ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
A model for the Briggs–Rauscher reaction mechanism with four intermediates and seven steps is proposed by simplifying the model of De Kepper and Epstein [J. Am. Chem. Soc. 104, 49 (1982)]. Assigning suitable rate constants for the steps of the simplified model, we obtain numerical results for the nonlinear dynamic behaviors such as oscillations, limit cycle, multistability, and inverse regulation of the iodine concentration. The results are compared with experiments and other previous models. The comparison shows that the present simplified model expresses the nonlinear dynamic behaviors better than the previous models. © 2002 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1491243