ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Unknown

Bis[μ-N-(pyridin-2-ylmethyl)pyridin-3-amine-κ2N:N′]disilver(I) bis(perchlorate) dimethyl sulfoxide disolvate (2013)

Moon, S.-H.Park, K.-M.

International Union of Crystallography (IUC)

In: Acta Crystallographica Section E

add to mindlist on the mindlist

Details

Publication Date: 2013-10-03

Description: In the binuclear title compound, [Ag2(C11H11N3)2](ClO4)2·2C2H6SO, the complex cation is centrosymmetric, with the unique AgI cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridine-2-ylmethyl)pyridine-3-amine ligands in a geometry slightly distorted from linear [N—Ag—N = 170.78 (9)°], resulting in the formation of a 16-membered cyclic dimer. The two pyridine rings coordinating to the AgI atom are almost perpendicular to each other [dihedral angle = 87.73 (10)°]. Intermolecular Ag...O interactions [3.149 (3) and 2.686 (3) Å], N—H...O and C—H...O hydrogen bonds and C—H...π interactions between the cyclic dimers and the anions or the solvent molecules lead to the formation of a three-dimensional supramolecular network.

Electronic ISSN: 1600-5368

Topics: Chemistry and Pharmacology , Geosciences

Published by International Union of Crystallography (IUC)

	Location	Call Number	Expected	Availability

Others were also interested in ...

PAPER CURRENT

S·F·X

Fulltext

hit 1 - 1 | 1 hit