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Thermal, spectral and magnetic studies on glycine complexes of cobalt(II), nickel(II) and zinc(II) with hydrazine (1996)

Sivasankar, B. N. ; Govindarajan, S.

Springer

Journal of thermal analysis and calorimetry 46 (1996), S. 117-127

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ISSN: 1572-8943

Keywords: bis-hydrazine metal glycinates ; complexes ; hydrazinium metal glycinates ; metal powders ; thermal analyses

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Hydrazinium metal glycinates [(N2H5 2M(NH2CH2COO)4] and bis(hydrazine)metal glycinates, [M(NH2CH2COO)2(N2H4)2], whereM=Co, Ni or Zn have been prepared and characterized by chemical analyses, magnetic moments and vibrational and electronic spectra. The thermal behaviour of these compounds has been studied by thermogravimetry and differential thermal analyses. These complexes decompose with high exothermicity giving metal powder as the final residue. The X-ray powder data of each set of complexes show isomorphism among themselves.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01979952

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