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    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 57 (2001), S. 333-334 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The reaction of Cu and V in a Rb2S5 melt yields black crystals of rubidium dicopper vanadium tetrasulfide, RbCu2VS4. The structure is comprised of [Cu2VS4]− layers within the (010) plane which are separated by Rb+ cations. The layers consist of a network of edge- and corner-sharing [VS4] and [CuS4] tetrahedra parallel to (010). The optical band gap was determined as 1.45 eV.
    Type of Medium: Electronic Resource
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