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Monodeuterated methane in the outer solar system. I Spectroscopic analysis of the bands at 1.55 and 1.95 microns (1983)

De Bergh, C. ; Lutz, B. L. ; Maillard, J. P.

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Publication Date: 2019-06-28

Description: The analysis of the near-infrared spectrum of monodeuterated methane (CH3D) near 6400/cm and 5100/cm is presented. Three new parallel bands which have locally perturbed upper states connecting with the ground state are identified, and approximate rotational constants are derived. The band centered near 6425/cm and the 9613 A band previously analyzed by Lutz, Danehy, and Ramsay (1978) are found to form an apparent vibrational progression with the nu2 fundamental at 2200/cm, and vibrational assignments of 3nu2 and 5nu2, respectively, are proposed. Detailed comparison of the rotational constants of the states involved is shown to support these assignments.

Keywords: LUNAR AND PLANETARY EXPLORATION

Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 273; 397-409

Format: text

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