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Identification and properties of ultra-fine iron particles dispersed in a glass-like carbon matrix (1979)

Omori, M. ; Yajima, S.

Springer

Journal of materials science 14 (1979), S. 2537-2542

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ISSN: 1573-4803

Source: Springer Online Journal Archives 1860-2000

Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract Various kinds of iron particles and an iron species were synthesized from acetylferrocenefurfural resins in a glass-like carbon matrix by heat-treatment. These irons were investigated in terms of magnetic susceptibility, saturation magnetization, esr, and the Mössbauer effect. Body-centred cubic (b c c) iron, expanded b c c iron, hexagonal close-packed iron, and cluster iron were present as ultra-fine iron particles. The presence of Fe+ was well established as an iron species. The formation of iron particles and Fe+ is discussed on the basis of the pyrolysis of ferrocene skeletons in the resin.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00610619

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