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  • 1
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract The rate constant for the addition of acetonyl radicals to isobutylene, producing the ketone CH3COCH2CH2CH/CH3/2 is $$\lg k = (9.5 \pm 0.6) - (12 000 \pm 1 000)/4.55 T 1/mol s$$ The logarithm of the preexponential factor and the activation energy vary in parallel for the addition of acetonyl radicals to isobutylene, 1-hexene and propylene.
    Notes: Abstract Определено значение константы скорости присоединения ацетонильного радикала к изобутилену с образованием кетона CH3COCH2CH2(CH3)2. Отмечено симбатное изменение логарифмов предэкспоненциальных множителей и энергий активации для констант скорости присоединения ацетонильного радикала к изобутилену, 1-гексену и пропилену.
    Type of Medium: Electronic Resource
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