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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Surface morphological and compositional evolution during the initial stages of Si growth on Ge(001)2×1 by cyclic gas-source molecular beam epitaxy from Si2H6 has been investigated using in situ reflection high-energy electron diffraction (RHEED), Auger electron spectroscopy, electron-energy-loss spectroscopy, and scanning tunneling microscopy, combined with post-deposition high-resolution cross-sectional transmission electron microscopy. The layers were deposited using repetitive cycles consisting of saturation Si2H6 dosing at room temperature, followed by annealing for 1 min at 550 °C. Film growth was observed to proceed via a mixed Stranski–Krastanov mode. Single-step-height two-dimensional growth was obtained for nominal Si deposition thicknesses tSi up to (approximately-equal-to)1.5 monolayers (ML). However, the upper layer remained essentially pure Ge which segregated to the surface through site exchange with deposited Si as H was desorbed. At higher tSi, the Ge coverage decreased slowly, the surface roughened, and two-dimensional multilayer island growth was observed for tSi up to (approximately-equal-to)7.5 ML, where bulk reflections in RHEED patterns provided evidence for the evolution of three-dimensional island formula.
    Type of Medium: Electronic Resource
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