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Diode laser spectroscopy of the hydrogen bond vibration ν2 OC---HF in a continuous wave supersonic jet (1989)

Wang, Zhongcheng ; Bevan, John W.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 3335-3339

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The high resolution spectrum of the ν2 (C≡O) stretching vibration in the hydrogen bonded dimer, OC---HF, has been recorded in a continuous wave (cw) supersonic molecular jet using a diode laser spectrometer. Spectroscopic analysis gives the following rovibrational parameters (in cm−1): ν0=2167.69 9 04(11); B0=0.102 200 647(13); D0J =3.244(18)×10−7; B2=0.101 552 5(15); D2J =3.449(36)×10−7. Investigation of observed line profiles allows a lower limit of 0.68 ns to be made for the excited state vibrational predissociative lifetime.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.457642

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