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Fluorescence cross section of the H2O+ A˜ 2A1 (0, 7, 0) produced through photoionization of H2O (1988)

Wu, C. Y. Robert ; Hwang, M. Y.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 89 (1988), S. 5524-5526

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The cross section for production of the H2O+ A˜ 2A1(0,7,0)→X˜ 2B1(0,0,0) fluorescence through photoionization of H2O has been measured in the 14.5–20.5 eV region. The maximum quantum yield is 1.4×10−3 at 16.5 eV. Further, the cross sections for producing the H2O+[A˜ 2A1(0,7,0)] and H2O+ A˜ 2A1 have been estimated. The magnitude of the latter is about a factor of 10 smaller than that obtained by electron spectroscopy. The discrepancy can be attributed to radiationless transitions between the A˜ and X˜ states of H2O+.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.455558

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