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  • 1
    Electronic Resource
    Electronic Resource
    Full matrix Analysis of Cross-relaxation Fails in Fractionally Deuterated Molecules (1998)
    Springer
    Journal of biomolecular NMR 12 (1998), S. 333-337 
    Details
    ISSN: 1573-5001
    Keywords: cross-relaxation ; deuteration ; isotope exchange ; spin-diffusion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract We have analyzed cross-relaxation in fractionally deuterated molecules and showed that the full matrix analysis fails except when the dilution is extreme. This is because the isotopic dilution alters the matrix exponential relationship between the observed spectrum and the cross-relaxation rate constants sought. Consequently, an average of the spectra of various isotopomers differs from the matrix exponential of an average relaxation matrix. We have derived a series expansion that allows the determination of the cross-relaxation rate constants in arbitrarily deuterated molecules.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1008272628775
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