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Racemic 1,2-diphenylbut-3-yn-2-ol (2000)

Madhavi, N. N. Laxmi ; Desiraju, Gautam R. ; Bilton, Clair ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 1359-1360

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: Molecules of the title compound, C16H14O, are chiral and crystallize in space group P\overline 4 with Z′ = 2, and with one R and one S molecule in the asymmetric unit. The conformations of the phenyl rings in the two independent molecules differ slightly. Supramolecular organization in the crystal is via tetrameric O—H...H(O) hydrogen-bonded synthons formed separately by each conformer. These tetrameric synthons stack along the c axis via C[triple-bond]C—H...O(H) hydrogen bonds. The only link between the conformer stacks is provided by weaker Cmethylene—H and Cphenyl—H interactions with πarene density.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100011343

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