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Oriented growth and crystal structure of phases precipitated in Eu2+-doped NaCI single crystals (1980)

Stępien-Damm, J. ; Lukaszewicz K.

[S.l.] : International Union of Crystallography (IUCr)

Acta crystallographica 36 (1980), S. 54-57

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ISSN: 1600-5724

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: X-ray investigations of Eu2+-rich precipitates in NaCl single crystals have revealed the presence of two phases. Phase A of chemical formula EuCl2 with a CaF2-type structure and lattice parameter a = 6.969 (2) Å preserves strictly the orientation of the matrix lattice. Phase B with the lattice parameter a = 7.47 (1) Å and tentative formula EuCl2.2NaCl, containing Eu2+ ions and charge-compensating cation vacancies, is localized at subgrain boundaries and is thermally less stable than phase A.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0567739480000101

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