ISSN:
1434-4475
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Diamagnetic susceptibilities of trimethyl(imino-oxy)silanes,Me 3SiON ∶ CMeR, and dimethyldi(imino-oxy)silanes,Me 2Si(ON ∶ ∶ CMeR)2, containing Si−O bonds are reported. χ M of these silicon compounds has been calculated theoretically from the method ofBaudet et al. and a good agreement has been obtained between the observed χ M values and the corresponding calculated values. χ Si in these compounds has been calculated graphically and the lower values have been explained on the basis of “back-bonding” to the silicon atom from the oxygen lone pair.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00906883