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RbH2AsO4 (2013)

Stöger, B.

International Union of Crystallography (IUC)

In: Acta Crystallographica Section E

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Publication Date: 2013-10-03

Description: RbH2AsO4, rubidium dihydrogenarsenate (RDA), was synthesized by partial neutralization of an aqueous H3AsO4 solution with aqueous Rb2CO3. Its paraelectric room-temperature phase is composed of virtually regular tetrahedral [AsO2(OH)2]− anions and Rb+ cations, both located on \overline{4} positions. The [AsO2(OH)2] units are connected via O—H...O hydrogen bonds into a three-dimensional network, whereby the H atoms are equally disordered between the O atoms. The Rb+ cations are located in channels running along the directions and coordinated by eight O atoms located at the vertices of a snub disphenoid.

Electronic ISSN: 1600-5368

Topics: Chemistry and Pharmacology , Geosciences

Published by International Union of Crystallography (IUC)

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