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Reactivity of acrylic monomers (1979)

Dumitriu, E. ; Oprea, Sp. ; Maxim, S. ; [et al.]

Springer

Colloid & polymer science 257 (1979), S. 1203-1206

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ISSN: 1435-1536

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Summary The copolymerization of N,N-diethylacrylamide (Ml) with methyl acrylate (M2) was investigated and reactivity ratiosr 1= 0.41 andr 2 = 0.52 obtained. Also the distribution of diad fractions was calculated and the results were interpreted in terms of the product of reactivity ratios. The tendency of the two monomers to alternate was explained on the basis of differences in polatities between the double bonds, this explanation being supported both by the values ofe parameter and NMR spectroscopy data. A copolymerization mechanism was suggested.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01517245

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