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Charge-overlap effect on the electronic transitions in moderate-energy collisions between closed-shell particles with rare-gas structure (1998)

Kita, S. ; Gotoh, S.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 109 (1998), S. 9713-9718

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: A potential model, which is represented by the overlap of electron clouds of interacting particles, has been applied to discuss the diabatic potential crossings which lead to one- and two-electron transitions in moderate-energy collisions of closed-shell particles. The crossings evaluated with the potential model interpret reasonably well both differential scattering experiments and ab initio calculations. In the model, the potential crossings originate from the hole(s) produced by the promotion of electron(s) in the outermost shell(s) of incident particle(s). © 1998 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.477641

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