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Mechanisms for a rapid phase transformation of Nb3Si from the Ti3P structure to the Cr3Si (A15) structure (1982)

Olinger, B. W. ; Newkirk, L. R. ; King, J. C.

[S.l.] : International Union of Crystallography (IUCr)

Acta crystallographica 38 (1982), S. 151-154

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ISSN: 1600-5724

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: Nb3Si in the Cr3Si (A15) structure has been successfully recovered in bulk amounts after shock compressing Nb3Si in the Ti3P structure. The material was under compression less than 1 μs. To account for the extreme rapidity of the transformation we find that the essential characteristics of the Cr3Si structure can be achieved by screw rotating one type of column of Nb-atom pairs 45° and one quarter cell length in the Ti3P structure. It is further shown that the Fe3P structure cannot be similarly transformed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0567739482000278

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