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p-Methyltetrahomodioxacalix[4]arene (2001)

Thuéry, Pierre ; Nierlich, Martine ; Vicens, Jacques ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 833-834

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, 7,13,21,27-tetramethyl-3,17-dioxapentacyclo[23.3.1.15,9.111,15.19,23]ditriaconta-1(29),5,7,9(30),11(31),-12,14,19(32),20,22,25,27-dodecaene-29,30,31,32-tetraol, C34H36O6, assumes in the solid state a very distorted cone-like conformation stabilized by intramolecular simple and bifurcated hydrogen bonds involving both phenolic and ether O atoms. One part of the molecule, comprising an ether link, is included in the cavity of an adjacent calixarene related by a screw axis, giving rise to a one-dimensional self-inclusion polymer.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270101005753

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