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Statistics of ion distribution in 1D and 2D mixed crystals (1980)

Friebel, C.

[S.l.] : International Union of Crystallography (IUCr)

Acta crystallographica 36 (1980), S. 259-265

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ISSN: 1600-5724

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: A statistical distribution of ions M in lattices or partial lattices ∞[A1 - xMxLm] of mixed crystals being assumed, the probability functions PJ(V)(x) for single coordination polyhedra MLn (j = 1), pairs (j = 2) and larger clusters of MLn groups (j 〉 2) in 1D (v = 2) and v-connected 2D systems (v = 3, 4, 6) are calculated. On raising the connecting number v, increasing cluster probabilities are distinctly shifted to lower concentrations x of the foreign ion M. For a relation between the numerical values P(x) and experimental results, the mixed-crystal series (BaF)2[Zn1 - xCuxF4] of a four-connected 2D structure is given as an illustrative example.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0567739480000514

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