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Magnetic behaviour of pollucite-related phases (1989)

Binks, J. H. ; West, A. R. ; Torres-Martinez, Leticia M.

Springer

Journal of materials science 24 (1989), S. 3160-3163

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ISSN: 1573-4803

Source: Springer Online Journal Archives 1860-2000

Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract The magnetic susceptibilities of powdered samples of Cs2CuGe5O12, Cs2FeGe5O12, Cs5NiSi5O12, Rb2CoGe5O12 and CsFeGe2O6 have been measured as a function of temperature. For the first four, the data show the transition metal ion to be in a distorted tetrahedral environment, in agreement with the expected pollucite-like structures. The data for CsFeGe2O6 are also consistent with this interpretation, but the results are less certain. An unusual feature of these materials is the substitution of a range of divalent transition metal ions into the aluminosilicate framework.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01139035

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