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  • 1
    ISSN: 1434-4475
    Keywords: Cyclic ethers, aqueous, as solvents for salts ; Free energy of solution, “standard” partial molar, isothermal estimation ; Interionic distances for potassium carboxylates at saturation in aqueous cyclic ethers at 25 °C ; Potassium carboxylates, solubilities at 25 °C in aqueous cyclic ethers ; Salt solubilities and solvent polarities ; Solubilities of potassium carboxylates in aqueous cyclic ethers at 25 °C
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Neue Messungen der Löslichkeiten von K-Acetat und K-Benzoat in wäßrigen Lösungen von 1,4-Dioxan bzw. THF wurden durchgeführt. Es wird eine quasi-thermodynamische Behandlung der Daten mit einer Kombination von chemischer Thermodynamik und einer uneingeschränktenDebye-Hückel-Theorie der Elektrolyte in Lösung angewandt; diese theoretische Beschreibung liefert eine Beziehung zwischen der Löslichkeit eines Salzes und der Lösungs-mittelpolarität.
    Notes: Abstract New measurements upon the respective solubilities of potassium acetate and benzoate at 25 °C in aqueous 1,4-dioxane and in aqueous tetrahydrofuran are reported, together with a quasi-thermodynamic development, from the union of chemical thermodynamics with the unrestricted result of theDebye-Hückel theory of electrolytes in solution, of a general theoretical function which in principle provides a summary descriptive expression of the relationship between the solibilities of any salt at any natural limiting concentrations and the polarities of its solvents.
    Type of Medium: Electronic Resource
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