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Binary nucleation of ethanol and water (1990)

Schmitt, J. L. ; Whitten, J. ; Adams, G. W. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 92 (1990), S. 3693-3699

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The authors have used a fast expansion cloud chamber to measure binary homogeneous nucleation rates in several ethanol–water mixtures as a function of temperature, ethanol and water activities and nucleation rate. Data (ethanol and water activities) are presented for a range in nucleation rate from 103 to 105 drops/cm3 s from 263 to 293 K for mixtures having mole ratios (ethanol/water) of 10, 4, 0.1, 0.01, and 0.001. A comparison of the extensive data set to other data in the literature shows good agreement. We find current theory, as expected, is unable to accurately predict the data at low ethanol concentrations.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.457827

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