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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 37 (1991), S. 1289-1298 
    ISSN: 1572-8943
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Mittels DTA und Röntgendiffraktion wurde das quasiternäre System Ag2S-Cu2S-P4O10 untersucht. Es konnte keine quasiternäre Verbindung gefunden werden. Erstmalig wurde das Phasendiagramm für das binäre Teilsystem Cu2S-P4O10 gegeben. Es enthält die Verbindungen Cu7PS6, Cu3PS4 und (CuPS3)n. Das unlängst beschriebene Cu4P2S7 wurde nicht beobachtet. Thermoanalytische und röntgenografische Daten dieser Verbindungen werden gegeben. Die Verbindungen Cu7PS6 + Ag7PS6 und Cu3PS4 + Ag3PS4 sind im festen Aggregatzustand unbegrenzt mischbar.
    Notes: Abstract The quasiternary system Ag2S-Cu2S-P4S10 was investigated by DTA- and X-ray measurements. No quasiternary compound was found. The phase diagram of the constituent binary Cu2S-P4S10 is given for the first time. It contains the compounds Cu7PS6, Cu3PS4 and (CuPS3)n. The previously reported Cu4P2S7 was not observed. Thermal and X-ray data of these compounds are given. The compounds Cu7PS6 + Ag7PS6 and Cu3PS4 + Ag3PS4 are completely miscible in the solid state.
    Type of Medium: Electronic Resource
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