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Infrared laser spectroscopy of the 210 and 221 bands of H2O+(X˜ 2B1) (1989)

Brown, Philip R. ; Davies, Paul B. ; Stickland, Ross J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 3384-3391

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Infrared laser absorption spectra of H2O+ have been recorded in an ac discharge using velocity modulation detection. Eighty-five lines of the 210 fundamental and 20 lines of the 221 hot band were used to derive rotation, spin-rotation, and distortion parameters for the ground state and the first two vibrationally excited states of the bending mode. The results are compared with those from analysis of the A˜–X˜ band system and from rotational and vibration–rotation laser spectra, as well as with recent ab initio results obtained using MRCI wave functions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.456913

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