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4,4′-Bipyridylium di-μ-chlorotetrachlorodicuprate(II): a redetermination (2001)

Näther, Christian ; Jeß, Inke ; Bolte, Michael

Copenhagen : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. m78-m79

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ISSN: 1600-5368

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The structure of the title compound, (C10H10N2)[Cu2Cl6], previously determined by Bukowska-Strzyzewska & Tosik [Pol. J. Chem. (1979), 53, 2423–2428], has been reinvestigated. Our structure determination is of a significantly higher precision and, in contrast to the previous investigation, H atoms could be clearly found. Thus, it can be shown that the chains of alternating bipyridylium cations and Cu2Cl62− anions are stabilized by bifurcated hydrogen bonds. The cation and anion both lie on inversion centres.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S1600536801001283

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