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Dynamic light scattering observation of droplet aggregation in a Winsor type W/O microemulsion system (1989)

Waaler, Dag ; Strand, Knut Arne ; Strømme, Gunvald ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 3360-3367

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We have performed scattered light intensity autocorrelation measurements on a Winsor type microemulsion system composed of brine, cyclohexane, SDS and a mixture of 1-butanol and 1-pentanol. At high cosurfactant concentration, where the microemulsion phase was considered to consist of individual, spherical water-in-oil droplets of relatively low droplet volume fraction, the autocorrelation functions were observed to be essentially single exponential, as expected. Above a certain droplet volume fraction, however, additional decay modes were observed to enter the correlation data. These modes were interpreted to be due to rotation and/or internal motion of droplet aggregates.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.456910

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