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Spin trapping of free radicals generated by gammaradiolysis of crown ethers and their analogues (1990)

Kuruc, J.

Springer

Journal of radioanalytical and nuclear chemistry 145 (1990), S. 205-213

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ISSN: 1588-2780

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering

Notes: Abstract Gamma-radiolytically generated radicals of crown ethers /12-crown-4, 1; 15-crown-5, 2; dicyclohexano-24-crown-8, 3/ and the model compounds /tetrahydrofurane, 4 and 1,4-dioxane, 5/ were studied by the spin-trapping method using C-phenyl-N-methylnitrone /PBN/ as a spin-trapping agent giving rise to the sufficiently stable nitroxyl radicals. The spin adducts of radicals 2 and 3 are relatively stable up to the temperature 253 K and 453 K, respectively.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02202026

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