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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 2 (1963), S. 1284-1295 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 10 (1971), S. 1406-1410 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 859-865 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The effect of the solute–solvent coupling on the dynamics of adiabatic charge transfer reactions is examined. A two-state description of the solute electronic configuration is implemented to adequately treat the gradual transfer of charge from the donor to acceptor as the reaction progresses. A formalism is developed for separating the solute and solvent contributions to the reaction coordinate (defined here as the difference in energy between the reactant and product states) and equations of motion are derived for these coordinates. It is found that these equations of motion are far more elaborate than the ones considered in the diabatic case (weak coupling between solute electronic states). In particular, they must reflect the effect of the solvent polarization on the solute polarization. The corresponding coupling term is missing in most treatments of charge transfer processes. To explore the coupled dynamics of the reactive trajectories we use both direct downhill simulations and a new approach which evaluates the average solvent coordinate using the linear response approximation. Our study indicates that the reactive fluctuations are characterized by both the polarization time of the solute dipole and the relaxation time (or times) of the solvent. The nature of the relevant solvent relaxation time is explored on a microscopic level for different charge configurations and different solute radii. The results demonstrate that the autocorrelation function of the solvent coordinate (which is proportional to the solvent reaction field) reflects saturation effects and depends on the solute size and charge distribution. Thus we conclude that the microscopic dynamics of the solvent can deviate from the corresponding macroscopic estimate.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 57 (1986), S. 1929-1931 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A commercial database software package has been used to create several databases and tools that assist and enhance the ability of experimental physicists to analyze data from the Tandem Mirror Experiment-Upgrade (TMX-U) experiment. This software runs on a DEC-20 computer in M-Divisions's User Service Center at Lawrence Livermore National Laboratory (LLNL), where data can be analyzed off line from the main TMX-U acquisition computers. When combined with interactive data analysis programs, these tools provide the capability to do batch-style processing or interactive data analysis on the computers in the USC or the supercomputers of the National Magnetic Fusion Energy Computer Center (NMFECC) in addition to the normal processing done by the TMX-U acquisition system. One database tool provides highly reduced data for searching and correlation analysis of several diagnostic signals within a single shot or over many shots. A second database tool provides retrieval and storage of unreduced data for use in detailed analysis of one or more diagnostic signals. We will show how these database tools form the core of an evolving off-line data analysis environment on the USC computers.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 67 (1963), S. 2583-2587 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 68 (1964), S. 368-374 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 68 (1964), S. 1886-1890 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 37 (1986), S. 459-491 
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 10 (1992), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: CO2–CH4 fluid inclusions are present in anatectic layer-parallel leucosomes from graphite-bearing metasedimentary rocks in the Skagit migmatite complex, North Cascades, Washington. Petrological evidence and additional fluid inclusion observations indicate, however, that the Skagit Gneiss was infiltrated by a water-rich fluid during high-temperature metamorphism and migmatization.CO2-rich fluid inclusions have not been observed in Skagit metasedimentary mesosomes or melanosomes, meta-igneous migmatites, or unmigmatized rocks, and are absent from subsolidus leucosomes in metasedimentary migmatites. The observation that CO2-rich inclusions are present only in leucosomes interpreted to be anatectic based on independent mineralogical and chemical criteria suggests that their formation is related to migmatization by partial melting. Although some post-entrapment modification of fluid inclusion composition may have occurred during decompression and deformation, the generation of the CO2-rich fluid is attributed to water-saturated partial melting of graphitic metasedimentary rocks by a reaction such as biotite + plagioclase + quartz + graphite ± Al2SiO5+ water-rich fluid = garnet + melt + CO2–CH4. The presence of CO2-rich fluid inclusions in leucosomes may therefore be an indication that these leucosomes formed by anatexis.Based on the inferences that (1) an influx of fluid triggered partial melting, and (2) some episodes of fluid inclusion trapping are related to migmatization by anatexis, it is concluded that a free fluid was present at some time during high-temperature metamorphism. The infiltrating fluid was a water-rich fluid that may have been derived from nearby crystallizing plutons. Because partial melting took place at pressures of at least 5 kbar, abundant free fluid may have been present in the crust during orogenesis at depths of at least 15 km.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Swakane Gneiss and the overlying Napeequa Complex in the North Cascade range, Washington, were metamorphosed and deformed during development of a Cretaceous-Paleogene continental arc, and are among the structurally deepest exposed rocks within the Cordilleran arcs of North America. Peak metamorphic conditions in both the Swakane Gneiss and Napeequa Complex were c. 640–750 °C, 9–12 kbar. Clockwise paths and widespread evidence for high-P metamorphism in meta-supracrustal rocks (burial to 〉40 km) document major vertical tectonic motion during arc construction and unroofing.These and other moderately high-pressure rocks in the North Cascades-Coast Mountains experienced a dramatically different tectonometamorphic history than metamorphic rocks within other Cordilleran arcs. The exhumed arc complexes of the Sierra Nevada and Peninsular Ranges are dominated by relatively low-P metamorphic and plutonic rocks (typically 〈6 kbar). There is no evidence that the northern Cordillera was thickened to a greater degree than these other belts, suggesting that the greater magnitude of vertical motion in the Cascades may have been related to exhumation mechanisms: Eocene extension in the northern Cordillera vs. erosional unroofing in the central and southern Cordillera.
    Type of Medium: Electronic Resource
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