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Ion-induced nucleation: A density functional approach (1995)

Kusaka, I. ; Wang, Z.-G. ; Seinfeld, J. H.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 102 (1995), S. 913-924

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Density functional theory is applied to ion-induced nucleation of dipolar molecules. The predicted reversible work shows a sign preference, resulting in a difference in the nucleation rate by a factor of 10–102, for realistic values of model parameters. The sign effect is found to decrease systematically as the supersaturation is increased. The asymmetry of a molecule is shown to be directly responsible for the sign preference in ion-induced nucleation. © 1995 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.469158

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