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X-ray diffraction study of the structure of a monolayer methanol film adsorbed on graphite (1990)

Morishige, K. ; Kawamura, K. ; Kose, A.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 93 (1990), S. 5267-5270

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The x-ray diffraction measurements of methanol adsorbed on graphite have been taken over the temperature range 32–150 K and the coverage range 0.02–0.17 molecule A(ring)−2. The diffraction data are analyzed to yield the configuration of the molecule on the surface by means of the least-squares fitting of the whole pattern. The data show clearly that zigzag chains of alternating weak and strong hydrogen bonds, as evidenced by the long and short 0⋅⋅⋅0 separations, are formed in the crystalline monolayer of methanol on graphite. The crystalline solid film near the complete monolayer melts around 142 K in comparison to bulk methanol which melts at 175.4 K.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.459645

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