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Experimental results on the rate of nucleation in supersaturated n-propanol, ethanol, and methanol vapors (1989)

Peters, F. ; Paikert, B.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 5672-5678

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The homogeneous nucleation of three supersaturated alcohol vapors carried in argon is investigated experimentally. A gasdynamic shock tube method serves to subject the vapors to short supersaturation pulses. The growing nuclei are detected in number and size by Mie-light scattering. The results provide the supersaturation over a wide range of temperature for the nucleation rate of 108 cm−3 s−1. Comparison with the classical nucleation theory (CNT) exhibits increasing divergence with decreasing temperature.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.457520

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