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    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 15 (1980), S. 21-28 
    ISSN: 1432-1432
    Keywords: β-radiolysis ; Asymmetric radiolysis ; Vester-Ulbricht Hypothesis ; Origin of optical activity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary We have extended earlier experiments on the radiolysis of DL-tryptophan using32Pβ-radiation to longer reaction times, observing complete destruction of the tryptophan by secondary, non-radiolytic processes. We have also undertaken the irradiation of DL-leucine with32Pβ's at -196°, achieving radiolyses to the extents of ca. 20–30%, but observing no concomittant asymmetric bias. The implications of these observations are discussed with regard to the Vester-Ulbricht mechanism for the origin of optical activity.
    Type of Medium: Electronic Resource
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