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A cyanide-bridged bimetallic complex, [CrPr(CN)6(C3H7NO)4(H2O)3]·H2O (2000)

Combs, Robert A. ; Farmer, J. Matt ; Kautz, Jason A.

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 1420-1422

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The crystal structure of the bimetallic cyanide-bridged title complex, triaqua-1κ3O-μ-cyano-1:2κ2N:C-pentacyano-2κ5C-tetrakis(N,N-dimethylformamide)-1κ4O-chromium(III)praseodymium(III) monohydrate, was obtained by single-crystal X-ray diffraction. The central praseodymium(III) ion is eight-coordinate, arranged in a square antiprism, while the chromium(III) ion is six-coordinate, oriented octahedrally. Molecules in the crystal lattice are held together by a network of hydrogen bonds.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S010827010001204X

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