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  • 1
    Electronic Resource
    Electronic Resource
    A CEMS/AES study of the passivation of iron (1989)
    Springer
    Fresenius' Zeitschrift für analytische Chemie 333 (1989), S. 555-560 
    Details
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The passivation of iron and steel (DIN 1623) was studied by integral and depth selective conversion electron Mössbauer spectroscopy and Auger electron spectroscopy. Thickness and phase composition of the passive layer formed in sulphate solution and in a phosphate buffer were determined in dependence on the anodic potential and the duration of the passivating procedure. The experimental results lead to the conclusion that not the whole oxidic layer is responsible for the passivity but only a very thin intermediate layer formed between the cubic substrate and the rhombic oxide (γ-FeOOH) cover.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00572376
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