ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title complex, [Mn(C5H4NCO2)2(C5H4NCOOH)]OH, consists of a cation and a hydroxide ion. The Mn atom is coordinated by three N atoms and three O atoms from three pyridinecarboxylate ligands, and has a distorted octahedral geometry, with Mn—N distances ranging from 2.157 (1) to 2.233 (1) Å and Mn—O distances from 1.910 (1) to 1.927 (4) Å. One ligand is protonated as the acid form. This forms one of two independent hydrogen bonds, to the anion.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100012245