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  • Articles  (118)
  • heavy metals  (118)
  • Energy, Environment Protection, Nuclear Power Engineering  (118)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Environmental Pollution 86 (1994), S. 83-88 
    ISSN: 0269-7491
    Keywords: Manila Bay ; heavy metals ; historical trend of pollution ; marine sediment ; riverine sediment
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 2
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    Amsterdam : Elsevier
    Environmental Pollution 83 (1994), S. 341-349 
    ISSN: 0269-7491
    Keywords: Antarctica ; distribution ; heavy metals ; inter-metal correlation ; seals
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 3
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    Amsterdam : Elsevier
    Environmental Pollution 84 (1994), S. 131-138 
    ISSN: 0269-7491
    Keywords: air pollution ; bioindicators ; element ratios ; geochemical relations ; heavy metals
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 4
    Electronic Resource
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    Springer
    Biodegradation 3 (1992), S. 161-170 
    ISSN: 1572-9729
    Keywords: bioremediation ; cadmium ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Cadmium pollution arises mainly from contamination of minerals used in agriculture and from industrial processes. The usual situation is of large volumes of soil and water that are contaminated with low — but significant — concentrations of cadmium. Therefore, detoxification of the polluted water and soil involves the concentration of the metal, or binding it in a way that makes it biologically inert. Cadmium is one of the more toxic metals, that is also carcinogenic and teratogenic. Its effects are short term, even acute (diseases like Itai-itai), or long term. The long term effects are intensified due to the fact that cadmium accumulates in the body. This paper describes a study involving several hundred cadmium-resistant bacterial isolates. These bacteria could be divided into three groups—the largest group consisted of bacteria resistant to cadmium by effluxing it from the cells. The bacteria of the other two groups were capable of binding cadmium or of detoxifying it. We concentrated on one strain that could bind cadmium very efficiently, depending on the bacterial biomass and on the pH. This strain could effectively remove cadmium from contaminated water and soil.
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  • 5
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    Springer
    Biodegradation 9 (1998), S. 311-318 
    ISSN: 1572-9729
    Keywords: glucosinolates ; gypsum ; heavy metals ; phyto-extraction ; phytoremediation ; sulfate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Sulfur is a major nutrient for all organisms. Plant species have a high biodiversity in uptake, metabolization and accumulation of sulfur so that there are potentials to use plants for phytoremediation of sulfur-enriched sites. A survey of soils enriched with sulfur either naturally or by human activities shows that a surplus of sulfur is mostly accompanied with a surplus of other chemical elements which may limit phytoremediation because these co-occurring elements are more toxic to plants than sulfur. In addition, the accumulation of the other elements makes the plant material (phyto-extraction) less suitable for the use as fodder and for human consumption.
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  • 6
    ISSN: 1572-9729
    Keywords: bioremediation ; heavy metals ; metal availability ; organic matter ; pyrite ; sulphide oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A field experiment, lasting 14 months, was carried out in order to assess the effect of organic amendment and lime addition on the bioavailability of heavy metals in contaminated soils. The experiment took place in a soil affected by acid, highly toxic pyritic waste from the Aznalcóllar mine (Seville, Spain) in April 1998. The following treatments were applied (3 plots per treatment): cow manure, a mature compost, lime (to plots having pH 〈 4), and control without amendment. During the study two crops of Brassica juncea were grown, with two additions of each organic amendment. Throughout the study, the evolution of soil pH, total and available (DTPA-extractable) heavy metals content (Zn, Cu, Mn, Fe, Pb and Cd), electrical conductivity (EC), soluble sulphates and plant growth and heavy metal uptake were followed. The study indicates that: (1) soil acidification, due to the oxidation of metallic sulphides in the soil, increased heavy metal bioavailability; (2) liming succeeded in controlling the soil acidification; and (3) the organic materials generally promoted fixation of heavy metals in non-available soil fractions, with Cu bioavailability being particularly affected by the organic treatments.
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  • 7
    ISSN: 1572-9729
    Keywords: acid mine drainage ; algae ; heavy metals ; high rate algal ponds ; sulphate reducing bacteria ; waste stabilisation ponds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Acid mine drainage pollution may be associated with large water volume flows and exceptionally long periods of time over which the drainage may require treatment. While the use and role of sulphate reducing bacteria has been demonstrated in active treatment systems for acid mine drainage remediation, reactor size requirement and the cost and availability of the carbon and electron donor source are factors which constrain process development. Little attention has focussed on the use of waste stabilisation ponding processes for acid mine drainage treatment. Wastewater ponding is a mature technology for the treatment of large water volumes and its use as a basis for appropriate reactor design for acid mine drainage treatment is described including high rates of sulphate reduction and the precipitation of metal sulphides. Together with the co-disposal of organic wastes, algal biomass is generated as an independent carbon source for SRB production. Treatment of tannery effluent in a custom-designed high rate algal ponding process, and its use as a carbon source in the generation and precipitation of metal sulphides, has been demonstrated through piloting to the implementation of a full-scale process.The treatment of both mine drainage and zinc refinery wastewaters are reported. A complementary role for microalgal production in the generation of alkalinity and bioadsorptive removal of metals has been utilised and an Integrated 'Algal Sulphate Reducing Ponding Process for the Treatment of Acidic and Metal Wastewaters' (ASPAM) has been described.
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  • 8
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    Springer
    Biodegradation 9 (1998), S. 411-422 
    ISSN: 1572-9729
    Keywords: agrochemicals ; heavy metals ; NMR imaging ; NMR spectroscopy ; subcellular compartmentation xenobiotic metabolism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The application of non-invasive nuclear magnetic resonance (NMR) methods in xenobiotic research is reviewed in relation to: (i) the characterisation of the effects of xenobiotics on the metabolism of plants and plant cell suspensions; (ii) the direct detection of xenobiotics and their degradation products in vivo; and (iii) the spatial localisation of xenobiotics and their derivatives at the subcellular and tissue levels. Novel information has been generated by in vivo NMR studies of both agrochemicals and heavy metals, but a lack of generality in the methods makes it difficult to extrapolate from one successful application to the next. In vivo NMR spectroscopy is shown to be informative when a xenobiotic perturbs metabolic pathways that are accessible to the technique, and it is useful for probing the partitioning of paramagnetic metal ions between the cytoplasm and the vacuole. The successful application of 19F NMR to the analysis of plant tissue extracts also suggests that in vivo 19F NMR spectroscopy may have a role in biotransformation studies of fluorinated xenobiotics. In contrast NMR imaging techniques have been little used for xenobiotic research in plants, and while the method has been shown to be capable of monitoring the uptake and translocation of paramagnetic ions in plants, the potential use of high resolution 1H and 19F NMR imaging for mapping agrochemicals in tissues is still in its infancy.
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  • 9
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    Environmental monitoring and assessment 56 (1999), S. 177-193 
    ISSN: 1573-2959
    Keywords: accumulation ; bioindicators ; concentrations ; heavy metals ; Karelia ; wildlife
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The levels of mercury, cadmium, lead, copper, nickel, zinc and iron were determined in samples of liver, kidney, skeletal muscle, heart, lungs and hair of moose (N = 67), reindeer (N = 45), brown bear (N = 18), wild boar (N = 10) and squirrel (N = 18) shot in Karelia from 1989 to 1991 during regular hunting. The highest heavy-metal concentrations were found in livers, kidney, lungs and hair samples. The samples of muscle contained lowest levels of these elements. The tissues of moose, reindeer and brown bear were contaminated with heavy metals to a greatest extent. Lowest levels of toxicants were recorded in wild boar. Results indicate a widespread presence of heavy metal in the environment and in wildlife, which may be linked to acid precipitation. There was no evidence of these elements accumulated to toxic levels, but Karelian public have been informed that the eating of moose liver and kidney would probably result in their exceeding WHO standard weekly intake limit for cadmium.
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  • 10
    ISSN: 1573-2959
    Keywords: heavy metals ; organochlorines ; red fox
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Heavy metals and organochlorine contamination were analyzed in tissues of red foxes (Vulpes vulpes) from the Province of Siena (central Italy). Mercury (Hg), cadmium (Cd) and lead (Pb) concentrations were assessed in liver tissues and the data were analyzed for differences in relation to sex and age. Overall Hg, Cd and Pb mean values were 0.16, 0.62 and 0.64 μg g_1 d.w., respectively. HCB, DDT and PCB concentrations were assayed in fatty tissues and muscle. The highest levels of those pollutants were found in muscle (0.47, 1.16 and 20.2 μg g_1 lipid basis of HCB, DDTs and PCBs respectively), rather than in fat (0.23, 0.49 and 7.2 μg g_1 l.b. of HCB, DDTs and PCBs respectively). Pollutant accumulation was analyzed in relation to sex, age and sexual maturity of females.
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  • 11
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    Environmental monitoring and assessment 54 (1999), S. 229-237 
    ISSN: 1573-2959
    Keywords: coastal index ; discriminant analysis ; fishing areas ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The quality assessment of fishing areas on the basis of the levels of heavy metals in clams ( Chamelea gallina) was attempted by using discriminant analysis. Five metals, Hg, Pb, Cd, Cu and Zn, were analyzed in the soft edible parts of clams from three fishing areas. The descriptive methods applied to data obtained do not show enough differences between sampling stations for management purposes. Only discriminant analysis is successful in the differentiation between all fishing areas. Through the first discriminant function, the group centroids are proposed as index of different source of clams. These values standardized are proposed as coastal quality index.
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  • 12
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    Environmental monitoring and assessment 55 (1999), S. 389-399 
    ISSN: 1573-2959
    Keywords: accumulation ; heavy metals ; mine spoils ; vegetation ; soil-plant relationships
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The presence of heavy metals (Cr, Ni and Fe) in soil and accumulated by herbs, shrubs and trees regenerated naturally on the minewaste-dumps of Sukinda chromite mines (TISCO sector) were investigated. There was significant correlationship between Cr and Fe in the soil where a tree species (Catunaregam spinosa) occurred. Guazuma ulmifolia and Diospyros montana also did show significant correlation between leaf, stem and soil for Cr, Ni and Fe. Among the shrubs (Calotropis gigantea, Chromolaena odorata, Phyllanthus reticulatus and Woodfordia fruticosa) significant and positive correlations were obtained for Cr and Ni in soil and iron and nickel in leaf and chromium and nickel in stem. Among the annual herbs, whole plant of tephrosia purpurea and Borrevia articularis showed significant and positive correlation with chromium and nickel with the maximum correlation coefficient value. It was concluded that the above information would be useful in revegetation programmes in subtropical regions having seasonal rainfall.
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  • 13
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    Environmental monitoring and assessment 59 (1999), S. 321-330 
    ISSN: 1573-2959
    Keywords: agar diffusion assay ; Arabian Gulf ; chromogenic bacteria ; heavy metals ; toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A simple method – direct agar diffusion assay – was optimised for rapid assessment of heavy metal toxicity to marine chromogenic and non-chromogenic bacteria. The procedure involved spotting of a 10 microliter test solution on the seeded agar plate and incubation of the plates at 30°C to accelerate bacterial growth. Under optimum conditions, test results were obtainable within 12–18 hr instead of 96 hr incubation time generally required for a marine bacterial assay by conventional agar plate methods. A range of sixteen heavy metals, each at 5 different concentrations was tested. Toxicity was demonstrated by the formation of a clear zone of growth inhibition around the point of application. Toxicity of tested chemicals could be easily demonstrated at concentrations as low as 0.1 μg per spot on the agar plate. A dose dependent relation between metal concentration (μg/spot) and the diameter of the clear zone on agar plate was observed, suggesting potential of this method as an easy and economical tool in quantitative toxicology studies.
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  • 14
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    Water, air & soil pollution 109 (1999), S. 1-15 
    ISSN: 1573-2932
    Keywords: EDTA ; heavy metals ; leaching ; lead ; soil remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The performance of EDTA for the treatment of calcareous soils contaminated with heavy metals from mining and smelting activities was evaluated in this study. Soil samples containing variable levels of contamination, from 500 to 35 000 mg kg-1 Pb and 700 to 20 000 mg kg-1 Zn, were subjected to EDTA treatment and the extraction of heavy metals was found to vary, ranging between 50 and 98% for Pb and 50 to 100% for Zn. Total residual concentrations were above the limits set by regulatory authorities; leachable metals, however, were efficiently removed and treated soils were all acceptable in terms of toxicity. The effect of EDTA concentration and pulp density was studied on a soil sample containing 12 000 mg kg-1 Pb and 10 000 mg kg-1 Zn. Heavy metals removal was improved at low pulp densities and when EDTA concentration was increased from 0.025 to 0.25 M. The tetrasodium salt Na4-EDTA was found to be less effective for metals removal compared to the disodium salt Na2-EDTA, though applied at higher concentrations. This experimental work has also demonstrated the great importance of soil matrix for the overall evaluation of the EDTA leaching as a cost effective remedial option. The simultaneous dissolution of calcite was found to consume approximately 90% of the available EDTA. It was thus concluded that for the treatment of calcareous soils the design criteria and cost estimations should be based on the calcite content of the soil.
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  • 15
    ISSN: 1573-2932
    Keywords: heavy metals ; polycyclic aromatic compounds ; sewage sludge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The total contents of PAHs, organic polar fractions and 14 major hydrocarbons containing 3–6 aromatic rings as well as heavy metal contents were determined in sewage sludges from highly industrialized (Upper Silesia), agricultural and recreational regions of Poland. Sludges from the industrial region showed markedly increased concentrations of all the organic micropollutants and 2–10 times higher levels of the following heavy metals: Pb, Cd, Cr, Cu, Fe, Zn, Ni, Mn and Co. The levels, however, did not exceed the Polish as well as European Economic Community limit values, which renders all the sludges applicable to land and some of them suitable for utilization on agricultural soils.
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  • 16
    ISSN: 1573-2932
    Keywords: bootstrapping ; heavy metals ; Norway ; palaeolimnology ; partition coefficients ; pH ; redundancy analysis ; surface sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Data from 96 headwater lakes from Norway are used to model heavy metal concentrations in surficial lake sediments in relation to atmospheric deposition. The study evaluates the application of sediment-water partitioning models at the field scale and finds optimum values for the partition coefficients. The impact of environment (sediment type, lake water pH, etc.) on KDvalues is explored directly by comparing KDestimates with environmental variables. KDvalues for each metal are found by optimising the fit between predicted and observed surface-sediment concentrations. The sensitivity of the KDestimates to data structure is examined by bootstrapping. KDvalues of 105.8and 106.2were calculated for cadmium (Cd) and lead (Pb), respectively, comparable to recent direct observations. Biogenic silica influenced KDvalues for Cd, Pb and Zn, whereas lake depth influenced Pb. pH did not have any detectable effect. KDfor zinc (Zn) was less well defined, but higher than indicated by published experimental measurements. The results suggest that sediment-water partitioning models have an important contribution to make to field-scale lake studies of sediment heavy metals, and have important implications for palaeolimnological evaluations of heavy metal deposition.
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  • 17
    ISSN: 1573-2932
    Keywords: factor analysis ; Germany ; heavy metals ; moss monitoring ; stream sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The results of the first German moss monitoring programme to estimate heavy metal pollution in the Federal Republic of Germany were combined with other large-scale investigations carried out in Germany and then classified geographically in a new form. Using Monte Carlo assisted factor analysis, six factors indicating sources of pollution were identified from the sets of element data from the moss monitoring project (As, Cd, Cr, Cu, Fe, Ni, Pb, Ti, V, Zn) and the data sets for SO2 and particulate. The geographic distribution patterns of the factor values showed the regions in which the various sources are to be found. By combining the data the primarily anthropogenic chromium concentrations of the mosses were compared with the mainly geogenic chromium concentrations of the stream sediments in the form of examples. After normalization, the transformed chromium concentrations were transferred to a map of the entire area using inverse distance weighting. Anthropogenic and geogenic influences are being discussed on the basis of the results.
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  • 18
    ISSN: 1573-2932
    Keywords: biomonitoring ; Brazilian coast ; heavy metals ; mussel ; Perna perna
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Heavy metal levels were determined in marine mussels Perna perna collected from Ubatuba Bay, northern coast of the State of SãoPaulo, Brazil, during the period from January toOctober 1995. The objective of the present study wasto analyze the seasonal concentrations of some metalsof toxicological interest (Cd, Cu, Cr, Pb and Zn) inUbatuba Bay using the bivalve Perna perna(Linnaeus, 1758) as a biological monitor. Collectionswere performed at three month intervals at Itaguábeach. In the laboratory, the frozen specimens werethawed at room temperature, removed from their shells,partially dried on filter paper, weighed andindividually submitted to acid digestion with sulfuricacid and hidrogen peroxide. The analyses for thedetection of Cd, Cu, Cr, Pb and Zn were carried out byflame atomic absorption spectrophotometer. The resultsshowed higher metal accumulation during July. Thevalues detected for Pb and Cr were relatively high inall seasons, especially in January and July (vacationperiods) in Ubatuba Bay, with the consequent risk ofcontamination by mussel ingestion for the localpopulation and for tourists from other regions.
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  • 19
    ISSN: 1573-2932
    Keywords: heavy metals ; particulate speciation ; sequential chemical extractions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Over the last century, discharge of industrial effluents and municipal wastewater have contaminated the Lachine Canal sediments. This study investigated the associations between heavy metals and natural sediment constituents. X-ray Diffraction, Transmission Electron Microscopy and geochemical analysis revealed that the sediments consisted mainly of silt and clay size fractions composed of: feldspar, illite, kaolinite, chlorite, calcite and dolomite as well as minor amounts of Fe minerals. Organic matter and amorphous metal oxides were also identified. Each of these constituents bound heavy metals at varying degrees as assessed by a sequential chemical extraction (SCE) protocol. The associations with each geochemical phase were (in order of decreasing significance): 1) residual phase, 2) oxide phase, 3) carbonate phase, 4) organic phase and 5) exchangeable phase. According to the cation exchange capacity (CEC), carbonate and oxide content measurements, the heavy metals occupied a minor fraction of the total capacity of the sediments to retain metals by these mechanisms. The SCE results revealed that the partition patterns varied with pH. The phases associated to the carbonate and the exchangeable phases were the most sensitive to a change in pH with the residual phase being almost unchanged. The Zn and Cd were sensitive to release when the conditions drifted to acidic conditions. The partition patterns for various grain size fractions (〈53 µm, 53–75 µm, 75–175 µm and 〈175 µm) revealed that no particular fraction accumulated a certain heavy metal. Finally, from protocols, techniques and results interpretation in this study, various engineering applications such as the technical choice of clean-up scenarios, screening of remediation techniques and the development of remediation quality criteria were proposed within the framework of the management of contaminated sediments.
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  • 20
    ISSN: 1573-2932
    Keywords: contaminated sediments ; heavy metals ; pollution indices ; quality criteria ; sediment quality assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Due to industrialization over the past 100 years, the sediments at the bottom of the Lachine Canal and Bay have become contaminated. This study investigated the heavy metal accumulation mechanisms within the Lachine Canal sediments and was carried out in three phases. Phase I is covered in the present article, while phases II and III will be discussed in a following paper. During Phase I, 28 parameters were measured on 44 sediment samples collected along the Lachine Canal and Bay. The results revealed the presence of a wide variety of both organic and inorganic contaminants. Heavy metals such as Zn 〈 Pb 〈 Cr 〈 Ni 〈 Cu 〈 Cd (in order of decreasing abundance) in addition to organic contaminants (PAHs 〈 MAHs 〈 PCBs) were found in high concentrations exceeding background concentrations and various quality criteria levels. The total load of both organic and inorganic contaminants was found to be higher in the canal than in the bay zone. Correlation analysis was performed to evaluate sediment assessment values with respect to known adsorptive phases such as % clay fraction, TOC (Total Organic Carbon), and % CaCO3. Although a positive correlation existed between % clay fraction or TOC and the total cumulative load of heavy metals, the correlation could not be assessed as conclusive. Significant correlations were obtained between Pb, Ni, and Zn and the carbonate content of the sediments. Pollution Indices (PI) were used according to the format proposed by Canadian authorities and as such were evaluated as incomplete.
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  • 21
    ISSN: 1573-2932
    Keywords: acidity ; Ca ; extra-intracellular ; F. antipyretica ; heavy metals ; K ; Mg ; transplants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract With the aim of investigating the effects of wateracidity and metal concentrations on the accumulationof heavy metals by aquatic bryophytes, batches of Fontinalis antipyretica Hedw. were transplanted froma clean site to one of four sites with characteristicsranging from clean to severely contaminated (highacidity and high heavy metal concentrations). After 1–35 days, metal levels were determined in theextracellular and intracellular compartments of thetransplanted material. The results show that heavymetal uptake is clearly lower in acid waters than innear-neutral waters, possibly due to competitivedisplacement of metal cations from extracellularbinding sites and membrane transport proteins byprotons. The reduced accumulation is particularlymarked in the extracellular compartment; theintracellular compartment shows rapid accumulation oflarge amounts of metal, followed by equally rapidrelease. The effects of heavy metals and acidity onphysiology were also investigated, on the basis oflevels of the essential cations potassium (K),magnesium (Mg) and calcium (Ca) in the extracellularand intracellular compartments. Bryophytestransplanted to the severely contaminated sites showedloss of intracellular K (indicating altered membranepermeability), loss of extracellular Mg, and loss ofboth extra- and intracellular Ca (implying damage tothe cell wall).
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  • 22
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    Water, air & soil pollution 103 (1998), S. 173-195 
    ISSN: 1573-2932
    Keywords: absorption ; edible mushrooms ; fruit bodies ; heavy metals ; sanitary standards ; wild berries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The total concentrations of nickel, copper, chromium, strontium, arsenic, lead, cadmium and cobalt were measured in berries and mushrooms, as well as manganese and iron in mushrooms. The study area (about 3500 km2) is situated on the border of the northern taiga and tundra forests (68–69°N) and is affected by emissions from the extensive Ni-Cu smelter complex at Monchegorsk, Kola Peninsula, NW Russia. Part of the study area, extending along the railway line used for transporting apatite concentrate, contains elevated quantity of strontium. Berries of Vaccinium vitis-idaea (82 samples), Vaccinium myrtillus (28), Rubus chamaemorus (42) and Empetrum hermaphroditum (40) and mushrooms of Leccinum auantiacum (47 samples), Leccinum scabrum (32), Russula vesca (25), Lactarius torminosus (8), Lactarius trivialis (9), Suillus luteus (10) and Xerocomus subtomentosus (20 specimens) were collected from 98 locations during 1987–1992. The nickel and copper concentrations in the berries, and nickel in mushrooms, correlated satisfactorily with the corresponding metal concentrations in the soil. The berries and mushroons growing over an area of at least 3000 km2 around the smelter complex are unsuitable for human consumption due to the elevated nickel concentrations caused by the smelter dust emissions. The berries and mushrooms gathered in the studied polluted forests were found to be contaminated by nickel by a factor of 15–30 times (berries) and 15–40 times (mushrooms) more than the background level. Increased levels of strontium were found close to the railway line. The concentrations of all the other metals in the studied area did not exceed sanitary standards.
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  • 23
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    Water, air & soil pollution 103 (1998), S. 315-339 
    ISSN: 1573-2932
    Keywords: fly ash ; heavy metals ; phytoplankton ; species diversity ; zooplankton ; water chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The impact of fly ash on the biology of the Yamuna River, Delhi, was studied. Effluents come from a 200 MW capacity I.P. thermal power station. Seasonal variations in the biological features in the non-impacted (Y-1) and the impacted (Y-2) segments of the river receiving fly ash effluents were studied. 60 genera of phytoplankton including 29 Chlorophyceae, 19 Bacillariophyceae, 8 Cyanobacteria, and 4 Euglenophyceae were recorded. Phytoplankton diversity was reduced at the impacted site in comparison to the non-impacted site of the river and substantial changes in the composition of various groups inhabiting these areas were observed. Zooplankton were also reduced at Y-2 compared to Y-1, especially rotifers and protozoans, while copepods and nauplii larvae were not affected to the same degree. Species diversity was not significantly different at Y-2 and Y-1 but similarity index varied from low to high between the two stations. Thus, not only was the density, number of genera and diversity reduced, even the generic composition of the plankton was markedly affected in the impacted waters. The observed perturbations could be due to sedimentation of ash particles, pH or elevated metal or salt concentration. A change in the concentration of one or more constituents disturbs the relationship between biota and could be the possible cause of reduced densities in the impacted waters.
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  • 24
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    Water, air & soil pollution 103 (1998), S. 277-314 
    ISSN: 1573-2932
    Keywords: fly ash ; elements ; water chemistry ; coal ash ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The impact of fly ash on the chemistry of the River Yamuna was studied. By-products from a 200 MW capacity I.P. thermal power station on the west bank of the River Yamuna, Delhi are largely from coal combustion (fly ash) and are disposed of as a slurry to off-site ash ponds. Many elements associated with fly ash are soluble and become available to the biota. A two-year survey was made of the seasonal variations in limnochemical features in the non-impacted and the impacted segments of the river receiving fly ash effluent and the ash treatment ponds. Conductivity, TDS, DO, hardness, sulphate and nitrate increased significantly in the receiving waters over background values. The reverse was noticed for free CO2, alkalinity and phosphate. Changes in some other parameters were insignificant. Fly ash effluents from the ash ponds significantly increased the concentration of some elements, viz., Al, Sb, Bi, Cd, Cr, Co, Li, Mn, Mo, K, Si, and Zn in river water. Generally, the highest concentration of most parameters were recorded in the ash ponds. This investigation was helpful in assessing the effect of wet ash disposal on the river limnology and understanding the solubility of various elements in the ash ponds.
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  • 25
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    Water, air & soil pollution 105 (1998), S. 451-458 
    ISSN: 1573-2932
    Keywords: critical loads ; critical times ; Czech Republic ; heavy metals ; predictive model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Critical load of trace metals in soils is a function of biological uptake, leaching by percolating water, input of the trace metals due to bedrock weathering, and the norms set to protect soils from metal pollution. The exceedance of the critical load is a difference between the calculated load and the measured input of the metals by atmospheric deposition and by application of agrochemicals. A critical time is the time when the concentration of a trace metal in soil, which is the result of all inputs and outputs of the metal in the soil, reaches the value of the norm. Data on biologically important trace metals in a small agricultural catchment in the Czech Republic indicate that the soil concentrations of As, Cd and Pb will reach the norms set for the soils after 4.5, 61, and 980 years, respectively. The present mass balances of Cu and Zn in the soils indicate that their steady-state concentrations will be below the norms so that the atmospheric and agricultural inputs will never overshoot the calculated critical load.
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  • 26
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    Water, air & soil pollution 107 (1998), S. 367-391 
    ISSN: 1573-2932
    Keywords: heavy metals ; needle ; peat ; Pinussylvestris ; toxicity limits
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Peat and needle samples were collected from an old Cu, Zn and Ni ore-prospecting experiment at Alkkia, SW Finland. The element rates applied were 100–400 kg ha-1 for Ni and 100–1000 kg ha-1 for Cu and Zn. The heavy metal toxicity of Scots pine stand was estimated primarily on the basis of stand mortality during 28 yr. The tolerance limit values were applied to pine stands growing along a Cu-Ni deposition gradient (0.9–10 km) at Harjavalta copper smelter, SW Finland. Very high heavy metal concentrations in the pine needles and strong accumulation in the surface humus and uppermost peat layers were found. A Cu concentration of 840, Ni 180 and Zn 220 mg kg-1 in peat 0–10 cm, and a Cu concentration of 50, Ni 30 and Zn 175 mg kg-1 in the current needles of the uppermost whorl are proposed as toxicity limits for peatland forests at Harjavalta. According to the heavy metal amounts in peat 0–20 cm, the toxicity area for Cu extended to a distance of 2.0 km, for Ni about 1.0 km and for Zn 0.4 km to the west of the emission point source.
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  • 27
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    Water, air & soil pollution 108 (1998), S. 51-68 
    ISSN: 1573-2932
    Keywords: Crustacea ; growth ; heavy metals ; monitoring
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The dynamics of lead (Pb) and cadmium (Cd) accumulation in juvenile Porcellio scaber were studied over 6 months after exposing them to three different concentrations of lead and cadmium in their food. Subsequently the ability of P. scaber to eliminate lead and cadmium was studied over two months. Growth was measured to determine whether metal contamination leads to physiological stress in the animals. The accumulation of Pb and Cd in P. scaber shows two different phases. Up to the age of 2–3 months the assimilation exceeds the rate of growth and leads to rapidly increasing concentrations. After 3 months the rate of accumulation is proportional to the rate of growth and the heavy metal concentrations remain on a stabilized level. P. scaber was able to eliminate about 40% of the assimilated lead within 2 weeks but there was no elimination of Cd within 7 weeks. Contaminated P. scaber shows significant growth reduction. The physiological response of P. scaber to heavy metal contamination is discussed.
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  • 28
    ISSN: 1573-2932
    Keywords: acid deposition ; heavy metals ; cadmium ; soil contamination
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Simultaneous soil acidification and deposition of heavy metals is a major concern for forest and agricultural soils of the Black Triangle region of East Central Europe including southern former East Germany, northern Bohemia of the Czech Republic, and southern Poland. The objective of this project was to develop historical and future projections of acid and heavy metal deposition to soils (As, Cd, Pb, Zn) and to produce a preliminary map of soil sensitivity to cadmium pollution and uptake by crops. Ultimately, we wish to assess the relative hazard and recovery times of soils to metals deposition in the region. Emission and deposition data bases obtained from several models developed at IIASA were linked using the Geographical Information System ARC/INFO to produce soil maps of sensitivity to cadmium mobility based on metals deposition, soil type, soil texture, organic matter content, and acid deposition. RAINS 6.1 (Alcamo et al., 1990) was utilized to produce maps of acid deposition for EMEP grids (150 km x 150 km). The largest amount of acid load is deposited in southern East Germany. Sulfur deposition in that area was 10–12 gS/m2/yr in 1990, and S+N deposition exceeded 8000 eq/ha/yr. But the “hot spot” for metals deposition is further to the east, in the Silesia area of southern Poland. The TRACE2 trajectory model of Alcamo, Bartnicki, and Olendrzynski (1992) was used to estimate cumulative metals deposition since 1955 with scenarios to 2010. Pb has improved over Europe since 1970 when depositions in the Ruhr River Valley of West Germany exceeded 60 mg/m2/yr. But cadmium deposition in southern Poland (Katowice and Krakow) has now accumulated to 60–70 mg/m2 by atmospheric deposition alone. During base case simulations from 1955–87, approximately 1.8 mg/kg Pb and 0.12 mg/kg Cd have been added to the mixed plow-layer of ∼30 cm. If these emissions continue indefinitely, the accumulation of metals will become problematic for agriculture and the food chain.
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  • 29
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    Water, air & soil pollution 92 (1996), S. 343-374 
    ISSN: 1573-2932
    Keywords: long-range transport ; atmospheric deposition ; heavy metals ; country budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Heavy Metal Eulerian Transport (HMET) model has been used to calculate the exchange of As, Cd, Pb and Zn between European countries in 1985. The model was run separately for each emitter country and the computed deposition field was used to calculate the contribution of the emitter to each receptor country. The results of these computations are presented in the form of a country budget matrix for each metal. Accuracy of such computations is dependant on the size and linearity of the numerical method applied to the transport equation. Exchange of heavy metals due to atmospheric transport over Europe is significant. Approximately 30% to 90% of the heavy metals emitted from each country is deposited in other countries. The remaining mass is deposited in European seas, Atlantic Ocean and transported outside the model domain. The largest part of the emission from each country is deposited in the same country. The next largest fraction is transported to the nearest neighbors. The results indicate also a significant long range ransport of heavy metals to the Soviet Union. This is partly justified by the size and location of this receptor country, as well as, the prevailing meteorological conditions in Europe. However, this large transport to USSR is slightly overestimated due to some artificial properties of the numerical method applied to basic model equations. In addition to the country budget, export versus import and emission versus deposition of metals were analyzed for each country. The largest positive difference between export and import was found for Poland, German Federal Republic and Yugoslavia (As, Cd and Zn), and United Kingdom, Italy and Belgium (Pb). The Soviet Union and Czechoslovakia are the countries where import of all metals is significantly larger than export. When emission versus deposition of heavy metals is analyzed, the Soviet Union has much higher emissions than deposition of all metals compared to other European countries.
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  • 30
    ISSN: 1573-2932
    Keywords: Acari ; bioindicators ; Gamasida ; heavy metals ; Oribatida ; Scots pine forest
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The soil mites were investigated in the areas covered with dead needles in young Scots pine forests (plant associationLeucobryo-Pinetum), polluted by a copper smelting works at Głogów, and in a control plot. The concentration of heavy metals, mainly copper and lead, was the lowest in the control plot, and increased towards the pollution source. A high concentration of these metals reduced the density of mites and species number of Oribatida and Gamasida, while small concentrations were associated with the increasing abundance of mites and species number of Oribatida. Among mites, the following categories were distinguished: a) sensitive to heavy metals, b) sensitive to a high concentration, but tolerant of small concentrations, and c) tolerant of these metals. The changed vertical distribution of mites in the most polluted soil was also observed, due to accumulation of heavy metals in the Of/h horizon.
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  • 31
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    Water, air & soil pollution 96 (1997), S. 185-201 
    ISSN: 1573-2932
    Keywords: Avenidas basin ; Pachuca mines ; hydrochemistry ; hydrochemical facies ; heavy metals ; groundwater
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Groundwater in the Rio de las Avenidas sub-basin corresponds to the bicarbonate-sodium and bicarbonate-calcium hydrochemical facies, which result from the mineralization of water passing through alkaline rocks (andesites) which prevail in this basin. However, the presence of high concentrations of Na+ and K+ reveals the existence of an external inflow of these elements: the registered mean values are respectively 94.3 and 19.0 ppm, with the Tèllez and Tizayuca areas standing out with reported values of up to 142 ppm. As for the concentration of soluble water cations, we find in decreasing order: Na+, Ca2+, Mg2+, K+, along with the anions HCO3 −, Cl−, SO4 2−, CO3 −, which combine to form the NaHCO3, NaCl, Ca(HCO3)2, MgSO4 and KCl salts. The presence of biological contaminants, P and detergents in the groundwater indicates that it may have been contaminated by waste water. In addition to the contaminants mentioned above, large quantities of Pb, B, Zn, Fe, Mn, Cr, Co were detected and although Fe, Pb, Zn, B, and Mn are closely related to the local lithology, the high concentrations of these elements along with the occurrence of Co, Cr, Cd, and Ni confirm the gradual degradation of the aquifers in the sub-basin. The water temperature indicates the existence of low temperature thermal processes in the area.
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  • 32
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    Water, air & soil pollution 109 (1999), S. 397-406 
    ISSN: 1573-2932
    Keywords: chicory ; fly ash pH ; heavy metals
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Chicory was cultivated in a pot experiment using two soils of different pH. Treatments were NPK, fly ash (pH 8) + NP and fly ash (pH 12) + NP, respectively. Another series of pots received heavy metals in soluble form additionally to the described treatments. It was observed that fly ash causes generally a decrease in Zn, Cd, Ni and Cu concentrations of chicory. The reduction occurs both for the metals naturally present in the soil and, to a greater extent, for those added as salts. This effect is more evident when fly ash at pH 12, rather than that at pH 8, was used. The increase of soil-pH through the fly ash addition is the major factor decreasing heavy metal availability. It was observed that potassium originating from fly ash is not available for crop uptake.
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  • 33
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    Water, air & soil pollution 111 (1999), S. 159-170 
    ISSN: 1573-2932
    Keywords: composting ; heavy metals ; municipal solid wastes ; sequential extraction ; speciation
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The organic fraction of municipal wastes has been composted on the laboratory scale. In the obtained compost the content of cadmium, cobalt, copper, manganese, nickel, lead and zinc were determined, as well as the speciation i.e, the form of their occurrence, making use of Rudd's method of sequential extraction. The investigations also concerned the way of removing these metals from the compost by means of leaching with solutions of sulphuric and nitric acid, as well as by electrochemically separating the metals from the solution after the compost had been leached with sulphuric acid. It has been found that the application of the electrochemical method with varying pH values of the leaching solution within the range of 6.8–2.8 allows for the separation of 83.5% Cd, 55.0% Co, 65.4% Cu, 59.4% Mn, 70.3% Ni, 90.5% Pb and 56.2% Zn.
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  • 34
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    Keywords: anions ; cations ; chemical composition ; heavy metals ; rain
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Precipitation events were collected during the period from October 1996 to April 1997 from two sites in the city of Amman, Jordan. The samples were analyzed for major cations (Na+, K+, Ca2+, Mg2+ and NH4+), major anions (F-, Cl-, NO3- and SO42-), in addition to heavy metals (Cu2+, Cd2+, Zn2+, and Pb2+). High levels of Ca2+ and SO42- were observed. The results were comparable with some regional values and they indicate that about 58% of Na+ and Cl- are of marine origin, while Ca2+, K+ and a large fraction of SO42- are of soil dust origin. Heavy metals were detectable in most of the samples, zinc showed the highest concentrations. Significant correlation was obtained between zinc and lead, which may indicate automobile emission source.
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  • 35
    ISSN: 1573-2932
    Keywords: extraction ; heavy metals ; soil remediation
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A model was developed that allowed for the evaluation of a soil metal cleaning technique in a rapid and cost effective manner. Metal flow (Pb, Cu, Zn, and Cd) during a counter-current soil-acid extraction procedure, consisting of a decarbonation, solubilisation, and washing step, was determined. Required input data are total soil metal content and metal equilibrium distribution coefficients, derived from batch equilibration experiments. The model was calibrated and validated against experimentally obtained results. Model predictions adequately described metal behaviour and removal in each of the extraction steps. Based on the results, optimum operating conditions for the steps involved in the extraction procedure were determined and the feasibility of the counter-current extraction procedure for heavy metal removal from a contaminated soil evaluated.
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  • 36
    ISSN: 1573-2932
    Keywords: Arcachon Lagoon ; atmospheric fluxes ; Cd ; coastal zones ; Cu ; Gironde Estuary ; heavy metals ; high frequency variability ; ICP-MS ; Ni ; Pb ; Zn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We report here the first data set on wet deposition of heavy metals in the southwestern French coastal zone. In this region, there are two major sensitive coastal ecosystems: the Gironde Estuary and the Arcachon Lagoon. Chemical analyses of heavy metals were carried out by ICP-MS. Annual mean concentrations of the dissolved fraction in precipitation were 0.2, 3.4, 4.3, 8.1 and 30 μg L-1for Cd, Ni, Cu, Pb and Zn, respectively. In terms of annual fluxes, these numbers are of the same order of magnitude as the fluxes measured in southeastern France, but are higher than those measured in western Brittany. When extrapolated to the entire Bay of Biscay, the annual wet dissolved fluxes of Cd, Ni, Cu, Pb and Zn are respectively 7, 110, 140 340 and 1440 t yr-1. According to available data in the literature, the regional Cd, Cu, Pb and Zn atmospheric fluxes for the Bay of Biscay are of the same order of magnitude as riverine inputs (Loire and Gironde). On a daily or weekly time scale, we observed a strong variability of elemental fluxes: up to 20% of the annual dissolved flux may occur in a rain event shorter than 3.5 days. Although elements display generally parallel variations with time, they sometimes follow independent behaviours (e.g. Pb and Cd), suggesting that they may derive from different geographical and/or pollution sources.
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  • 37
    ISSN: 1573-2932
    Keywords: arid-zone soils ; field capacity ; fractionation ; heavy metals ; kinetics ; redistribution ; transformation
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformation of added Cd, Cu, Cr, Ni, Pb and Zn, in two arid-zone soils incubated in the field capacity moisture regime for one year, were studied. The heavy metals were fractionated into six empirically defined fractions using a selective sequential dissolution (SSD) protocol optimized for arid-zone soils. Each of these fractions was named based on the major soil component targeted for dissolution during the specific SSD step, but it is not assumed that they are mineralogically and chemically totally specific. The transformations of the metals in the two soils incubated at the field capacity regime were compared with those at the moisture saturation regime (Han and Banin, 1997). An initial fast stage of transformation of the soluble metals from the exchangeable (EXC) fraction to the less labile fractions (the carbonate (CARB) fraction for Cd, Pb, Zn, Ni and Cu, and the organic matter (OM) fraction for Cr, and to some extent Cu and Ni) occurred during the fractionation and within one hour after addition. This was followed by a second stage, involving long-term transformation processes of all metals: added Cd was transferred from the EXC into the CARB fraction; added Cr was transferred from the CARB to the OM fraction and Pb was transferred very slowly to the easily reducible oxide (ERO) fraction. Added Cu, Ni and Zn were transferred from the EXC and CARB fractions into the ERO fraction and to some extent OM and RO fractions. In Part I of this series, we reported that during incubation in the saturated moisture regime, Zn and Ni were transferred mainly into the RO and OM fractions. Cadmium, Cr and Pb underwent the same transformation pathways during the slow long-term process, with slightly different rates, in both water regimes. At low levels of addition, the incubated soils moved over one year towards a distribution similar to that of the native soil. At higher levels, the soils still remained removed from the quasi-equilibrium which characterized the native soil, even at the end of one year of incubation.
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  • 38
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    Water, air & soil pollution 102 (1998), S. 313-328 
    ISSN: 1573-2932
    Keywords: dredged sediment derived surface soils ; heavy metals ; sedimentdisposal site ; sequential extraction DTPA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The objective of this study was to characterise pollution with heavy metals in surface soils sampled at various dredged sediment disposal sites in the Flemish region (Belgium). The sites selected varied in the period since sediment disposal ceased and in current vegetation and land use. Total metal contents (Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn) in the surface soils varied widely. For some disposal sites Cd and Zn concentrations greatly exceeded reference values for clean soil. The distribution of the metals as determined by sequential extraction differed between elements, but was simular for all the soils. This suggested that metals in these sediment derived surface soils were accumulated and transformed in a similar way. Residual fractions were low compared to total contents (2 – 4% for Cd, 25% – 35% for Co, 7 – 18% for Mn, 4 – 22% for Zn, 12 – 41% for Ni, 11 – 42% for Pb, 20 – 45% for Cu, 〈 10% for Zn). High metal concentrations in the acid-extractable and reducible fractions may indicate pollution from anthropogenic sources. DTPA-extractable metals, which may be considered indicative of plant-available contents, were relatively high compared to the total contents. The relative extractability, expressed as the ratio of DTPA-extractable to total contents, decreased in the order Cd (38%) 〉 Cu (28%) = Zn (26%) 〉 Pb (13%) 〉 Ni (10%) 〉 Co (3%). Most of the sites studied would be of concern if they were used for agricultural activities. No trends in metal availability in the period following disposal were apparent from the data.
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  • 39
    ISSN: 1573-2932
    Keywords: heavy metals ; redox ; sulfides ; wetland soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The objective of this study was to measure the mobility of heavy metals in freshwater estuary soils that are seasonally inundated and to characterize the distribution of sulfide precipitates in these soils. Precipitation and dissolution of labile sulfides may account for changing pore water concentrations of heavy metals in freshwater wetland soils that are subject to temporary flooding or fluctuating groundwater levels. The presence of authigenic zinc- and iron-(mono)sulfide in this type of soils during periods with a high groundwater level was demonstrated by electron microprobe analyses. Because sulfide precipitates are strongly associated with root remnants, fresh soil organic material may be an important intermediary in the sulfur cycling and, consequently, in the behavior of heavy metals in these freshwater soils. Oxidation of labile sulfides may be partly responsible for the increased zinc and sulfate concentrations in the pore water during periods with low groundwater levels. Heavy metals may also be mobilized by degradation of their host phase organic matter during periods with high biodegradation.
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  • 40
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    Water, air & soil pollution 102 (1998), S. 389-405 
    ISSN: 1573-2932
    Keywords: air pollution ; heavy metals ; needle element content ; Pinus sylvestris ; XRF
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concentrations of aluminium (Al), arsenic (As), calcium (Ca), cadmium (Cd), chlorine (Cl), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), sulphur (S), silicon (Si) and zinc (Zn) were measured by X-ray fluorescence spectrometry (XRF) in Scots pine needles collected from transects across Finnish Lapland and the Kola Peninsula in Russia. Ni, Cu, Fe, P and S concentrations were significantly higher in the needles collected in the vicinity of the smelters in Monchegorsk, whereas Mn and Zn decreased towards Monchegorsk. No distinct increase of S or decrease of Mn and Zn concentrations in the needles were observed when approaching Nikel. Foliar S concentrations were higher in C needles than in C+1 needles, even in plots close to the smelters. The effect of the emissions from the smelters was clearly seen in the needle chemistry up to 50 km away from smelters and was still perceivable over 100 km away.
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  • 41
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    Water, air & soil pollution 118 (2000), S. 131-142 
    ISSN: 1573-2932
    Keywords: Baiyin urban area ; cultivated graycalcareous soil ; heavy metals ; historical trend of pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concentrations of cadmium (Cd), copper(Cu), lead (Pb), zinc (Zn), manganese (Mn) and nickel(Ni) were measured in cultivated gray calcareous soilscollected in the two basins of Baiyin urban area. Thevalues revealed fluctuating and enriched Cd, Pb, Cuand Zn concentrations in the cultivated soils,suggesting recent inputs from anthropogenic sources.There also existed differences between these twodrainage areas, indicating the characteristics ofpollution sources differed. Concentrations of Cd, Pband to a lesser extent Cu and Zn were higher in thisregion as compared with the micrometal backgroundvalues in gray calcareous soil, which may beattributed to the proximity of these soil sites tocontaminated streams, or to the utilization offarmyard manure or fertilizers. Comparison of obtainedmetal concentration levels with other areas in theworld revealed elevated values for Cd and Pb, showinga considerable amount of pollution in the area.Continuous monitoring and further studies of the areaare recommended to ascertain long-term effect that mayhave not yet been reached and to prevent pollution offarmland from worsening.
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  • 42
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    Water, air & soil pollution 104 (1998), S. 305-312 
    ISSN: 1573-2932
    Keywords: heavy metals ; sediment ; analysis ; Anzali wetland ; Iran
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concentrations of Cd, Pb, Cu, Zn and Ni were determined in surficial sediments from eleven sampling sites in Anzali wetland. Four different methods were tested to choose the most efficient procedure for determination of the metals. The measurement of the metal levels were performed using atomic absorption spectroscopy. In order to interpret analytical results, several statistical methods were applied. There were statistically significant differences among the accumulation of the metals in sediments, while differences were not be observed among the seasons. Sampling site eight showed the lowest similarity compared to others. Kurtzfassung. Gehalte an Cd, Pb, Cu, Zn und Ni wurden in den oberflächliche sedimenten von elf probestellen aus der Anzali Lagune gemessen. Vier verschiedene Methoden Wurden untersucht um das leistungsfähigste zu wählen. Die Messungen wurden mittles flammen-AAS vorgenommen. Zur Interpretation der Ergebnisse, mehrere statistische Methoden wurden angewendet. Es gab allgemein statistische Signifikanz Unterschiede zwischen der Akkumulation der Metalle in Sedimente. Beträchtliche Unterschiede zwischen den Jahrezeiten Konnten dagegen nicht festgestellt werden. Die Probestelle acht wies die geringste Ähnlichkeit mit den anderen auf.
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  • 43
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    Water, air & soil pollution 124 (2000), S. 155-168 
    ISSN: 1573-2932
    Keywords: cadmium ; copper ; estuarine sediments ; heavy metals ; lead ; sequential extraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Estuarine systems adjacent to urban areas are at risk of contamination by contaminants from anthropogenic sources, such as heavy metals. We anticipated that the sediments of the Swan River estuary, which runs through metropolitan Perth in Western Australia, would show metal contamination related to industrialization and inputs of stormwater. Total Cu, Pb and Cd concentrations, and Cu, Pb, Cr and Zn inoperationally-defined fractions, were determined inseparate sampling exercises in near-shore sediments ofthe upper Swan River estuary.Total metal concentrations in sediments were not high (maximum values of 297 mg kg-1 for Cu, 184 mg kg-1 for Pb and 0.9 mg kg-1 for Cd) when compared with Australian environmental assessmentguidelines for soils. On the basis of linear regressions between sediment metal concentrations andphysicochemical properties of the sediments (pH, organic carbon, particle size distribution), no single parameter could explain the variation in metal concentrations for all metals. Sediment organic carbon content was positively correlated with Cu concentration; Cu concentrations also increased significantly with increasing clay content anddecreasing sand content. Pb concentrations showed a significant increase with increasing sediment pH, and were approximately three-fold higher in sediments adjacent to stormwater drain outfalls than in sediments remote from drains; no such effect was observed for Cu or Cd. No effect of distance downstream was observed. Sequential extraction of sediments showed that most of the metals were in relatively immobile forms, for example bound to Feoxides, or only extractable by aqua regia. The enhanced concentrations of Pb near stormwater outfalls suggest that vehicle-derived Pb may be an important contributor of Pb to the estuary.
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  • 44
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    Water, air & soil pollution 89 (1996), S. 317-335 
    ISSN: 1573-2932
    Keywords: Soil remediation ; extraction ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Effective remediation and sanitation technologies for soils contaminated with heavy metals are limited. We investigated the feasibility of a counter-current metal extraction procedure for the removal of selected heavy metals (Cd, Cu, Ph, and Zn) from two contaminated soils. The process involved a decarbonation (removal of carbonates), acid solubilisation, washing, and liming step. Results from batch equilibration experiments simulating the counter-current process showed more than 85% of the Cd present to be removed. Removal efficiencies for Cu and Pb were limited to approximately 15%, this mainly due to resorption of these elements during the decarbonation step. As most Zn was found to be present in a more difficult acid-extractable solid phase, its extractability accounted for only 25%. While reaction (pH) conditions of both decarbonation and solubilisation determined removal efficiencies, washing the extracted soil with deionized water only slightly increased the amount of metals removed. Metal distribution among solid phases — exchangeable, carbonate, reducible, organically bound, and residual — was affected by the different treatments. The amount of metals contained in the exchangeable and residual fractions determined their extractability. Except for Cu, the reducible and organically bound fractions were less important. After solubilisation 13 to 70% of the metals were present in an exchangeable solid phase. This implicates that washing the solubilized soil with a salt may increase the extractability of metals, especially for Zn and Pb. Based on our results the process is critically evaluated and possibilities for optimization formulated.
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  • 45
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    Water, air & soil pollution 90 (1996), S. 543-556 
    ISSN: 1573-2932
    Keywords: heavy metals ; solubility ; redox potential ; pH ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract To assess the mobilities of Pb, Cd, and Zn from a contaminated soil, the effects of redox potential and pH value on metal solubilities were investigated. Both redox potential and pH were found to greatly affect heavy metal solubility in the soil. Results showed that the soil suspension under continuous oxygen aeration for 21 days resulted in increases of redox potential from 290 to 440 mV and pH value from 6.9 to 7.0, respectively. Soluble concentrations of Pb, Cd, and Zn varied with time, and were all lower than 1 mg kg−1. When the soil suspension was aerated with nitrogen, final redox potential was −140 mV and pH value of 7.1. The soluble metal concentrations were slightly higher than those aerated with oxygen. The equilibrium solubility experiments were conducted under three different pH values (3.3, 5.0, 8.0) and three redox potential (325, 0, −100 mV). Results showed that metals were sparingly soluble under alkaline conditions (pH = 8.0). Metal solubilities were higher when under slightly acidic conditions (pH = 5.0), and increased drastically when pH was kept at 3.3. When solubilities were compared under same pH values, it was observed that metal solubilities increased as redox potential decreased. Generally speaking, acidic and reducing conditions were most favorable for metal solubilization, and the effect of pH was more significant than that of redox potential. It was proposed that heavy metals were mostly adsorbed onto Fe-Mn oxyhydroxides. The pH-dependent metal adsorption reaction and the dissolution of Fe-Mn oxyhydroxides under reducing conditions was the mechanism controlling the release of heavy metals from soils.
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  • 46
    ISSN: 1573-2932
    Keywords: heavy metals ; TNR ; stream sediments ; Suquía River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Suquía is a semiarid (rainfall, 700-900 mm y-1), medium-size (7700 km2) riversystem located in central Argentina. Its mountainous upper catchment includes pristine areas aswell as a variety of human settlements and a reservoir lake. A large city (Córdoba, ca. 1.3million inhabitants) and a terminal hypersaline lake are included in the middle and lower basin.Total non-residual (TNR) heavy metals (Pb, Cu, Ni, Zn, Mn, and Fe) have been determined inriver bed sediments in two seasons (spring and autumn), seeking to establish the factors whichcontrol the temporal and spatial variability. The major findings were: a) concentrations of TNRmetals were, in general, higher during springtime than during autumn, particularly downstreamfrom the city of Córdoba; b) organic matter played a significant role as a controlling factorwherever it defined reducing conditions, lowering the concentrations of Mn and Fe hydrousoxides; c) a higher organic load (e.g., downstream the city) and more pronounced reducingconditions could be the causes for the increased Fe concentration, probably precipitated assulfides; d) organic matter exhibited a closer correlation with some TNR metals in autumn,probably caused by a larger capacity for complexation in the biologically-processed organicdebris; and, e) the existence of pristine areas in the drainage basin allowed for the calculation ofenrichment factors (EF) which show the significance of several environmental impacts in theSuquía system.
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  • 47
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    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsulawere surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kolasmelters were on an average twice as high as on the Finnish side of the border. The Cu and Niconcentrations near the smelters were almost 100-fold the mean values in northern Finland. Therewas a marked decrease in the sulphur and heavy metal concentrations with increasing distancefrom the emission sources. The effects of emissions from the Kola Peninsula were evident inFinland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland)where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur andheavy metal concentrations in most of northern Finland were low. However were theconcentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissionsfrom the Tornio refined steel plants.
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  • 48
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    Water, air & soil pollution 93 (1997), S. 409-417 
    ISSN: 1573-2932
    Keywords: CO2 evolution ; heavy metals ; loading effect ; metal equivalent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a laboratory study the effects on soil respiration of trace metals (Ni, Cd, Cu, Mn, Pb, Zn)added at loading rates ranging from 0 to 1000 µg g-1 were determined. Differences intoxicity with respect to the type of metal salt added were also evaluated. The inhibitory effect onsoil respiration differed considerably among the heavy metals and increased with the increasingloading rate. No linear relationships were found between the degree of inhibition and the levels oftotal and available metals. Toxicity evaluation at 20 and 50% inhibition of soil respiration showedCu as the most toxic and Mn as the most tolerable metal. A ‘metal equivalent’ was calculated asthe sum of the amounts of the available metals weighted to their relative toxicity with respect tothe least toxic one: Mn equivalent = Mn + 1.9Pb + 2.1Ni + 2.5Zn + 6.7Cd + 6.7Cu. The ionicpotential of the heavy metals was found to be positively related to the percent inhibition of soilrespiration. Chlorides and sulphates appeared to depress soil respiration more than nitrates, thelatter counter-balancing the toxic effect of the heavy metals.
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  • 49
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    Water, air & soil pollution 93 (1997), S. 93-108 
    ISSN: 1573-2932
    Keywords: straw ash ; ashes ; bottom ash ; fly ash ; biofuel ; cereal straw ; rape straw ; straw combustion ; fertilizer ; plant nutrients ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The composition of 79 samples of straw ash from seven heating plants in Sweden wasanalysed with the aim of evaluating straw ash as a fertilizer and liming agent. The variation in ashcomposition was explained mainly by ash fraction (bottom ash vs. fly ash) and straw type (wheat,barley, rye, rape) but also by heating plant. Compared with concentrations of Zn, Pb and Cd inbottom ash, levels in fly ash were 10-90 times higher. Fly ash also contained more Cu and Kcompared with bottom ash. The Cd/P ratio was 0.03 in bottom ash and 0.6 g Cd/kg P in fly ash.Ash from rape straw had a higher Ca content and liming effect compared with ash from cerealstraw; e.g., the liming effect of rape ash was more than three times higher than that of wheat ash.The liming effect varied between 3.5 and 44% CaO and depended mainly on the Ca content. Theaverage P content was 1.7% (0.2-4.4%), with slightly higher concentration in rape ash than inwheat ash. The potential for using straw ash as a fertilizer and liming agent is discussed. Compared withcommercial fertilizers the use of bottom ash as a P fertilizer results in a lower addition of Cd.However, the total heavy metal content of straw ash poses a potential problem.
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  • 50
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    Water, air & soil pollution 99 (1997), S. 615-622 
    ISSN: 1573-2932
    Keywords: Near-shore sediments ; heavy metals ; bioindicators ; bivalves ; benthic populations ; multivariate analysis ; multiple regression analysis ; predictive models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Copper, lead, cadmium, zinc, chromium, manganese, iron and nickel were determined in near-shore sediments in the harbour of Trieste (Northern Adriatic), in an area highly exposed to urban and industrial wastes, where severe alteration of benthic population was observed. A typical bivalve of this area, Corbula gibba, was used as bioindicator of sea-bottom pollution. Multivariate statistical analysis of the chemical data interpret concentrations and distributions of heavy metals in these sediments, attesting anthropogenic source for Cu, Pb, Cd and Zn. Using labile fractions of heavy metals in sediments as 'predictors', and length or biomass of the bivalve as dependent variables, we obtained, by a multiple regression procedure, a predictive model showing the influence of metals on this benthic organism of this polluted area.
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    Water, air & soil pollution 99 (1997), S. 651-659 
    ISSN: 1573-2932
    Keywords: River sediments ; biofilms ; organic micropollutants ; heavy metals ; temporal variations ; biosorption ; accumulation processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a partly urbanized catchment to the south of Trier, Germany, short term variations in river sediment compounds as well as the bioaccumulation of pollutants on surface associated microbial coatings (biofilms) were investigated weekly during a period of six months. Concentrations of selected heavy metals (Cu, Zn, Pb), polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and for microbial characterisation protein, carbohydrate and uronic acid were analyzed. Sorption processes on biofilms were determined by temporal variations in pollutants and microbial parameters and through the comparison of sorbed substances in biofilms and sediments. The results show, that sorption events on biofilms play an important and dynamic role in spring and summer for transport and accumulation of the investigated pollutants in the aquatic environment. The amount of pollutants sorbed on sediment particles is not only dependent on the particulate bound or solved pollutants in the river water, but is strongly controlled by the changing conditions of the biofilms.
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  • 52
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    Water, air & soil pollution 94 (1997), S. 361-372 
    ISSN: 1573-2932
    Keywords: heavy metals ; contamination ; mobilization ; cadmium ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Analysis of spatial distribution of sewage-sludge born cadmium on the experimental plot revealed positive correlation of total cadmium and organic matter. Soil pH fluctuated randomly on the field. ‘Bioavailable’ concentrations, as determined by NH4-acetate extraction, were closely correlated to the total cadmium levels, and only negligible effects of pH and/or organic matter fluctuations were recorded. Desorption model using modified Freundlich isotherm was applied to predict risks of cadmium solubilization at different conditions. Simulations revealed that the organic matter content within the ranges found at the experimental field cannot support a proper immobilization of cadmium at pH-range observed at the field. The phenomenon was explained by ineffective care for the soil in the past.
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  • 53
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    Water, air & soil pollution 99 (1997), S. 651-659 
    ISSN: 1573-2932
    Keywords: River sediments ; biofilms ; organic micropollutants ; heavy metals ; temporal variations ; biosorption ; accumulation processes
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a partly urbanized catchment to the south of Trier, Germany, short term variations in river sediment compounds as well as the bioaccumulation of pollutants on surface associated microbial coatings (biofilms) were investigated weekly during a period of six months. Concentrations of selected heavy metals (Cu, Zn, Pb), polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and for microbial characterisation protein, carbohydrate and uronic acid were analyzed. Sorption processes on biofilms were determined by temporal variations in pollutants and microbial parameters and through the comparison of sorbed substances in biofilms and sediments. The results show, that sorption events on biofilms play an important and dynamic role in spring and summer for transport and accumulation of the investigated pollutants in the aquatic environment. The amount of pollutants sorbed on sediment particles is not only dependent on the particulate bound or solved pollutants in the river water, but is strongly controlled by the changing conditions of the biofilms.
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  • 54
    ISSN: 1573-2932
    Keywords: fractionation ; redistribution ; saturation ; kinetics ; heavy metals
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function,U ts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (GARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. TheU ts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
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  • 55
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    Water, air & soil pollution 96 (1997), S. 39-59 
    ISSN: 1573-2932
    Keywords: acid mine drainage ; heavy metals ; jarosite ; soils ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The discharge of acidic mine drainage waters onto a hillslope in Dalarna, central Sweden, has lead to the contamination of the podzol soils with Cu, Fe, Ni, Pb, Zn and sulfate. Samples from contaminated and reference soils have been collected for chemical and mineralogical analyses. Jarosite is identified by x-ray diffraction analysis as a precipitate in the upper horizons (A, E, B) of the contaminated soils, where the soil acidity (pHKCl ∼ 2.6) promotes jarosite stability. The sequential chemical extraction of soil samples indicates that, in the reference A horizon, Cu, Pb, Ni and Zn are bound primarily to cation exchange sites and organic matter. In the A horizon of the contaminated soils closest to the rock dump, metal partitioning is dominated by the Fe oxide fractions, despite the high organic matter content; Pb is almost completely bound to crystalline Fe oxides, possibly adsorbed to Fe oxides or occuring in a jarosite solid solution. In the reference B and C horizons, Cu, Ni and Zn are primarily adsorbed/coprecipitated in the Fe oxide fractions, while Pb remains with a large fraction bound to organic matter. In the Fe-rich B horizon of the contaminated soils, the partitioning of the metals in cation exchange sites and to organic matter has greatly increased relative to the reference soils, resulting from the mobilization of organo-metal complexes down the profile.
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  • 56
    ISSN: 1573-2932
    Keywords: critical load ; deposition ; heavy metals ; persistent organic pollutants ; soil quality ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the pilot study ESQUAD the impact of atmospheric deposition of three heavy metals (cadmium, copper and lead) and two persistent organic pollutants (benzo(a)-pyrene and lindane) on the quality of European soils and seawater has been calculated. Calculations have been made of atmospheric transport and deposition using a detailed emissions database for Europe. This enabled deposition maps to be produced to a resolution of approximately 50 km. The distribution of pollutant concentrations in forest soils was calculated for each grid cell using a database of soil property parameters in Europe. For the North Sea, a model was used to map long-term concentrations in water and sediment, which are due to atmospheric deposition and other, non-atmospheric sources. The model calculations allowed detailed comparisons of deposition fluxes and concentrations of the substances studied with critical loads and environmental quality threshold values, including critical loads. Although significant uncertainties were identified, the study gives insight in how threshold exceedance rates in Europe relate to pollutant type, threshold type, environmental compartment and chemophysical phase (adsorbed, dissolved). For all pollutants and for all compartments exceedances were calculated for at least some of the quality thresholds that were chosen.
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  • 57
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    Water, air & soil pollution 112 (1999), S. 21-40 
    ISSN: 1573-2932
    Keywords: China ; eutrophication ; heavy metals ; palaeolimnology ; spheroidal carbonaceous particles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract There is growing concern about the environmental impact of rapid economic growth in China. The problem is compounded by the scarcity of baseline data on the state of China's natural environment. As a step towards solving this problem, palaeolimnological methods have been applied to seven lakes in the Jianghan Plain, China, to evaluate recent changes in human impact. Lake sediment cores show enhanced concentrations of fossil fuel derived spheroidal carbonaceous particles (SCP) and Pb at all sites across the Jianghan Plain. The distribution of these industrial contaminants shows the overwhelming influence of the industrial cities. Wuhan dominates the fossil fuel derived pollution, while the copper smelter at Daye dominates the heavy metal pollution. Analysis of sediment diatom assemblages indicates mean total phosphorus concentrations of greater than 40 μg L-1 P in the lakes of the more intensely agricultural western part of the Jianghan Plain. The sediment concentration profiles for biogenic elements at these sites indicates a post-1960 eutrophication. Evidence for eutrophication in the eastern lakes is much weaker, though some evidence is present at all sites. The tracers of industrial pollution (Pb and SCP) correlate with Mn in the many of the lake sediments. This is compatible with both soil acidification, and soil gleyification due to intensified rice production.
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    Water, air & soil pollution 112 (1999), S. 349-363 
    ISSN: 1573-2932
    Keywords: aerosols ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract An extensive study of the different heavy metals (Fe, Mn Ni, Cr, Zn, Cd, Pb, Cu) present in the atmospheric aerosols collected at two stations in Mallorca located in the evirons of a new incinerator plant has been carried out. The aim of this study is to establish the quality of the air surrounding this new MSW (Municipal Solid Waste) incinerator on the island of Mallorca prior to its setting up. Besides, a study of the distribution of the analyzed metals in both the fine (diameter ≤1.5 μm) and coarse (diameter ≥1.5 μm) fractions of the aerosol has been performed. Concentrations of heavy metals in the atmospheric aerosols prior to the running of the new incinerator plant were found to be very low and similar to the values obtained at other Mediterranean stations.
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  • 59
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    Water, air & soil pollution 113 (1999), S. 115-125 
    ISSN: 1573-2932
    Keywords: adsorption ; clay ; desorption ; heavy metals
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study evaluated the effect of competing copper, zinc, cadmium and nickel ions in 0.01 M Ca(NO3)2 on heavy metal sorption and desorption by soil clay fractions. Initial Cu addition levels varied from 99 mg kg-1 to 900 mg kg-1 and Zn, Cd and Ni levels were 94, 131 and 99 mg kg-1, respectively. Sorption of Cu conformed to a Freundlich equation. The amounts of metals not displaced by successive 48 h desorption cycles with 0.01 M Ca(NO3)2 were considered ‘specifically adsorbed’. Total sorption of Zn and Cd generally decreased in the order: Vertisol 〉 Gleyic Acrisol 〉 Planosol clay. More than 70% of the copper was specifically sorbed. Specific sorption of Zn was depressed by competition with Cu in the three clays investigated. At surface coverages higher than 200 mg Cu per kg of soil clay, zinc sorption in the Planosol and Gleyic Acrisol clays took place at low affinity sites. The exchangeable component of sorbed cadmium accounted for 〉:60% of the sorption in the Vertisol clay, 〉70% in the Gleyic Acrisol clay and was almost 100% in the Planosol clay. Nickel was not retained by the Planosol and Gleyic Acrisol clays and was ionexchangeably adsorbed by the Vertisol clay. At the conditions studied, Ni and Cd remain a ready source of pollution hazard.
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    Water, air & soil pollution 113 (1999), S. 261-272 
    ISSN: 1573-2932
    Keywords: coal fly ash ; heavy metals ; nutrient cycling ; sewage sludge ; soil enzymes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Previous studies showed that coal fly ash could stabilize sewage sludge by reducing metal availability, but fly ash may cause an adverse effect on soil microbial activities. Therefore, an experiment was performed to evaluate the effects of amendment of soil with anaerobically digested dewatered sewage sludge, stabilised with alkaline coal fly ash, on soil enzyme activity and the implications for soil nutrient cycling. Sewage sludge was amended with 0, 5, 10, 35 and 50% w/w of fly ash, and then the ash-sludge mixtures were incubated with a sandy soil at 1:1 (v/v). Dehydrogenase activity decreased with an increase in fly ash amendment level and the time of incubation. Soil receiving 5% ash-sludge amendment had a higher dehydrogenase activity than other treatments. Soil receiving 10% ash-sludge mixture had the highest urease activity and in general, urease activity decreased with increasing incubation time. Phosphatase activity was the highest at 5% ash-sludge mixture amended soil and no general trend was observed with time. Water-soluble Zn, Mn and Cu contents were suppressed by the addition of fly ash. The present experiment indicated that addition of 10% ash-sludge mixture should have a positive benefit on the activity of soil microorganisms, N and P nutrient cycling, and reduce the availability of heavy metals.
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    Water, air & soil pollution 114 (1999), S. 251-276 
    ISSN: 1573-2932
    Keywords: canola meal ; energy dispersive X-ray ; heavy metals ; scanning electron microscopy ; sorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The results from this research indicate that canola meal (CM) can be used for adsorption of Zn2+, Cd2+, Cu2+, Pb2+and Ni2+from aqueous solutions. The order of sorption for these metals in single metal systems was as follows (molar basis): Zn2+〉 Cu2+〉 Cd2+〉 Ni2+〉 Pb2+. It was noted that a decrease in the concentration of CM caused a higher metal loading on the meal. Increases in the metal concentration, temperature or pH resulted in increased sorption of the metals by the meal. The systems with identical ratios of CM to Zn2+concentrations, regardless of their levels, resulted in the same amount of metal adsorbed per unit weight of meal. The Freundlich isotherm type model was used in this study and was found to fit the experimental equilibrium concentration data of Zn2+and Cd2+; however, the Langmuir isotherm model fit only the equilibrium data of Zn2+. Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray (EDX) microanalyses revealed that the metal ions were sorbed mainly at the cell wall and only small amounts of ions diffused into the cytoplasm of the CM cells. The Electron Spin Resonance (ESR) tests were inconclusive regarding the direct participation of free radicals in copper sorption.
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  • 62
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    Water, air & soil pollution 114 (1999), S. 339-346 
    ISSN: 1573-2932
    Keywords: biomonitoring indices ; germination ; heavy metals ; lead ; mercury ; rice ; seedling growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Treatment of seeds of two rice (Oryza sativa L.) cultivars (Ratna and IR36) separately with 10-5and 10-4M PbCl2and HgCl2decreased germination percentage, germination index (GI), shoot and root length, tolerance index (TI), vigour index (VI) and dry mass of shoot and root but increased percentage difference from control (% DFC) of germination and percentage phytotoxicity in both the cultivars. It was observed from these indices that the phytotoxic effect of mercury was greater than lead at identical concentrations and that IR36 appeared more tolerant than Ratna to these metals. Among the monitoring indices examined, TI, VI, and % phytotoxicity seemed to serve as good biological monitoring methods for evaluating the relative toxicity of lead and mercury to rice cultivars.
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  • 63
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    Water, air & soil pollution 115 (1999), S. 347-361 
    ISSN: 1573-2932
    Keywords: Bangladesh ; contamination ; heavy metals ; soils ; vegetation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A study was conducted to investigate the heavy metal contamination of soil and vegetation in the vicinity of industries around Dhaka city in Bangladesh. Categorically soils, grass (Cynoden doctylon L), water hyacinth (Eichhornia crassipes L), rice (Oryza sative L), and arum (Alocasia esculenta L) were collected from tannery, ceramic, textile dying and sulphuric acid producing industrial sites. The concentrations of total Cd, Cu, Mn, Ni, Pb and Zn ranged from 0.1–1.8, 28–217, 106–577, 25–112, 17–99 and 53–477 mg kg−1 soil, respectively among the industrial sites. The concentrations of some heavy metals ranged from background levels to levels in excess of tolerable limits in agricultural soils. The concentrations of total Cu, Mn, Ni, Pb and Zn decreased with increasing distance from the disposal points of the tannery and the textile dying industries. Cadmium, Cu, Mn, Ni, Pb and Zn showed highly significant (p 〈 0.01) positive correlations with their total and DTPA-extractable contents in soils. The concentrations of most heavy metals were also higher in the vegetation samples of tannery area and the content of Pb (13–45 mg kg−1) in grass samples exceeded the toxic limit. In correlation matrix, plant concentrations of Cu, Mn, Pb and Zn were significantly correlated with their total and extractable contents in soils.
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    Water, air & soil pollution 115 (1999), S. 385-394 
    ISSN: 1573-2932
    Keywords: ferrite sludge ; heavy metals ; magnetic separation ; wastewater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The purification of wastewater containing dissolved metal ions by in situ precipitation gives rise to a sludge composed mainly of ferrites MeXFe3-xO4 (where Me represents the existing metal ions in the wastewater). Oxides, iron oxy-hydroxides and other impurities are also present in the sludge in smaller proportion. The present investigation proposes magnetic separation of the sludge to recover the ferrites for their possible re-use. Under optimum operating conditions of the magnetic separator, a recovery efficiency of the magnetic fraction in excess of 99% and a high degree of selectivity were obtained.
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    Water, air & soil pollution 115 (1999), S. 465-479 
    ISSN: 1573-2932
    Keywords: gravel sludge ; heavy metals ; immobilization ; soil remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Field plot studies were conducted on sandy loam soils in Dottikon, Rafz and Giornico contaminated by Zn, Cu and Cd to investigate the effectiveness of gravel sludge as an in situ immobilization additive. In addition to NaNO3-extractable heavy metal concentrations in the soil, metal concentrations in ryegrass (Lolium perenne L.) and lettuce (Lactuca sativa L.) were analyzed at two application doses of gravel sludge. Application of gravel sludge increased pH in all three topsoils by up to 0.6 units and reduced NaNO3-extractable Zn concentrations by more than 65%. No effect was seen for the NaNO3-extractable Cu concentrations in Rafz and even an increase resulted in Giornico. In Dottikon, gravel sludge additions decreased the NaNO3-extractable Cu concentrations from 0.97 to 0.7 mg kg−1 and reduced the concentrations of Zn and Cu by more than 35% in ryegrass. For lettuce grown in Giornico and Dottikon, we found reductions of Zn and Cd concentrations by 22 to 48%, whereas in Rafz, no significant variations were found. Immobilization by gravel sludge was most efficient in soils with high total/NaNO3-extractable heavy metal ratio and more effective for ryegrass than for lettuce. Part of the immobilization effect was due to a pH increase, caused by CaCO3 in gravel sludge.
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  • 66
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    Water, air & soil pollution 114 (1999), S. 413-421 
    ISSN: 1573-2932
    Keywords: heavy metals ; incineration ; medical waste ; Taiwan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The purpose of this study was threefold: to investigate the types and amounts of medical waste from various hospitals in Taiwan; to analyze residues from incinerated medical waste for heavy metal content; and to measure the amount of infectious and general medical waste per bed per day and determine the ratio of infectious to general medical waste. Information was first obtained on the amounts of medical waste produced per bed per day and on waste handling and treatment. Next, residue samples were taken from incinerators and analyzed for heavy metal content. Third, daily records concerning waste content and weight from one hospital were kept over the period of one year. Chromium (Cr) and zinc (Zn) concentrations were significantly higher in medical waste than in general waste. Medical waste fluctuated significantly over the one-year period. Records showed that wastes containing dialysis material and wood/cotton materials were found to have the highest weight and wastes containing human organs had the lowest weight. Results of the present study underscore the need for all hospitals to effectively separate waste for proper treatment and disposal, particularly waste that produces residues which may be hazardous to the environment. In addition, hospitals also need to recycle or reuse certain materials in order to reduce waste production.
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  • 67
    ISSN: 1573-2932
    Keywords: anaerobic bacteria ; heavy metals ; organic matter ; toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The present study reports on the effect of Fe2+, Ni2+ and CO2+ on anaerobic bacterial activity and dynamics during anaerobic mineralization of organic matter. Fe2+ stimulated biogas yield and methane content at 37 °C, but inhibited same marginally at low temperatures (10 and 20 °C). Ni2+ and CO2+ inhibited methane production; the toxicity increased with decreasing temperature. Fe2+ stimulated sulfate reducing bacterial (SRB) and methane producing bacterial (MPB) counts while Ni2+ and CO2+ inhibited the same. All the metals had no effect on obligate proton reducing bacterial (OPRB) counts. Fe2+ stimulated, Ni2+ severely and CO2+ appreciably inhibited H2 uptake and acetate/propionate utilization irrespective of presence/absence of sulfate. Thus, Ni2+ and CO2+ inhibited the overall anaerobic degradative process by inhibiting SRB and MPB activity.
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  • 68
    ISSN: 1573-2932
    Keywords: heavy metals ; pretreatment ; sediment ; speciation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The identification of the geochemical forms of heavy metals in contaminated sediments gives information on their availability. This requires the use of a geochemical speciation procedure such as the one developed by Tessier et al. (1979). In addition to the imperfections of these protocols, their results can vary depending on the technique used for the preservation of sediments which must be suited to the materials studied and to particularities of the investigation. This study was carried out on superficial river sediments, seriously polluted by Cu, Cd and Pb. Compared to fresh sediment, none of the drying methods studied (freeze-drying, air-drying and oven-drying at 105 °C) completely preserve the distribution of Cu, Pb, Zn and Cd in the various geochemical fractions of the sediment. The modifications depend directly on the quantities of metals present in the various fractions of the sediment, the effects being more marked when the quantity is smallest. This results in a decrease in metals in the exchangeable fraction and in those bound to carbonates under the action of atmospheric oxygen and a corresponding increase in the other fractions. To minimize this, freeze-drying and air-drying are satisfactory techniques which enable preservation of sediments representative of the environment.
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  • 69
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    Water, air & soil pollution 85 (1995), S. 829-834 
    ISSN: 1573-2932
    Keywords: Birds ; Parus major ; heavy metals ; persistent organic substances ; breeding ; nestling development ; Hb
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Breeding performance of Great tit (Parus major) was studied in two forests in southern Poland, in the districts of Cracow and Katowice, and in a Swedish reference area. Concentrations of Cd, Cu, Fe, Pb, Zn, methyl Hg, ΣDDT, and ΣPCB in tissues of nestlings, were monitored. The birds′ tissue concentrations of the nonessential elements, Cd and Pb, were elevated at the Polish localities, and reflected the degree of environmental contamination. ΣDDT levels were higher in the Polish birds than in the Swedish. Breeding results of the birds were severely affected in southern Poland, and high frequencies of the fledged young showed low Hb.
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  • 70
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    Water, air & soil pollution 90 (1996), S. 531-542 
    ISSN: 1573-2932
    Keywords: heavy metals ; smelting ; soil contamination ; plant contamination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Forms of Cu, Ni, and Zn in the contaminated soils of the Sudbury mining/smelting district were studied to assess metal mobility and plant availability. Soil, tufted grass (Deschampsia caespitosa (L.) Beauv.), tickle grass (Agrostis scabra Willd.), dwarf birch (Betula pumila L. var. glandulifera Regel) and white birch (Betula paprifera Marsh.) leaf and twig samples were taken from 20 locations around three Cu-Ni smelters. The sampling sites were collected to cover a wide range of soil pH and soil Cu and Ni concentrations. The water-soluble, exchangeable, sodium acetate-soluble, and total concentrations of the metals in the soils were analyzed. The soils were contaminated with Cu and Ni up to 2000 µg g−1. Zinc concentrations were also elevated in some samples above the normal soil level of 100 µg g−1. The mobility of Cu and Zn, expressed as the proportion of metals in Fl and F2 forms, increased with soil pH decrease. A strong positive correlation was found between the soil exchangeable (F2) Ni and the soil pH. Concentrations of Cu and Ni in birch twigs showed a good linear relationship with exchangeable forms of the metals in soils. A highly significant correlation was also found between total Ni in soils and the metal content of the twigs. No significant correlation was found between Zn concentrations in the soils and plants. Birch twigs are a good indicator (better than leaves) of Cu and Ni contamination of the Sudbury soils. The mobile forms of Cu and Ni and low pH seem to be the main factors that will control the success of revegetation. Strong variability of the soil metal mobility requires any reclamation effort be site-specific.
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  • 71
    ISSN: 1573-2932
    Keywords: Acari ; bioindicators ; Gamasida ; heavy metals ; Oribatida ; Scots pine forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The soil mites were investigated in the areas covered with dead needles in young Scots pine forests (plant association Leucobryo-Pinetum), polluted by a copper smelting works at Głogów, and in a control plot. The concentration of heavy metals, mainly copper and lead, was the lowest in the control plot, and increased towards the pollution source. A high concentration of these metals reduced the density of mites and species number of Oribatida and Gamasida, while small concentrations were associated with the increasing abundance of mites and species number of Oribatida. Among mites, the following categories were distinguished: a) sensitive to heavy metals, b) sensitive to a high concentration, but tolerant of small concentrations, and c) tolerant of these metals. The changed vertical distribution of mites in the most polluted soil was also observed, due to accumulation of heavy metals in the Of/h horizon.
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  • 72
    ISSN: 1573-2932
    Keywords: heavy metals ; TNR ; stream sediments ; Suquía River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Suquía is a semiarid (rainfall, 700–900 mm y−1), medium-size (7700 km2) river system located in central Argentina. Its mountainous upper catchment includes pristine areas as well as a variety of human settlements and a reservoir lake. A large city (Córdoba, ca. 1.3 million inhabitants) and a terminal hypersaline lake are included in the middle and lower basin. Total non-residual (TNR) heavy metals (Pb, Cu, Ni, Zn, Mn, and Fe) have been determined in river bed sediments in two seasons (spring and autumn), seeking to establish the factors which control the temporal and spatial variability. The major findings were: a) concentrations of TNR metals were, in general, higher during springtime than during autumn, particularly downstream from the city of Córdoba; b) organic matter played a significant role as a controlling factor wherever it defined reducing conditions, lowering the concentrations of Mn and Fe hydrous oxides; c) a higher organic load (e.g., downstream the city) and more pronounced reducing conditions could be the causes for the increased Fe concentration, probably precipitated as sulfides; d) organic matter exhibited a closer correlation with some TNR metals in autumn, probably caused by a larger capacity for complexation in the biologically-processed organic debris; and, e) the existence of pristine areas in the drainage basin allowed for the calculation of enrichment factors (EF) which show the significance of several environmental impacts in the Suquía system.
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  • 73
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    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsula were surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kola smelters were on an average twice as high as on the Finnish side of the border. The Cu and Ni concentrations near the smelters were almost 100-fold the mean values in northern Finland. There was a marked decrease in the sulphur and heavy metal concentrations with increasing distance from the emission sources. The effects of emission from the Kola Peninsula were evident in Finland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland) where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur and heavy metal concentrations in most of northern Finland were low. However were the concentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissions from the Tornio refined steel plants.
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  • 74
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    Water, air & soil pollution 93 (1997), S. 409-417 
    ISSN: 1573-2932
    Keywords: CO2 evolution ; heavy metals ; loading effect ; metal equivalent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a laboratory study the effects on soil respiration of trace metals (Ni, Cd, Cu, Mn, Pb, Zn) added at loading rates ranging from 0 to 1000μg g−1 were determined. Differences in toxicity with respect to the type of metal salt added were also evaluated. The inhibitory effect on soil respiration differed considerably among the heavy metals and increased with the increasing loading rate. No linear relationships were found between the degree of inhibition and the levels of total and available metals. Toxicity evaluation at 20 and 50% inhibition of soil respiration showed Cu as the most toxic and Mn as the most tolerable metal. A ‘metal equivalent’ was calculated as the sum of the amounts of the available metals weighted to their relative toxicity with respect to the least toxic one: Mn equivalent=Mn+1.9Pb+2.1Ni+2.5Zn+6.7Cd+6.7Cu. The ionic potential of the heavy metals was found to be positively related to the percent inhibition of soil respiration. Chlorides and sulphates appeared to depress soil respiration more than nitrates, the latter counter-balancing the toxic effect of the heavy metals.
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  • 75
    ISSN: 1573-2932
    Keywords: soil ; pollution ; heavy metals ; smelters ; factoranalysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
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  • 76
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    Water, air & soil pollution 94 (1997), S. 361-372 
    ISSN: 1573-2932
    Keywords: heavy metals ; contamination ; mobilization ; cadmium ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Analysis of spatial distribution of sewage-sludge born cadmium on the experimental plot revealed positive correlation of total cadmium and organic matter. Soil pH fluctuated randomly on the field. ‘Bioavailable’ concentrations, as determined by NH4-acetate extraction, were closely correlated to the total cadmium levels, and only negligible effects of pH and/or organic matter fluctuations were recorded. Desorption model using modified Freundlich isotherm was applied to predict risks of cadmium solubilization at different conditions. Simulations revealed that the organic matter content within the ranges found at the experimental field cannot support a proper immobilization of cadmium at pH-range observed at the field. The phenomenon was explained by ineffective care for the soil in the past.
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  • 77
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    Water, air & soil pollution 99 (1997), S. 615-622 
    ISSN: 1573-2932
    Keywords: Near-shore sediments ; heavy metals ; bioindicators ; bivalves ; benthic populations ; multivariate analysis ; multiple regression analysis ; predictive models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Copper, lead, cadmium, zinc, chromium, manganese, iron and nickel were determined in near-shore sediments in the harbour of Trieste (Northern Adriatic), in an area highly exposed to urban and industrial wastes, where severe alteration of benthic population was observed. A typical bivalve of this area,Corbula gibba, was used as bioindicator of sea-bottom pollution. Multivariate statistical analysis of the chemical data interpret concentrations and distributions of heavy metals in these sediments, attesting anthropogenic source for Cu, Pb, Cd and Zn. Using labile fractions of heavy metals in sediments as ‘predictors’, and length or bionnass of the bivalve as dependent variables, we obtained, by a multiple regression procedure, a predictive model showing the influence of metals on this benthic organism of this polluted area.
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  • 78
    ISSN: 1573-2932
    Keywords: fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function, Uts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (CARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. The Uts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
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  • 79
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    Water, air & soil pollution 95 (1997), S. 119-131 
    ISSN: 1573-2932
    Keywords: geochemical investigations ; geochemical validation ; heavy metals ; ICP-AES ; environmental monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A little known alternative to highcost environmental analysis, especially in Europe, is the use of commercially available, lowcost exploration geochemical laboratory analysis. To test for suitable accuracy and precision, both indicated parameters were monitored during several sample runs for environmental examinations at a selected commercial geochemical laboratory using various digestive methods and ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometry). By evaluating duplicate samples and repeated measurements of internal standards and comparing the results with precision needed for environmental investigations, exploration geochemical analysis is found to be more than adequate for most elements and digestive methods in environmental applications. Accuracy is highest for total digestion ICP-AES analysis, with expectedly greater error margins for aqua regia digestion. Lowcost exploration geochemical analysis is an inexpensive analytical tool for screening, detailed investigations and monitoring of contaminated sites.
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  • 80
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    Risk analysis 18 (1998), S. 563-573 
    ISSN: 1539-6924
    Keywords: Risk assessment ; mourning doves ; hunting ; radionuclides ; heavy metals ; lead shot ; cesium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Recreational and subsistence hunters and anglers consume a wide range of species, including birds, mammals, fish and shellfish, some of which represent significant exposure pathways for environmental toxic agents. This study focuses on the Department of Energy's (DOE's) Savannah River Site (SRS), a former nuclear weapons production facility in South Carolina. The potential risk of contaminant intake from consuming mourning doves (Zenaida macroura), the most popular United States game bird, was examined under various risk scenarios. For all of these scenarios we used the mean tissue concentration of six metals (lead, mercury, cadmium, selenium, chromium, manganese) and radiocesium, in doves collected on and near SRS. We also estimated risk to a child consuming doves that had the maximum contaminant level. We used the cancer slope factor for radiocesium, the Environmental Protection Agencies Uptake/Biokinetic model for lead, and published reference doses for the other metals. As a result of our risk assessments we recommend management of water levels in contaminated reservoirs so that lake bed sediments are not exposed to use by gamebirds and other terrestrial wildlife. Particularly, measures should be taken to insure that the hunting public does not have access to such a site. Our data also indicate that doves on popular hunting areas are exposed to excess lead, suggesting that banning lead shot for doves, as has been done for waterfowl, is desirable.
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  • 81
    ISSN: 1573-2932
    Keywords: bio-accumulation ; heavy metals ; Louisiana ; Parmotrema praesorediosum ; partitioning ; sulfur dioxide ; Tillandsia usneoides ; X-ray micro-probe analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Samples of the epiphytic bromeliad Tillandsia usneoides L. (Bromeliaceae) and the lichen Parmotrema praesorediosum (Nyl.) Hale, growing on bald cypress trees in southern Louisiana, were chemically examined by means of X-ray micro-probe analysis to determine their comparative elemental content. The plants were found to effectively bio-accumulate heavy metals and sulfur from the atmosphere; the accumulatory capacities and implications are discussed. Partitioning occurs within the plants of T. usneoides and consequently any analytical procedure should standardise on precisely which parts are to be analysed. The bio- accumulation of certain heavy metals such as manganese, nickel and cadmium increases with age of the T. usneoides.
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  • 82
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    Water, air & soil pollution 101 (1998), S. 25-44 
    ISSN: 1573-2932
    Keywords: air pollution ; heavy metals ; Isothecium stoloniferum ; moss monitoring/ ; trace elements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The atmospheric heavy metal pollution of the Fraser Valley, B.C., Canada was assessed in 1993 by analyzing 62 samples of the common woodland moss Isothecium stoloniferum for lead, cadmium, nickel, zinc, chromium, and manganese. The latter two metals did not show a distinct regional distribution, but lead, cadmium, nickel, and zinc showed distinct pattern along a west-east gradient. High values were found in the metropolitan Vancouver area, located in the west of the study region. Significantly lower values were recorded for mosses from the eastern more rural areas of the Fraser Valley. Metal pollutants are likely to be contained close to their emission sources by alternating south-east, north-west winds. Highest values overall were found in the North Shore Mountains, adjacent to Vancouver. This was related to higher precipitation and short range pollutant transport from the industrialized, heavily populated areas in the floodplain of the Fraser River.
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  • 83
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    Water, air & soil pollution 114 (1999), S. 377-394 
    ISSN: 1573-2932
    Keywords: heavy metals ; snow quality ; urban snow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The aim of the study was to investigate how the quality of snow varies within a city. The study area is situated in the Luleå municipality, in northern Sweden (lat. 65°35′N and long. 22°10′E). For this study, the city was divided into three different types of areas: housing areas, city centre and outskirts. In one area of each type, sampling sites were selected. Snow samples were taken at nine occasions, once every fourteenth day in the city centre and in the housing area. Analyses were carried out for pH, conductivity, suspended solids and both the total and dissolved concentration of phosphorus and selected metals. It was concluded that traffic or activities related to traffic were a major source of heavy metals and phosphorus in urban snow, both in the city centre and in the housing area. Also, the type of area and the design of the street were important for the quality of snow. A clear relation was found between the pH and the quantity of suspended solids in the snow. Higher pH values were found in snow samples from sites with higher traffic loads, and lower pH values at sites, which were the no-traffic sites, with small quantities of particles. The particulate and dissolved substances in the snow behaved in different ways.
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  • 84
    ISSN: 1573-2932
    Keywords: heavy metals ; leaching ; mobility ; surface runoff ; percolation ; rainfall
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Heavy metals in dredged sedimentdisposal sites may be transported through runoff andpercolation. In the present study metal fluxes byrunoff and percolation were determined under simulatedrainfall at a slope of 19% and a rainfall intensityof approximately 40 mm h-1. These circumstancescorrespond to half the mean annual erosivity of rainunder Belgian weather conditions. Surface runoff andpercolating water samples were analysed for suspendedsolids, total dissolved carbon and Cd, Cr, Cu, Ni, Pb and Zn.Runoff rate and sediment yields were highest for asilt loam sediment, characterised by a low clay andorganic matter content. Metal concentrations in runoffand percolating water varied widely between thesediments studied and were related to the total metalcontent in the sediment. In runoff and percolatingwater from the contaminated sediments, metalconcentrations strongly exceeded the Netherlands Areference values for ground water quality. Very highmetal fluxes were observed for the recently oxidiseddredged sediment. Metal transport per unit surfacearea through percolating water was from two to morethan twenty times greater than that in surface runoff.
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  • 85
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    Water, air & soil pollution 118 (2000), S. 87-99 
    ISSN: 1573-2932
    Keywords: acetic acid extraction ; aqua regiadigestion ; heavy metals ; sediments ; total digestion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sediment analysis is very important ininvestigations of the heavy metal burden in theenvironment. In the present work various digestion andextraction procedures were evaluated in order toassess the extent of contamination with heavy metalsin sediments from the Moste hydroelectric reservoir.Total acid dissolution, aqua regia digestion andacetic acid extraction procedures were applied tosamples. Zn, Cd, Pb, Co, Ni, Cu and Cr were determinedby flame or electrothermal atomic absorptionspectrometry (FAAS, ETAAS) under optimized measurementconditions. A comparison of total acid dissolutionincluding hydrofluoric acid (HF) treatment and theaqua regia soluble fraction was made to estimatethe applicability of aqua regia digestion inanalysis of total metal concentrations in sediments.In general, good agreement of the results was observedfor Co, Pb, Cu and Zn, however for Cr, Ni and Cdsignificantly lower results were obtained in the aqua regia soluble fraction. In addition, an extraction procedure using 25% v/v acetic acid wasapplied for estimation of the extent of contaminationwith heavy metals originating from anthropogenicactivities. The results indicate that the sedimentsupstream of the reservoir are not contaminated, whilethe sediments from the hydroelectric reservoir showsa significant anthropogenic input of Ni, Zn and Pb,which corresponds well with pollution sources.
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    Water, air & soil pollution 119 (2000), S. 295-316 
    ISSN: 1573-2932
    Keywords: air pollution ; atmosphere deposition ; fly ash ; heavy metals ; incineration ; major and trace elements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Because municipal solid waste incineration is onepotential source of air pollution, the incinerationindustry has provoked great public concern, especiallyfor areas within 10–20 km of an incinerator. However,little work has been done to evaluate whetheran incinerator significantly contributes pollutants to nearbyareas. Rain and snow samples were collected at eightlocations distributed in a semi-circular patternradiating out in the prevailing wind direction fromthe Claremont incinerator, New Hampshire, U.S.A. Sodium, Mg, K, Ca, Fe, Al, B, Sr, Ba, Pb, Cr, Cd, V, Ni, Mn, As,Co, Cu, and Zn were analyzed in the solutions of rain and snowand in particulate fractions of rain samples. Principal component analysis was used toidentify the most important sources of atmosphericdeposition in an attempt to identify the contributionof heavy metal deposition due to the incinerator. Analyses show that the predominant sources of metaldeposition are very different for fall and winter. The most important source of metals for the rainsamples collected in fall 1996 is soil dust, but forthe snow samples collected in the winter 1997 isprobably coalfired fly ash. The Claremont incineratorcontributes less than 20% of the total variance of theelemental concentrations.
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  • 87
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    Water, air & soil pollution 120 (2000), S. 29-45 
    ISSN: 1573-2932
    Keywords: geostatistics ; heavy metals ; samplingdesign ; soil contamination ; spatial variability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The choice of a sampling design forassessing soil contamination is a key issue. The leveland spatial pattern of contaminants needs to be takeninto account by those buying, selling or developingsuch land. This paper evaluates sampling design andsize in order to provide satisfactory and efficientestimates of contamination levels. Geostatisticalmethods are used to quantify the spatial dependence ofheavy metals. Semivariance is calculated forlog-transformed data to minimise the effects ofextreme outliers. Several models at different samplingstages are presented for characterising spatialpattern of heavy metals at the investigated site.Variogram models are calculated for a range of samplesizes. The results are assessed by a jack-knifingtechnique and then used for block kriging. The overallconclusion is that a sample size of 50 to 60 isoptimal for characterising variability incontamination levels at an old industrial site of 6.25 ha.
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  • 88
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    Water, air & soil pollution 121 (2000), S. 93-108 
    ISSN: 1573-2932
    Keywords: atmospheric deposition ; Harz ; heavy metals ; ombrotrophic peat bogs ; Sphagnum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Chemical analyses of dated ombrotrophicpeat cores from the Sonnenberger Moor, Harz, Germany,were done to determine the effect of early mining andsmelting on the tropospheric aerosol. Elementalconcentrations in peat were determined using XRF. Pb,Cu and Zn enrichment factors (EFs), and Pb and Cu fluxes were calculated. The results show that theconcentration of Pb and Cu as well as the calculatedPb and Cu EFs closely follow changes in the activitiesof man, especially those of the history of mining andsmelting. In contrast to Zn which seems to besubjected to post-depositional migration, Cu appearsto be immobile. Elevated Pb and Cu emissions, due tomining activities, can be followed back topre-Medieval times. These findings were supported byother studies in the vicinity or in the SonnenbergerMoor itself, all revealing the strong impact ofprimitive mining and smelting on the local aerosol.Thus peat cores from ombrotrophic bogs are very usefulfor quantifying temporal changes in metal emissions.
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  • 89
    ISSN: 1573-2932
    Keywords: copper ; element flux ; heavy metals ; Pinus ; soil pollution ; understorey vegetation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Distribution and fluxes of copper within Pinus sylvestris stands were studied during 1992–1994 along a heavy-metal pollution gradient in south-western Finland. The stands are situated at distances of 0.5, 4 and 8 km from a copper-nickel smelter that started operating in 1945 at Harjavalta. According to the results, copper concentrations in the soil, in the understorey vegetation and in the trees increased steeply towards the smelter. Almost 50 years' accumulation of heavy metals in the soil has caused direct toxic effects to soil microbes, thus decreasing decomposition and nutrient mineralisation. During the past few years, sulphur and heavy metal emissions from the copper and nickel smelter have been radically decreased. However, the heavy metals which have been accumulating in the soil for decades continue to affect the vegetation for a long time through soil processes. Consequently, long-term accumulation in the soil has to be taken into account when determining the critical loads of forest ecosystems for heavy metals.
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  • 90
    ISSN: 1573-2932
    Keywords: Pulp and paper mill sludge ; nitrogen ; DOC ; heavy metals ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Primary sludge, secondary sludge, and wood ash from a pulp and paper mill were combined with sand to create a synthetic topsoil (C:N ratio of 18:1) to restore an abandoned gravel pit. Synthetic topsoil was applied to field microcosms at rates equivalent to 0, 2170, 4341, or 6511 kg N/ha; each was seeded with grass. Fifteen chemical constituents in leachate were measured during two field seasons. Cadmium, Ni and Zn were mobilized rapidly by soil disturbance. Chloride and SO4-S eluted rapidly from the sludge along with Na. Nitrate leached with Ca late in each field season when sludge N-mineralization and nitrification exceeded plant uptake and microbial immobilization. Ammonium elution was negligible. Dissolved organic carbon (DOC) was mobilized by decomposition of organic matter in the sludge, as were Mg and K. Copper eluted with DOC, probably as an organic ligand. Lead and ortho-P were below our detection limits. We concluded that a synthetic topsoil with a 30:1 C:N ratio applied at a rate of 2100-4300 kg N/ha should provide adequate plant nutrition while minimizing water quality hazards.
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  • 91
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    Water, air & soil pollution 91 (1996), S. 249-254 
    ISSN: 1573-2932
    Keywords: heavy metals ; sewage sludge ; incineration ; mass balance ; particle size
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The fate of heavy metals in multiple hearth sewage sludge incinerators was examined using mass balance techniques. All major process streams into and out of the incinerators were sampled in order to characterize the partitioning of Cu, Ni, Ph, and Cd into the major effluent streams, and to calculate a metals mass balance around the incinerators. The results indicate that the residual particulate matter from the incineration process becomes progressively more enriched in the more-volatile metals (Cd and Ph) with decreasing particulate size, in the order bottom ash 〈 cyclone ash 〈 scrubber water particulate 〈 stack particulate. The less-volatile metals Cu and Ni are not similarly enriched. The mass balance indicates that approximately two-thirds of the Cd mass entering the incinerators is partitioned to the scrubber water stream, while the bottom ash stream receives most of the Cu, Ni, and Pb.
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  • 92
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    Water, air & soil pollution 91 (1996), S. 233-248 
    ISSN: 1573-2932
    Keywords: Arabian Gulf ; Bahrain ; heavy metals ; marine organisms ; provisional tolerable weekly intake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A total of 162 fish and shellfish samples representing important species have been collected from different coastal areas of Bahrain in the Arabian Gulf, and analyzed for lead, cadmium, mercury, and arsenic using electrothermal atomic absorption spectrophotometric method. The dverall mean levels for Pb, Cd, Hg and As in fish samples were 0.132, 0.032, 0.084 and 1.7 µg g−1 wet weight, respectively, whereas for shellfish they were 0.149, 0.045, 0.042 and 3.61 µg g−1 wet weight. These values indicate higher levels of metals in shellfish when compared with fish, except for mercury, and reveal that generally the levels of metals in these organisms are lower than existing guidelines, except for arsenic. The provisional tolerable weekly intake of Pb, Cd, Hg and As through fish was estimated to be 0.7, 0.17, 0.45 and 9 µg kg−1 bodyweight per week, respectively. Our results did not reveal a clear pattern regarding variations of metals concentration between areas and species.
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  • 93
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    Water, air & soil pollution 93 (1997), S. 93-108 
    ISSN: 1573-2932
    Keywords: straw ash ; ashes ; bottom ash ; fly ash ; biofuel ; cereal straw ; rape straw ; straw combustion ; fertilizer ; plant nutrients ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The composition of 79 samples of straw ash from seven heating plants in Sweden was analysed with the aim of evaluating straw ash as a fertilizer and liming agent. The variation in ash composition was explained mainly by ash fraction (bottom ash vs. fly ash) and straw type (wheat, barley, rye, rape) but also by heating plant. Compared with concentrations of Zn, Pb and Cd in bottom ash, levels in fly ash were 10–90 times higher. Fly ash also contained more Cu and K compared with bottom ash. The Cd/P ratio was 0.03 in bottom ash and 0.6 g Cd/kg P in fly ash. Ash from rape straw had a higher Ca content and liming effect compared with ash from cereal straw: e.g., the liming effect of rape ash was more than three times higher than that of wheat ash. The liming effect varied between 3.5 and 44% CaO and depended mainly on the Ca content. The average P content was 1.7% (0.2–4.4%), with slightly higher concentration in rape ash than in wheat ash. The potential for using straw ash as a fertilizer and liming agent is discussed. Compared with commercial fertilizers the use of bottom ash as a P fertilizer results in a lower addition of Cd. However, the total heavy metal content of straw ash poses a potential problem.
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  • 94
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    Water, air & soil pollution 99 (1997), S. 255-263 
    ISSN: 1573-2932
    Keywords: heavy metals ; sediments ; pollution ; resuspension ; release processes ; bioavailability ; anthropogenic metal ; residual metal ; geochemical phases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The space-time distribution of some pollutants (Cu, Pb, Zn, Cd, Fe, Mn, V, Ni, Cr) in the sludge of the canals of Venice was studied. The contamination levels were comparable to, or higher, than those measured in the most polluted sediments of the Lagoon of Venice. Sediments were collected by two different sampling techniques: 1) collection of sediment cores (upper 5 cm) by a syringe-type corer; 2) collection by traps, placed on the bottom of the canal. Traps permitted the sampling of sediments essentially resuspended by overlying water turbulence. This sediment fraction is subjected to variations of its physicochemical parameters (principally change of redox conditions) and therefore to pollutant exchange at the water/sediment interface. The metals principally exchanged during sediment resuspension were Cd, Pb, Zn and Cu. These metals have principally an anthropogenic origin and are bound to the most labile geochemical phases of the sediment (such as sulphides), which can be oxidised during sediment resuspension, releasing metals into the water. Fe, Cr and Ni were only partially exchanged, while Mn and V were generally not exchanged; a significant fraction of these metals is of natural origin and is bound to the most refractory phases of the sediment.
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  • 95
    ISSN: 1573-2932
    Keywords: soil ; pollution ; heavy metals ; smelters ; factor analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
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  • 96
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    Water, air & soil pollution 99 (1997), S. 255-263 
    ISSN: 1573-2932
    Keywords: heavy metals ; sediments ; pollution ; resuspension ; release processes ; bioavailability ; anthropogenic ; metal ; residual inetal ; geochemical phases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The space-time distribution of some pollutants (Cu, Ph, Zn, Cd, Fe, Mn, V, Ni, Cr) in the sludge of the canals of Venice was studied. The contamination levels were comparable to, or higher, than those measured in the most polluted sediments of the Lagoon of Venice Sediments were collected by two different sampling techniques I ) collection of sediment cores (upper 5 cm) by a syringe-type corer, 2) collection by traps, placed on the bottom of the canal Traps pennitted the sampling of sediments essentially resuspended by overlying water turbulence This sediment fraction is subjected to variations of its physicochemical parameters (principally change of redox conditions) and therefore to pollutant exchange at the water/sediment interface The metals principally exchanged during sediment resuspension were Cd, Pb, Zn and Cu These metals have principally an anthropogenic origin and are bound to the most labile geochemical phases of the sediment (such as sulphides), which can be oxidised during sediment resuspension, releasing metals into the water Fe, Cr and Ni were only partially exchanged, while Mn and V were generally not exchanged, a significant fraction of these metals is of natural origin and is bound to the most refractory phases of the sediment.
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  • 97
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    Water, air & soil pollution 95 (1997), S. 119-131 
    ISSN: 1573-2932
    Keywords: geochemical investigations ; geochemical validation ; heavy metals ; ICP-AES ; environmental monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A little known alternative to highcost environmental analysis, especially in Europe, is the use of commercially available, lowcost exploration geochemical laboratory analysis. To test for suitable accuracy and precision, both indicated parameters were monitored during several sample runs for environmental examinations at a selected commercial geochemical laboratory using various digestive methods and ICP-AES(Inductively Coupled Plasma Atomic Emission Spectrometry). By evaluating duplicate samples and repeated measurements of internal standards and comparing the results with precision needed for environmental investigations, exploration geochemical analysis is found to be more than adequate for most elements and digestive methods in environmental applications. Accuracy is highest for total digestion ICP-AES analysis, with expectedly greater error margins for aqua regia digestion. Lowcost exploration geochemical analysis is an inexpensive analytical tool for screening, detailed investigations and monitoring of contaminated sites.
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  • 98
    ISSN: 1573-3017
    Keywords: heavy metals ; old-fields ; municipal sludge ; blackfaced leafhopper ; Graminella nigrifrons ; Cicadellidae ; cabbage looper moth ; Noctuidae ; Trichoplusia ni
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Municipal sewage sludge containing heavy metals had a toxic effect on the development of the cabbage looper, Trichoplusia ni (Lepidoptera: Noctuidae), one of two herbivorous insects commonly found in an Ohio old-field which had been subjected to long-term sewage sludge application. Soils were removed in 1992 from an old-field following 11 years of heavy nutrient enrichment (1978 to 1988) with applications of either sewage sludge (Milorganite®) containing heavy metal contaminants or urea-phosphate fertilizer. Egg to adult development rate and survival of the blackfaced leafhopper, Graminella nigrifrons (Homoptera: Cicadellidae), and the cabbage looper was determined on maize (leafhopper) and broccoli (looper) seedlings grown in soils from sludge-treated, fertilizer-treated, or untreated control plots of the old-field. Fertilizer and sludgetreated soils had higher levels of N. P and organic matter, and a lower pH than the untreated control soils, while sludge-treated soils contained significantly higher concentrations of Cd, Cu, Pb, and Zn. Maize appeared to be unaffected by the three soil treatments, and survival and rate of egg to adult development of the leafhopper was not affected. Broccoli seedlings grown in both the high nutrient fertilizer and sludge soils were greener and larger than broccoli grown in control soils. However, the cabbage looper had significant larval and pupal mortality (25 to 40%) and prolonged egg to adult development on sludge-grown broccoli compared to control and fertilizer treatments. As assimilation into the food chain of heavy metals and other organic pollutants, such as PCBs, is in part a function of the interaction of soil chemistry and type of plant, the application of municipal sludges to old-fields needs to be carefully monitored, as contaminants may have significant developmental and behavioural effects on some secondary links in the old-field food chain.
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  • 99
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    Ecotoxicology 3 (1994), S. 180-192 
    ISSN: 1573-3017
    Keywords: adaptation ; damage ; drought ; fluorinated compounds ; heavy metals ; phytochelatins ; proline ; putrescine ; seleno amino acids ; stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The potential of metabolites, enzymatic processes and changes in plant performance as biomarkers in environmental assessment is reviewed. Biomarkers may be used as an early warning system of specific or general stress at each biological level, from molecules to ecosystems. The sensitivity of a species and, thus, the efficiency of a biomarker will depend on the degree of already present adaptation to environmental stress and on the homogeneity of the investigated population. Biomarkers for specific environmental stresses are scarce; better known are biomarkers for environmental stress complexes such as heavy metals, physiological drought and extreme temperature or biomarkers as a reaction on a full scale of environmental stresses. It is argued that a battery of biomarkers is necessary to evaluate chemical hazards to species.
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  • 100
    ISSN: 1573-3017
    Keywords: red wood ant ; phosphoa denine nucleotides ; enzyme patterns ; heavy metals ; tolerance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Biochemical and physiological effects of prolonged feeding of the ant Formica aquilonia, in natural conditions with excess of cadmium or mercury, were studied. In all developmental stages metals caused the time-dependent increase of AMP, parallel with a decrease of ATP and the pool size of adenylates. This was reflected by a low adenylate energy charge (AEC) index and accompanied by an inhibition of ATPases. Despite the fall in the adenylate pool of workers, the levels of adenylate energy charge confirmed their ability to maintain energetic balance. Prolonged access to food highly contaminated with Cd, or Cd with Hg, diminished these adaptive abilities, but pre-adaptive reactions (not correlated with the metal load) were induced. Activity patterns of enzymes involved in energy metabolism showed metal dependent inhibitory effects, but repeated contamination evoked some compensatory mechanisms, both in workers and in the pupal stage from the next generations. Cadmium (indirectly) stimulated the esterases and free radical scavengers. Compensatory mechanisms were insufficient in insects contaminated with both Hg and Cd, even causing family disappearance, through increased mortality and migration to other colonies. Compensatory mechanisms expressed by the adult workers appeared to be of a phenotypic origin
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