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Decomposition of β-alumina in an oxygen potential gradient (1983)

Jacob, K. T.

Springer

Journal of applied electrochemistry 13 (1983), S. 469-472

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ISSN: 1572-8838

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology

Notes: Abstract Single phase sodiumβ-alumina solid electrolyte was found to undergo isothermal phase separation in electrochemical cells, where a large oxygen potential gradient was imposed across the electrolyte and electrodes, not reversible to sodium ions, were short circuited. The experimental conditions and evidence of decomposition are outlined and a thermodynamic explanation for the phenomenon is given. This finding may lead to new methods for making multi-layered ceramic materials involving ionic conductors.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00617521

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