ISSN:
1572-8838
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract The electrochemical corrosion behaviour (passivity, pitting and repassivation) of austenitic stainless steel AISI 321 containing titanium has been investigated in methanol containing different concentrations of sulphuric acid (0.001–1 M). The cathodic reaction is observed to be hydrogen evolution. Anodic polarization of the stainless steel reveals a characteristic ‘cathodic loop’ in methanol with higher concentrations of H2SO4 (0.1 M and 1 M). A clear and stable passivity is also observed in each solution mixture which breaks down at higher potentials due to pitting. The passivation current, passivity range, pitting intensity and pitting potential are found to vary with variation of acid concentration in the methanol. The kinetics of pitting and the morphology of the pits have been studied. A variation in concentration of acid and scan rate has been found to influence the protection potential of the stainless steel.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01015229
