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Synthesis of a Calix[4]arene Containing 'Hard' and 'Soft' Metal Ion Binding Sites (1997)

Pulpoka, Buncha ; Asfari, Zouhair ; Vicens, Jacques

Springer

Journal of inclusion phenomena and macrocyclic chemistry 27 (1997), S. 21-30

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ISSN: 1573-1111

Keywords: Co-receptors ; ‘hard’ and ‘soft’ ; calix[4]arene 1,3-alternate conformation ; crown ether ; diazabenzo crown-ether ; Schiff base

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Co-receptor 1,3-calix[4]-di(aza-benzo)crown-crown-6 (1-H) designed with one calix[4]arene in a 1,3-alternate conformation and ‘hard’ and ‘soft’ metal ion binding sites has been prepared according to three pathways (A-C). Pathway B, consisting of two different 1 + 1 condensations with ditosylate derivatives, was shown to be the most efficient.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1007962601884

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