimental set-up was estimated to be about 1000 ppm, but suggestions are given how to reach a detection limit of about 1 ppm. The feasibility of the technique and various ways of improving it are briefly discussed.
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    Fire and Materials 7 (1983), S. 49-61 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fourteen mathematical models of post-flashover compartment fires are classified on the basis of fourteen principal modeling aspects. Expressions are presented for the potential of fire to spread by destruction and convection. The assessment of the fire resistance requirements for the compartment boundaries is discussed and measures to counter the potential of fires to spread by convection are outlined.
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    Fire and Materials 7 (1983), S. 119-122 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A method is described by which the UK Upholstered Furniture (Safety) Regulations of 1980 may be complied with. By coating the surface of flexible polyurethane foam with vinylidene chloride copolymer latex, a fire retardant surface is obtained. This enables most fabric/foam combinations to pass both the cigarette and the match tests as laid down in BS5852. The coating process can be carried out with a brush, a roller or by spraying. Drying can be at room temperature or by using heat and/or a forced draught. Using about 350 gm-2 only certain deep-pile fabrics fail, and even hen additionally back-coating them with PVDC can ensure compliance. The presence of thin wadding or stockingette makes no difference, but thick wadding will burn with the fabric for more than the mandatory two minutes without setting fire to the PU foam. Fabrics successfully tested with the coated PU foam include cottons, polypropylene, acrylic, polyester and ‘Dralon’. After 80 000 indentations in a standard test the coating was still effective, as it was also after heating in a detergent for 4h.
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    Fire and Materials 7 (1983), S. 150-156 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A device constructed and used to determine the flammability limits of pyrolysate-air mixtures as a function of percentage weight loss on pyrolysis has been employed to investigate the pyrolysate gases generated from poly (ethylene terephthalate) both in the presence and absence of chemical flame retardants. The chemicals tripropyl phosphate (TPP), dibromopropanol (DBP) and tris (2, 3 dibromopropyl) phosphate (TRIS) all influenced both the lower and upper flammability limits, with the largest effects being obtained when both phosphorus and bromine were present, followed by bromine only and then phosphorus only. The results indicate TPP has negligible condensed phase activity with only small gas phase action. DBP has no condensed phase activity but is a very active gas phase inhibitor. In contrast, TRIS has a detrimental effect upon the condensed phase reactions in that it is responsible for the formation of a more flammable pyrolysate gas mixture. Fortunately, its gas phase inhibition reaction is capable of reducing the overall flammability.
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    Fire and Materials 7 (1983) 
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    Fire and Materials 7 (1983), S. 180-184 
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    Notes: Flammability tests are difficult because of the complexity of burning processes and of safety considerations. Experimental fires only give a partial view of the combustion process. Owing to the dynamic processes occurring in the flame, tests are very sensitive to external influences. Use, therefore, of flammability test methods should be made only with a clear understanding of what is being tested. Only officially standardized and recognized test methods should be sued.
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    Fire and Materials 7 (1983), S. 193-201 
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    Notes: Fire retardants improve reaction to fire characteristics such as ignitability and flame propagation. This paper presents the toxicological results of tests performed on eleven pairs of untreated and treated materials, including woods, synthetic materials and textiles (both natural and synthetic). It is shown that the effects of fire retardants on toxicity results can be variable. In addition, the problem of the use of toxicity results is discussed more generally.
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    Fire and Materials 7 (1983), S. 210-215 
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    Notes: A Preliminary study of the thermal degradation of wool fabric was carried out under a wide range of oxidative degradation conditions including flaming combustion. Product collection methods and analysis conditions were designed to minimize secondary reactions. The degradation products obtained included a variety of organic nitriles and heterocyclic compounds as well as the usual aromatic and oxygenated products. Variations in moisture content and fire retardant level in the wool had little effect on the organic volatiles produced form the fabrics.
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    Fire and Materials 9 (1985), S. 30-35 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Smoke-obscuration of monochromatic (0.632μm) light helium-neon lasers and of broad-band continuum light a hot tungsten filament is reported. The effect of forward-scattered light is evaluated for the monochromatic source, and the degree to which the Bouguer law is obeyed for a non-monochromatic source is discussed. Practical experience with both small-scall and fire experiments is described.
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    Fire and Materials 9 (1985) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 9 (1985), S. 75-80 
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    Notes: Traditional material-flammability tests are discussed in terms of their empirical foundation and oversimplified interpretation of fire phenomena. More recent rate of heat-release tests overcome some of these problems by measuring a material's response to different levels of fire exposure. However, no existing small-scale tests are sensitive to the radiant emission from the material's own flames. This radiant emission controls large-scale fire hazards. As a result, existing flammability tests canot be xpected to adequately characterize large-scale hazards. Some new approaches to this problem are discussed and a specific bench-scale test method is suggested which may overcome the identified problems of existing test methods.
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    Fire and Materials 8 (1984), S. 55-56 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 8 (1984) 
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    Fire and Materials 8 (1984), S. 69-76 
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    Notes: Some examples of the application of fire tests to hazard and risk assessment and some of the problems to be encountered are described. Reference is made to theoretical studies designed to show how to obtain basic data on material properties from ignitability and flame spread tests, and recent correlations of the rate of heat release required to cause flashover are presented. Progress in predicting fire growth from theory for certain idealized conditions will increasingly condition the choice of which processes shall be the subject of tests.
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    Fire and Materials 8 (1984), S. 54-55 
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    Fire and Materials 8 (1984), S. 57-63 
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    Notes: Laboratory tests have been developed that evaluate realistically the protective performance of clothing materials and garments. Test conditions are chosen to stress the high temperature resistance of materials in the same manner as in an industrial flash fire exposure. A second degree burn in human tissue is used as the criteria to ate performance of materials. Test results have been correlated between the small-scale lab swatch test and a full-scale instrumented manikin garment test, and these results related to industrial experience. The TPP lab test has been found useful in evaluating the performance of candidate materials as replacement for existing materials with known acceptable protective performance. It can be used to specify the level of protection needed in a garment when the intensity of the exposure hazard is known. Also, the test is especially useful for developing new materials and selecting candidates for additional field testing.
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    Fire and Materials 8 (1984) 
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    Fire and Materials 8 (1984), S. 96-104 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: ‘Normalized heat load’ is a quantifier of the destructive potential of fires, real-world compartment fires and test fires alike. For real-world fires it is subject to some uncertainties owing to the random nature of two of the variables it depends on: ventilation and fire load. For test fires also it is subject to uncertainties owing to a moderate degree of randomness that characterizes the results of test fires. A procedure is described for predicting the failure probability in fire of the boundaries of a compartment designed for fire resistance on the basis of information concerning the characteristics of the compartment and the design value of the fire load. The procedure is essentially deterministic, employing statistical considerations only as far as required by the nature of some of the input variables. With the aid of second-moment analysis, it is possible, furthermore, to design the compartment boundaries for appropriate target failure probabilities.
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  • 94
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    Fire and Materials 8 (1984), S. 113-124 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The general nature of fire problems on energy-conservative passenger trains is described, including a description of vehicle structures and lightweight design. Effects of high energy demand, tunnels and high maximum speeds on fire safety are outlined. The considerations used in design analysis are described, beginning with the development of a ‘worst-case fire scenario’. Typical combustible materials are considered and some of the reasons for choices are given. Notes on cavity and chimney effects emphasize the importance of clear objectives. Structural fire resistance is examined, and the basis of conventional recommendations analysed. The application of British Standard 6336 guidelines on fire tests and hazard assessment is examined. Limitation of fire load density is described, and some problems of calorific value determination outlined. Sources of ignition and hazards from passengers are defined. Flammability and flame-spread control are discussed, and rate of heat release is referred to in the context of fire behaviour. Problems of passenger escape linked to flashover, smoke and combustion gases are dealt with briefly.
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  • 95
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    Fire and Materials 8 (1984), S. 125-136 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: ‘Oxygen Index’, ‘Rate of Burning and Extent of Burning of Self-supporting Plastics in a Horizontal Position’ and ‘Vertical Flammability’ tests were used for examination of polypropylene copolymer HW 607M and the same copolymer filled with 40% w/w calcium carbonate. Room-scale studies were also carried out using a range of standard ignition sources. In the latter tests, measurements of the levels of smoke generated in the test chamber were monitored continuously, and intermittent measurements were made of the carbon monoxide concentrations. Small-scale testing showed that addition of the filler to the polypropylene raised the limiting oxygen index of the polymer from 17.8 to 20.3, which is only marginally lower than the oxygen concentration in ambient air (20.9); this introduces the possibility of a filled polypropylene which is not ignitable in air. However, the results of the UL94 and ASTM D635 tests did not show significant differences in flammability and rates of vertical and horizontal flame spread as between the two materials, through the unfilled polymer produced extensive burning droplets early in both tests whilst the filled polymer did not. Such droplets can spread fires to floor coverings, so that the filled plastic might be preferable in application. In our laboratory tests, the filled samples gave considerably lower smoke generation than the unfilled ones. At high heat fluxes they generated considerably less smoke than (smaller) unfilled samples containing the same mass of polymer. This suggests that the calcium carbonate has specific smoke-suppressant activity and is not merely acting as a polymer diluent. In larger-scale tests, unfilled samples were readily ignited by a domestic match, whilst the filled samples required an ignition source of 43 kJ (some six times greater than the match source) in order to light them and sustain ignition. The filled polymer did not melt on ignition and there was no lateral spread of flame from the sample. Smoke generation was considerably lower, the average optical density at maximum obscuration being 0.27, compared with 0.84 for the unfilled control. In particular, smoke suppression achieved by use of calcium carbonate at higher heat-flux levels is considerably greater than that expected for an inert diluent.
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  • 96
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 8 (1984), S. 172-173 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 1 Ill.
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  • 97
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    Fire and Materials 8 (1984), S. 175-175 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 98
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 8 (1984), S. 177-182 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The use of Critical Oxygen Index testing columns in the horizontal configuration is investigated. Gas analysis results from within columns of simple design indicate that they are unsuitable for burning studies because of entrainment of the external atmosphere and recirculation of combustion products. A new design of column and holder is proposed that eliminates these effects and provides a possible means of studying small-scale horizontal combustion in different oxygen/nitrogen mixtures.
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  • 99
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    Fire and Materials 9 (1985), S. 88-94 
    ISSN: 0308-0501
    Keywords: toxic gas ; smoke ; fire performance ; fire tests ; linings ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No standard method has been developed for measureing the evolution of specific toxic gases from building lings when involved in fire. The British Fire Propagation test (BS 476 Part 6) operated in an instrumented room has been proposed for this purpose previously but has not found general acceptance. It is considered further in this report, which investigates the movement and measurement of smoke and specific fire gases under different conditions of room stirring and the effect of the latter on fire propagation indexes. Stiring has been found to have no statistically significant effect on fire propagation indexes provided that the effects of this on calibration of the apparatus are taken into account. Stirring also had little effect upon smoke production per se. Under unstire conditions smoke and toxic gases stratify in the same layer early in the test, and measurement of their production at any single room location will be subject to the location, the way the room influences stratification and how the room is instrumentee, as well as by the prpduct performance. Under stirred room conditions smoke and toxic gases are evenly distributed and product performance can be assessed more simply from concurrent measurements of fire, smoke and toxic gas parameters. The latter procedure is proposed for obtaining relative data on building linings and for examination in further studies for correlation to room and corridor burns.
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  • 100
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    Fire and Materials 10 (1986), S. 47-55 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This theoretical and experimental study, complementary to that discussed in Reference 1, examines those factors that affect the ‘test efficiency’ in fire resistance testing. Convective heat transfer in the test chamber may become an essential part of the heat transmission process if, due to small furnace size or non-luminous furnace gases, the radiative transmission is not sufficiently intense. The standard technique of measuring and controlling the temperature conditions in the furnace chamber, though not in line with strict scienctific practices, appears to provide insurance against poor test result. A calibration procedure is described for checking the adequacy of fire resistance test facilities and some solutions presented for improving the test efficiency.
    Additional Material: 9 Ill.
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