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Clathrate formation in water-cyclic ether systems at high pressures (1991)

Dyadin, Yu. A. ; Zhurko, F. V. ; Bondaryuk, I. V. ; [et al.]

Springer

Journal of inclusion phenomena and macrocyclic chemistry 10 (1991), S. 39-56

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ISSN: 1573-1111

Keywords: Clathrate hydrates ; high pressure clathrate formation ; cyclic ether ; P, t, x phase diagram

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Experimental data on the investigation of the water-trimethyleneoxide system,P, t, x phase diagram (up to 6 kbar) are presented. The results are compared with those on water systems with ethyleneoxide, 1,3- and 1,4-dioxane, 1,3-dioxolane and tetrahydrofuran, on the basis of which a summarizedP, t, x diagram is plotted for water-cyclic ether systems. It is shown that in all the systems in which a cubic structure II hydrate forms at 1 bar, it eventually turns to cubic structure I under pressure. The nature of high pressure hydrates is discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01041638

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