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Acceleration of the photodimerization of water-soluble anthracenes included by β- and γ-cyclodextrins (1984)

Tamaki, Takashi ; Kokubu, Tomokuni

Springer

Journal of inclusion phenomena and macrocyclic chemistry 2 (1984), S. 815-822

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ISSN: 1573-1111

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The photodimerization of 2-anthracenesulfonate in water was accelerated in the presence of β- and γ-cyclodextrins (CyDs). While four configurational isomers of the photodimer were obtained in the presence of γ-CyD with similar ratio of the yields to that in the host-free solution, only one of the isomers was obtained in the presence of β-CyD. The results were explained by the formation of two guest-one host inclusion complex in the former case and of two guest-two host inclusion complex in the latter. No evidence of an inclusion complex with α-CyD was obtained. The inclusion effects of CyD on the photodimerization of other water-soluble anthracenes were also examined.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00662250

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